Textiles — Measurement of exothermic and endothermic properties of textiles under humidity change

ISO 16533:2014 specifies a method for the measurement of exothermic and endothermic properties by moisture absorption and desorption in sheet-like textiles, e.g. fabrics, knit or nonwovens for clothing, bedding, upholstery, and similar textile products.

Textiles — Mesurage des propriétés exothermiques et endothermiques de textiles sous conditions d'humidité changeantes

General Information

Status
Published
Publication Date
01-Jul-2014
Technical Committee
ISO/TC 38 - Textiles
Current Stage
9093 - International Standard confirmed
Start Date
17-Sep-2025
Completion Date
14-Feb-2026

Overview

ISO 16533:2014 specifies a laboratory test method to measure the exothermic and endothermic thermal behaviour of sheet-like textiles (fabrics, knits, nonwovens) when environmental humidity changes. The method quantifies heat released during moisture absorption (exothermic) and heat absorbed during moisture desorption/evaporation (endothermic) by recording temperature changes of a specimen transferred between controlled humidity environments.

Key topics and technical requirements

  • Scope: Measurement of exothermic/endothermic properties caused by moisture absorption/desorption for clothing, bedding, upholstery and similar products.
  • Definitions: includes terms such as exothermic property, endothermic property, hygroscopic and exothermic, and hygroemissive and endothermic.
  • Principle: specimen is equilibrated at one humidity level, transferred to another, and the temperature response is recorded. The effect is determined as the temperature difference between measurements with and without a specimen.
  • Specimen preparation:
    • Cut three specimens of (50 ± 1) mm × (50 ± 1) mm.
    • Dry at (105 ± 3) °C for ≥2 h and store in a desiccator until test.
  • Apparatus:
    • Temperature and humidity controlled chamber (≈220 L) with tolerance ±0.5 °C and ±3 % RH.
    • Constant-humidity containers (2 L flasks) using chemical humidity buffers.
    • Airtight silicone rubber plugs with a temperature sensor probe protruding ~10 cm into the flask.
    • Temperature sensor probe: disk type (5 ± 1 mm diameter, 2.5 ± 0.5 mm thickness).
  • Humidity control & reagents:
    • Sulfuric acid–water solutions provide fixed RH at test temperature (example at 34 °C: ~65 wt% H2SO4 → 10 % RH; 48 wt% → 40 % RH; 20 wt% → 90 % RH; uncertainty ±3 % RH).
    • Water for lab use per ISO 3696.
  • Test procedure:
    • Equilibrate plug+specimen in first (low or high) humidity flask for ≥3 h.
    • Transfer plug to second (target) humidity flask, record temperature ≥30 min.
    • Determine peak (exothermic) or bottom (endothermic) temperature and compute ΔT = T_specimen − T_blank.

Practical applications and users

  • Textile manufacturers and R&D labs validating thermal performance of materials.
  • Product developers of active thermal garments (outdoor, sports, innerwear), bedding, upholstery, healthcare textiles.
  • Quality control teams comparing hygroscopic heat generation or cooling performance between materials.
  • Researchers and standards bodies assessing thermal comfort, product claims, or enabling comparability across suppliers.

Related standards

  • ISO 3696:1987 - Water for analytical laboratory use.
  • ISO 3801:1977 - Determination of mass per unit area for woven fabrics.

ISO 16533 provides a repeatable, objective way to quantify humidity-driven thermal effects in textiles, aiding material selection, product development, and performance claims related to moisture-induced heating or cooling.

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ISO 16533:2014 - Textiles -- Measurement of exothermic and endothermic properties of textiles under humidity change

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Frequently Asked Questions

ISO 16533:2014 is a standard published by the International Organization for Standardization (ISO). Its full title is "Textiles — Measurement of exothermic and endothermic properties of textiles under humidity change". This standard covers: ISO 16533:2014 specifies a method for the measurement of exothermic and endothermic properties by moisture absorption and desorption in sheet-like textiles, e.g. fabrics, knit or nonwovens for clothing, bedding, upholstery, and similar textile products.

ISO 16533:2014 specifies a method for the measurement of exothermic and endothermic properties by moisture absorption and desorption in sheet-like textiles, e.g. fabrics, knit or nonwovens for clothing, bedding, upholstery, and similar textile products.

