EN 12049:1996

Overview

EN 12049:1996 is a European standard established by CEN that specifies a precise gravimetric method for determining the moisture content in solid fertilizers and liming materials. This method employs drying under reduced pressure to ensure accurate moisture measurement, adapting the ISO 8189:1992 standard with modifications. The procedure is essential for quality control in fertilizer production, helping to ensure proper handling, storage, and application of these agricultural inputs.

This standard is relevant for industries involved in manufacturing and analyzing solid fertilizers and soil conditioners. However, it excludes certain fertilizer types such as those containing calcium nitrate, calcium hydroxide, or specific forms of calcium and magnesium sulfate due to their chemical properties affecting the drying process.

Key Topics

• Scope and Applicability
  The method targets solid fertilizers and liming materials for moisture content determination. It specifically excludes fertilizers with:

  • Calcium nitrate
  • Calcium hydroxide
  • Calcium sulfate containing less than two water molecules of crystallization
  • Magnesium sulfate with one or seven water molecules of crystallization
  • Readily efflorescent salts under ambient conditions

• Principle of the Method
  The moisture content is determined gravimetrically by drying a test sample at 25°C and a reduced pressure of 66 × 10³ Pa for 24 hours. The loss in mass after drying corresponds to the moisture content.

• Apparatus and Materials Needed

  • Weighing bottles with stoppers (70-80 mm diameter)
  • Vacuum desiccator (approx. 200 mm diameter) with activated silica gel desiccant
  • Vacuum pump and pressure gauge
  • Evaporating basin (approx. 100 mm diameter)
  • Oven capable of maintaining 105 ± 2 °C

• Test Procedure

  1. Prepare the sample according to ISO 8358 without grinding or by gentle crushing if necessary.
  2. Dry and cool the weighing bottle and stopper before sample weighing.
  3. Weigh approximately 10 g of the test sample in the prepared weighing bottle.
  4. Place the bottle and stopper in the vacuum desiccator with activated silica gel.
  5. Apply vacuum to maintain 66 × 10³ Pa pressure at 25 ± 3 °C for 24 hours.
  6. After drying, reintroduce air dried via silica gel, quickly seal the bottle, and weigh again to determine mass loss.

• Calculations and Reporting
  Moisture content is expressed as a percentage of the initial sample mass. Test results should be averaged over at least two determinations and rounded to 0.1%. The test report must include:

  • Reference to this standard
  • Test results and expression method
  • Sample identification details
  • Any anomalies observed
  • Description of any deviations or optional steps applied

• Precision and Reliability
  Informative annexes provide repeatability and reproducibility limits based on interlaboratory studies, enhancing confidence in the method’s robustness.

Applications

• Quality Control in Fertilizer Production
  Accurate moisture content determination is critical to ensure product stability, prevent caking, and maintain nutrient availability. EN 12049:1996 provides a standardized test assuring consistent quality.

• Compliance with Regulatory Requirements
  Fertilizer manufacturers and distributors can use the standard method to demonstrate adherence to moisture content regulations, supporting safe transportation and storage.

• Agricultural Research and Soil Science
  Laboratories analyzing soil conditioners and amendments use this gravimetric method to control moisture variables impacting efficacy and application rates.

• Import/Export Verification
  Harmonized testing enables uniform assessment of fertilizer shipments across international borders, reducing disputes related to moisture content.

Related Standards

• ISO 8189:1992 – The original international standard detailing the gravimetric moisture determination by drying under reduced pressure, forming the basis for EN 12049:1996 with modifications.

• ISO 8358:1991 – Provides guidance on the preparation of fertilizer samples for chemical and physical analysis, referenced in EN 12049 for sample preparation.

• Other Fertilizer Testing Standards
  Standards covering chemical composition, physical properties, and safety of solid fertilizers complement EN 12049 for comprehensive quality assessment.

Keywords: EN 12049, ISO 8189, solid fertilizers, liming materials, moisture content determination, gravimetric method, drying under reduced pressure, fertilizer quality control, soil conditioners, CEN standards, fertilizer analysis, moisture testing standard.