Refrigerants - Designation and safety classification - Amendment 2

Fluides frigorigènes — Désignation et classification de sécurité — Amendement 2

General Information

Status
Published
Publication Date
07-Apr-2021
Current Stage
9599 - Withdrawal of International Standard
Start Date
27-Nov-2024
Completion Date
13-Dec-2025

Relations

Effective Date
01-Jan-2022
Effective Date
06-Jun-2022

Overview

ISO 817:2014/Amd 2:2021 is the second amendment to the International Standard ISO 817, titled "Refrigerants - Designation and safety classification". Published by the International Organization for Standardization (ISO), this updated document refines the guidelines for assigning designations and safety classifications to refrigerants, including individual compounds and blends. It provides crucial revisions related to refrigerant concentration limits, toxicity exposure thresholds, flammability data, and harmonization processes with other standards such as ASHRAE 34.

This amendment plays a critical role in enhancing the safety, identification, and regulation of refrigerants used in refrigeration and air-conditioning systems, thereby supporting industry compliance and environmental sustainability.


Key Topics

  • Refrigerant Identification Numbers
    Unique identifying numbers are assigned for each refrigerant, following updated series for zeotropes (400 series) and azeotropes (500 series), including differentiation by upper-case letters for variations in composition.

  • Safety Classification Updates
    Safety classifications are aligned with exposure limits such as acute toxicity exposure limits (ATEL), oxygen deprivation limits (ODL), and flammable concentration limits (FCL), which are recalibrated based on peer-reviewed scientific data.

  • Refrigerant Concentration Limits (RCL) Eliminated
    This amendment removes references to Refrigerant Concentration Limits (RCL) from tables and text, focusing instead on limiting flammability and toxicity using updated metrics such as Lower Flammable Limits (LFL).

  • Updated Toxicity and Flammability Assessment
    The method to calculate ATEL for blends has been clarified, including formulas based on mole fractions and toxicity concentration factors. Burning velocity data and flammability classifications are expanded upon with new parameters.

  • Harmonization with ASHRAE 34
    Amendment 2 formalizes a harmonization process to avoid duplication or conflict of refrigerant numbers between ISO 817 and ASHRAE 34, ensuring consistent worldwide designation.

  • Applications and Data Submission
    Protocols for submitting applications for new refrigerants, safety classifications, and concentration limits are defined, including data requirements for toxicity, flammability, and composition. Applications must include comprehensive scientific and engineering data summaries.


Applications

  • Refrigerant Industry Usage
    This amendment is essential for manufacturers and users of refrigerants to correctly identify, classify, and handle refrigerants according to internationally recognized safety standards.

  • Safety and Compliance Management
    Regulatory bodies and safety agencies rely on ISO 817:2014/Amd 2:2021 to assess refrigerant risks related to toxicity, flammability, and exposure, driving safer HVAC and refrigeration system designs.

  • Environmental Impact Mitigation
    Correct classification aids in selecting refrigerants that balance environmental concerns with performance, thus helping reduce the impact of refrigerants on global warming and ozone depletion.

  • Standardization of Blends
    Refrigerant blends, including azeotropes and zeotropes, benefit from clear designation and safety classification, which is vital for refrigeration system servicing and regulatory compliance.


Related Standards

  • ISO 817:2014
    The base standard on refrigerant designation and safety classification, which Amendment 2 refines and supplements.

  • ASHRAE Standard 34
    Addresses refrigerant numbering and safety group classification in North America. Harmonization efforts ensure consistent refrigerant designations worldwide.

  • AHRI Standard 700
    Relates to refrigerant purity, impurities, and limits on contaminants that may affect safety classifications.

  • ISO/IEC Directives Part 1 and Part 2
    Define the procedures and editorial rules for preparing and maintaining ISO standards, ensuring high-quality documentation.

  • ISO 10298
    Provides data on toxic concentration factors used for calculating exposure limits referenced in ISO 817.


Keywords: ISO 817 amendment 2, refrigerant designation, refrigerant safety classification, refrigerant concentration limits, refrigerant toxicity, flammability limits, refrigerant blends, zeotropes, azeotropes, ASHRAE harmonization, HVAC safety standards, refrigerant concentration, toxicity exposure limit, lower flammable limit, refrigerant standards, refrigerant safety compliance.