ISO 16533:2014 is classified under the following ICS (International Classification for Standards) categories: 59.080.01 - Textiles in general. The ICS classification helps identify the subject area and facilitates finding related standards.

ISO 16533:2014 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


INTERNATIONAL ISO
STANDARD 16533
First edition
2014-07-01
Textiles — Measurement of
exothermic and endothermic
properties of textiles under humidity
change
Textiles — Mesurage des propriétés exothermiques et endothermiques
de textiles sous conditions d’humidité changeantes
Reference number
©
ISO 2014
© ISO 2014
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Case postale 56 • CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail copyright@iso.org
Web www.iso.org
Published in Switzerland
ii © ISO 2014 – All rights reserved

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Symbols and units . 2
5 Principle . 2
6 Apparatus . 2
7 Reagent . 4
8 Preparation of the humidity control material . 4
9 Test procedure . 5
9.1 Preparation of test specimen . 5
9.2 Preparation of apparatus . 5
9.3 Test specimen mounting . 5
9.4 Measurement of exothermic and endothermic properties . 6
10 Test report . 8
Annex A (informative) Example of hygroscopic and exothermic property test .9
Annex B (informative) Example of hygroemissive and endothermic property test .10
Annex C (informative) Example of practical humidity measurement .11
Bibliography .13
Foreword
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bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
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ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the meaning of ISO specific terms and expressions related to conformity
assessment, as well as information about ISO’s adherence to the WTO principles in the Technical Barriers
to Trade (TBT) see the following URL: Foreword - Supplementary information
The committee responsible for this document is ISO/TC 38, Textiles.
iv © ISO 2014 – All rights reserved

Introduction
The thermal properties of textile materials contribute to a wearer’s physiological comfort, product’s
durability, etc. Hence, there are many kinds of products with specific thermal performances and various
test methods that have been developed and standardized. However, these tests should be conducted in
a certain humidity. The method for thermal properties in elevated or reduced humidity has not been
standardized.
All materials generate heat when absorbing moisture and absorb heat when releasing moisture. The
heat of absorption varies according to the material, for example, the heat of absorption in wool fibre is
much bigger than that in common synthetic fibre. Recently, with this property, some heat-generating
textiles have been developed and applied to various products, such as outdoor wear, sportswear, inner
wear, special working wear, and healthcare wear. Therefore, the test for the hygroscopic and exothermic
properties of textiles is needed for both producers and customers. Despite these needs, accurate and
reliable information about hygroscopic and exothermic properties of textiles cannot be offered because
of the absence of a standard test method.
The exothermic and endothermic properties of textiles under changing conditions of environmental
humidity can be measured with this test method and apparatus proposed in this International Standard.
INTERNATIONAL STANDARD ISO 16533:2014(E)
Textiles — Measurement of exothermic and endothermic
properties of textiles under humidity change
1 Scope
This International Standard specifies a method for the measurement of exothermic and endothermic
properties by moisture absorption and desorption in sheet-like textiles, e.g. fabrics, knit or nonwovens
for clothing, bedding, upholstery, and similar textile products.
2 Normative references
The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any amendments) applies.
ISO 3696:1987, Water for analytical laboratory use — Specification and test methods
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
exothermic property
property of material whereby it releases heat to the surroundings
3.2
endothermic property
property of material whereby it absorbs heat from the surroundings
3.3
hygroscopic and exothermic property
property of material whereby it generates heat by absorbing moisture and releases the generated heat
to its surroundings where relative humidity changes from low to high over time
3.4
hygroemissive and endothermic property
property of material whereby it loses heat and cools down by releasing moisture through evaporation
to its surroundings where relative humidity changes from high to low over time
4 Symbols and units
T is the ambient temperature in a temperature and humidity controlled chamber, in degrees Celsius.
A
RH is the ambient relative humidity in a temperature and humidity controlled chamber, in per cent.
A
RH is the relative humidity in the first constant humidity container, starting humidity, in per cent.
RH is the relative humidity in the second constant humidity container, target humidity, in per cent.
T is the peak temperature, determined using a temperature sensor with or without the test specimen
peak
mounted on the sensor probe in the second constant humidity container during the hygroscopic and
exothermic property tes
...

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