CEN/TR 10317:2009

SLOVENSKI STANDARD
01-november-2009
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European certified reference materials (EURONORM-CRMs) for the determination of the
chemical composition of iron and steel products prepared under the auspices of the
European Committee for Iron and Steel Standardization
Europäische zertifizierte Referenzmaterialien (EURONORM-ZRMs) für die Bestimmung
der chemischen Zusammensetzung von Eisen- und Stahlerzeugnissen, hergestellt unter
der Schirmherrschaft des Europäischen Komitees für Eisen- und Stahlnormung (ECISS)
Matériaux de référence certifiés européens (EURONORMMRC) destinés à la
détermination de la composition chimique des produits ferreux élaborés sous les
auspices du Comité européen de normalisation du fer et de l'acier (ECISS)
Ta slovenski standard je istoveten z: CEN/TR 10317:2009
ICS:
77.040.30 Kemijska analiza kovin Chemical analysis of metals
77.080.01 Železne kovine na splošno Ferrous metals in general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

TECHNICAL REPORT
CEN/TR 10317
RAPPORT TECHNIQUE
TECHNISCHER BERICHT
July 2009
ICS 71.040.30; 77.150.10 Supersedes CR 10317:2002
English Version
European certified reference materials (EURONORM-CRMs) for
the determination of the chemical composition of iron and steel
products prepared under the auspices of the European
Committee for Iron and Steel Standardization
Matériaux de référence certifiés européens (EURONORM- Europäische zertifizierte Referenzmaterialien
MRC) destinés à la détermination de la composition (EURONORM-ZRMs) für die Bestimmung der chemischen
chimique des produits ferreux élaborés sous les auspices Zusammensetzung von Eisen- und Stahlerzeugnissen,
du Comité européen de normalisation du fer et de l'acier hergestellt unter der Schirmherrschaft des Europäischen
(ECISS) Komitees für Eisen- und Stahlnormung (ECISS)
This Technical Report was approved by CEN on 30 May 2009. It has been drawn up by the Technical Committee ECISS/TC 20.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2009 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 10317:2009: E
worldwide for CEN national Members.

Contents Page
Foreword .3
1 Scope .4
2 Introduction .4
3 Classification of EURONORM-CRMs .4
4 Preparation of the samples .6
4.1 EURONORM-CRMs of cast and wrought materials .6
4.1.1 High purity irons, steels and special alloys .6
4.1.2 Pig irons and cast irons .6
4.1.3 Ferro-alloys .6
4.2 EURONORM-CRMs of non-metallic materials .6
4.2.1 Ores, Concentrates, Sinters and Miscellaneous Materials: Additives and Refractories .6
4.2.2 By-products, such as slags, dusts and similar materials .7
5 Certification .7
5.1 Main rules .7
5.2 Main content of the certificates .7
5.2.1 General .7
5.2.2 Description of the sample .8
5.2.3 Intended use and stability .8
5.2.4 Traceability .8
5.2.5 Further information.8
6 Samples presentation .8
7 Distribution of EURONORM-CRMs .9
8 Details of current EURONORM-CRMs .9
Bibliography . 10

Foreword
This document (CEN/TR 10317:2009) has been prepared by Technical Committee ECISS/TC 20 “Methods of
chemical analysis of ferrous products”, the secretariat of which is held by SIS.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document supersedes CR 10317:2002.
1 Scope
This document describes the classification, the method of sample preparation for each material, the
certification main rules and certificate content of the EURONORM-CRMs.
It also lists the samples' presentation, the corresponding producer's organizations and the distributing
sources.
2 Introduction
ln accordance with the definition in ISO Guide 30 the Certified Reference Materials (CRMs) described in this
CEN Report are "homogeneous materials or substances, one or more of whose property values are certified
by a procedure which establishes its traceability to an accurate realization of the unit in which the property
values are expressed, and for which each certified value is accompanied by an uncertainty value at a stated
level of confidence". Furthermore, they are accompanied by a certificate issued by the producing organisation
on behalf of the Co-ordinating Committee (COCOR) of ECISS after approval by the participating laboratories
and all the producing organisations:
a) France:
1) ArcelorMittal Maizières [former Institut de Recherches de la Sidérurgie Française (IRSID)],
2) Centre de Développement des Industries de Mise en Forme des Matériaux (CTIF);
b) Germany: Iron and Steel CRM Working Group (AGZRM) comprising:
1) BAM Bundesanstalt für Materialforschung und -prüfung,
2) Max-Planck-Institut für Eisenforschung (MPI),
3) Stahlinstitut VDEh;
c) Nordic Countries: Nordic CRM Working Group, (NCRMWG) comprising:
1) Swerea KIMAB [former Swedish Institute for Metals Research (SIMR)],
2) Jernkontoret;
d) United Kingdom - Bureau of Analysed Samples Limited (BAS).
Since 1968 EURONORM-CRMs have been analysed by laboratories in most countries in the European
Union (EU) or former European Community (EC).
Pending their eventual replacement by EURONORM-CRMs, a number of former national CRMs prepared,
analysed and certified by laboratories in Germany, France and the United Kingdom respectively, were
accepted as EURONORM-CRMs after their accuracy had been checked by other European laboratories. This
procedure ceased in 1990.
3 Classification of EURONORM-CRMs
EURONORM-CRMs, prepared under the auspices of ECISS, are classified into two main groups:
 Cast and wrought materials: irons, steels, special alloys and ferro-alloys;
 Non-metallic materials: raw materials (ores, concentrates, additives and refractories) and by-products
(slags, dusts and similar materials).
Besides this first generic classification, EURONORM-CRMs are grouped into the following categories:
a) From 001 to 099 – high purity irons and unalloyed steels
Normally no element has a mass content greater than the limit values in the following list:
1) silicon, limit value 1,0 %;
2) manganese, limit value 1,5 %;
3) chromium and nickel, limit value for each 0,5 %;
4) cobalt, copper and tungsten, limit value for each 0,3 %;
5) other elements, limit value for each 0,10 %;
6) boron, carbon, phosphorus, lead and sulphur, no limit value.
b) From 101 to 199 – low alloy steels
The content of one or more elements is greater than the limit for unalloyed steels but none exceeds 5 %. The
sum of these alloying elements remains under 10 %.
c) From 201 – 299 – highly alloyed steels
The content of one or more elements is greater than 5 % or the sum of all these alloying elements is at
least 10 %. Nevertheless the iron content will normally be greater than 50 %.
d) From 301 to 399 - special alloys
The iron content is less than 50 %.
e) From 401 to 499 – pig irons and cast irons
f) From 501 to 599 – ferro-alloys
g) From 601 to 699 – ores, concentrates, sinters and miscellaneous materials
h) From 701 to 799 – additives and refractories
i) From 801 to 899 – by-products, such as slags, dusts and similar materials
The expression "-1" after a CRM number refers to the first issue of a CRM and "-2", "-3" etc. refer to
replacement CRMs of generally similar
...