Standard

ISO 817:2014/Amd 2:2021 - Refrigerants — Designation and safety classification — Amendment 2 Released:4/8/2021

English language
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Frequently Asked Questions

ISO 817:2014/Amd 2:2021 is a standard published by the International Organization for Standardization (ISO). Its full title is "Refrigerants - Designation and safety classification - Amendment 2". This standard covers: Refrigerants - Designation and safety classification - Amendment 2

Refrigerants - Designation and safety classification - Amendment 2

ISO 817:2014/Amd 2:2021 is classified under the following ICS (International Classification for Standards) categories: 71.100.45 - Refrigerants and antifreezes. The ICS classification helps identify the subject area and facilitates finding related standards.

ISO 817:2014/Amd 2:2021 has the following relationships with other standards: It is inter standard links to ISO 817:2014, ISO 817:2024. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ISO 817:2014/Amd 2:2021 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


INTERNATIONAL ISO
STANDARD 817
Third edition
2014-06-01
AMENDMENT 2
2021-03
Refrigerants — Designation and safety
classification
AMENDMENT 2
Fluides frigorigènes — Désignation et classification de sécurité
AMENDEMENT 2
Reference number
ISO 817:2014/Amd.2:2021(E)
©
ISO 2021
ISO 817:2014/Amd.2:2021(E)
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2021 – All rights reserved

ISO 817:2014/Amd.2:2021(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www .iso .org/
iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 86, Refrigeration and air-conditioning,
Subcommittee SC 8, Refrigerants and refrigeration lubricants.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/ members .html.
ISO 817:2014/Amd.2:2021(E)
Refrigerants — Designation and safety classification
AMENDMENT 2
3.1.36
Replace Note 1 to entry with the following:
Note 1 to entry: Acute toxicity exposure limit, oxygen deprivation limit and flammable concentration
limit are refrigerant concentration limits that are determined in accordance with this document.

3.2
Delete the following text:
RCL refrigerant concentration limit
RCL RCL expressed as grams per cubic metre
M
RCL RCL expressed as parts per million by volume
ppm
4.1
Replace the text with the following:
An identifying number shall be assigned to each refrigerant. Assigned numbers and safety
classifications are shown in Tables 5, 6 and 7. Tables E.4, E.5 and E.6 provide designations for
refrigerants for which insufficient data are available for safety classification or determination of
refrigerant concentration limits.

4.4.1
Replace the text with the following:
Zeotropes shall be assigned an identifying number in the 400 series. In order to differentiate
among the different zeotropes having the same components but in different proportions, an upper-
case letter (A, B, C, etc.) is added after the number. The numbers and letters shall be assigned
considering harmonization as presented in Clause 9.

4.4.2
Replace the text with the following:
Azeotropes shall be assigned an identifying number in the 500 series. In order to differentiate
among the different azeotropes having the same components but in different proportions, an
upper-case letter (A, B, C, etc.) is added after the number. The numbers and letters shall be assigned
considering harmonization as presented in Clause 9.
ISO 817:2014/Amd.2:2021(E)
5.2
Replace the second paragraph with the following:
The compositional designating prefixes for ethers shall substitute an “E” for “C” (carbon), such that
HFE, HCFE, and CFE refer to hydrofluoroether, hydrochlorofluoroether, and chlorofluoroether,
respectively. E in the identifying number shall be omitted when composition-designating prefixes
are used. The composition designating prefixes for halogenated olefins shall be either:
—  CFC, HCFC, or HFC to refer to chlorofluorocarbon, hydrochlorofluorocarbon, or
hydrofluorocarbon, respectively; or
—  with substitution of an O for the carbon C, as CFO, HCFO, HCO or HFO, to refer to chlorofluoro-
olefin, hydrochlorofluoro-olefin, hydrochloro-olefin or hydrofluoro-olefin, respectively.

Clause 8
Replace the title with the following:
8  Refrigerant concentration limits

8.1
Replace the text with the following:
Determination of the refrigerant concentration limits shall assume full vaporization and uniform
mixing; no removal by dissolution, reaction or decomposition in the volume to which it is released.
Safety factors are included for consideration of temporary local concentrations or uncertainties in
the test data.
8.1.1.1
Replace the text with the following:
The ATEL shall be the lowest of the toxic concentration factors (TCF) 8.1.1.2 to 8.1.1.5. For blends,
where available, the blend toxicity data shall be used for the individual parameter values in 8.1.1.1
to 8.1.1.5 and when toxicity data for the blends are not available, shall be calculated according to
the following formula:
X X X
1 2 n
=+ +…+
C C C C
blend 1 2 n
where
x is the mole fraction of component n of the blend;
n
C is the TCF for component n in accordance with ISO 10298.
n
NOTE See Annex D for a sample calculation of ATEL and Annex E for a
...

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