EN ISO 16190:2021

SLOVENSKI STANDARD
01-januar-2022
Nadomešča:
SIST-TS CEN ISO/TS 16190:2014
Obutev - Kritične snovi, ki so lahko v obutvi in delih obutve - Preskusna metoda za
kvantitativno ugotavljanje policikličnih aromatskih ogljikovodikov (PAH) v
obutvenih materialih (ISO 16190:2021)
Footwear - Critical substances potentially present in footwear and footwear components
- Test method to quantitatively determine polycyclic aromatic hydrocarbons (PAHs) in
footwear materials (ISO 16190:2021)
Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische
Substanzen - Prüfverfahren zur quantitativen Bestimmung polyzyklischer aromatischer
Kohlenwasserstoffe (PAK) in Schuhwerkstoffen (ISO 16190:2021)
Chaussures - Substances critiques potentiellement présentes dans les chaussures et les
composants de chaussures - Méthode d’essai pour déterminer quantitativement les
hydrocarbures aromatiques polycycliques (HAP) dans les matériaux de chaussures (ISO
16190:2021)
Ta slovenski standard je istoveten z: EN ISO 16190:2021
ICS:
61.060 Obuvala Footwear
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 16190
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2021
EUROPÄISCHE NORM
ICS 61.060 Supersedes CEN ISO/TS 16190:2013
English Version
Footwear - Critical substances potentially present in
footwear and footwear components - Test method to
quantitatively determine polycyclic aromatic
hydrocarbons (PAHs) in footwear materials (ISO
16190:2021)
Chaussures - Substances critiques potentiellement Schuhe - Möglicherweise in Schuhen und
présentes dans les chaussures et les composants de Schuhbestandteilen vorhandene kritische Substanzen -
chaussures - Méthode d'essai pour déterminer Prüfverfahren zur quantitativen Bestimmung
quantitativement les hydrocarbures aromatiques polyzyklischer aromatischer Kohlenwasserstoffe (PAK)
polycycliques (HAP) dans les matériaux de chaussures in Schuhwerkstoffen (ISO 16190:2021)
(ISO 16190:2021)
This European Standard was approved by CEN on 7 November 2021.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 16190:2021 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 16190:2021) has been prepared by Technical Committee ISO/TC 216
"Footwear" in collaboration with Technical Committee CEN/TC 309 “Footwear” the secretariat of which
is held by UNE.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2022, and conflicting national standards shall be
withdrawn at the latest by May 2022.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN ISO/TS 16190:2013.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 16190:2021 has been approved by CEN as EN ISO 16190:2021 without any modification.

INTERNATIONAL ISO
STANDARD 16190
First edition
2021-11
Footwear — Critical substances
potentially present in footwear and
footwear components — Test method
to quantitatively determine polycyclic
aromatic hydrocarbons (PAHs) in
footwear materials
Chaussures — Substances critiques potentiellement présentes dans
les chaussures et les composants de chaussures — Méthode d’essai
pour déterminer quantitativement les hydrocarbures aromatiques
polycycliques (HAP) dans les matériaux de chaussures
Reference number
ISO 16190:2021(E)
ISO 16190:2021(E)
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
ISO 16190:2021(E)
Contents Page
Foreword .iv
Introduction . vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 1
6 Apparatus . 5
7 Sample preparation .5
8 Procedure .5
8.1 Extraction . 5
8.2 Optional: Solid-phase extraction (SPE) clean-up . 6
8.3 Determination by GC-MS or GC-MS/MS . . 6
9 Expression of results . 6
9.1 Determination of the PAH content . 6
9.1.1 For each PAH . 6
9.1.2 When a sum of PAHs is requested. 6
9.2 Performance of the test method . 7
10 Test report . 7
Annex A (informative) Examples of chromatographic conditions for GC-MS and GC-MS/MS .8
Bibliography .11
iii
ISO 16190:2021(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 216, Footwear, in collaboration with
the European Committee for Standardization (CEN) Technical Committee CEN/TC 309, Footwear, in
accordance with the Agreement on technical cooperation between ISO and CEN (Vienna Agreement).
This first edition cancels and replaces the first edition Technical Specification (ISO/TS 16190:2013),
which has been technically revised. The main changes compared with the previous edition are as
follows:
— the Introduction has been added;
— in the Scope, editorial changes have been made and a note has been added;
— the Normative references have been updated;
— Clause 3 “Terms and definitions” has been added and the following clauses have been renumbered;
— Clause 5 “Reagents” has been renamed and major technical changes have been made;
— Clause 6 “Apparatus” has been renamed, further equipment has been added and further minor
technical changes have been made;
— Clause 7 “Sample preparation” has been added, which has been mainly taken from ISO/TS 16190:2013,
6.2, and the following clauses have been renumbered;
— in Clause 8 “Procedure”, major technical changes and editorial changes have been made;
— Clause 9 “Expression of results” has been renamed and subclause headings have been added;
— 9.1.2 “When a sum of PAH is requested” has been added;
— in 9.2 “Performance of the test method”, the limit of quantifi
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