ISO/TC 201/SC 5 - Auger electron spectroscopy

ISO 15472:2010 specifies a method for calibrating the binding-energy scales of X‑ray photoelectron spectrometers, for general analytical purposes, using unmonochromated Al or Mg X‑rays or monochromated Al X‑rays. It is only applicable to instruments which incorporate an ion gun for sputter cleaning. It further specifies a method to establish a calibration schedule, to test for the binding-energy scale linearity at one intermediate energy, to confirm the uncertainty of the scale calibration at one low and one high binding-energy value, to correct for small drifts of that scale and to define the expanded uncertainty of the calibration of the binding-energy scale for a confidence level of 95 %. This uncertainty includes contributions for behaviours observed in interlaboratory studies but does not cover all of the defects that could occur. ISO 15472 is not applicable to instruments with binding-energy scale errors that are significantly non-linear with energy, to instruments operated in the constant retardation ratio mode at retardation ratios less than 10, to instruments with a spectrometer resolution worse than 1,5 eV, or to instruments requiring tolerance limits of ±0,03 eV or less. It does not provide a full calibration check, which would confirm the energy measured at each addressable point on the energy scale and which would have to be performed in accordance with the manufacturer's recommended procedures.

ISO 17974:2002 specifies a method for calibrating the kinetic energy scales of Auger electron spectrometers used for elemental and chemical state analysis at surfaces. It also specifies a calibration schedule for testing the kinetic energy scale linearity at one intermediate energy, for confirming the uncertainty of the scale calibration at one low and one high kinetic energy value, for correcting for small drifts of that scale and defining the expanded uncertainty of the calibration of the kinetic energy scale for a confidence level of 95 % (with this uncertainty including contributions for behaviours observed in interlaboratory studies but not covering all possible defects). It is applicable only to those instruments incorporating an ion gun for sputter cleaning. It is not applicable to instruments with kinetic energy scale errors significantly non-linear with energy, those operated at relative resolutions poorer than 0,2 % in the constant delta E/E mode or 1,5 eV in the constant delta E mode, those requiring tolerance limits of plus or minus 0,05 eV or less, nor those with an electron gun that cannot be operated in the energy range 5 keV to 10 keV. It does not provide a full calibration check for confirming the energy measured at each addressable point on the energy scale, this being performed according to the manufacturer's recommendations.

ISO 15471:2004 describes the way in which specific aspects of the performance of an Auger electron spectrometer shall be described.

ISO 15470:2004 describes the way in which specific aspects of the performance of an X-ray photoelectron spectrometer shall be described.

ISO 17973:2002 specifies a method for calibrating the kinetic energy scales of Auger electron spectrometers with an uncertainty of 3 eV, for general analytical use in identifying elements at surfaces. In addition, it specifies a method for establishing a calibration schedule. It is applicable to instruments used in either direct or differential mode, where the resolution is less than or equal to 0,5 % and the modulation amplitude for the differential mode, if used, is 2 eV peak-to-peak. It is applicable to those spectrometers equipped with an inert gas ion gun or other method for sample cleaning and with an electron gun capable of operating at 4 keV or higher beam energy.