EN ISO 11495:2019

SLOVENSKI STANDARD
01-november-2019
Nadomešča:
SIST EN ISO 11495:2016
Nakit in plemenite kovine - Določevanje paladija v zlitinah paladija - Metoda ICP-
OES z uporabo notranjega standardnega elementa (ISO 11495:2019)
Jewellery and precious metals - Determination of palladium in palladium alloys - ICP-
OES method using an internal standard element (ISO 11495:2019)
Schmuck und Edelmetalle - Bestimmung von Palladium in
Palladiumschmucklegierungen - ICP-OES-Verfahren unter Verwendung eines internen
Standardelements (ISO 11495:2019)
Joaillerie et métals précieux - Dosage du palladium dans les alliages de palladium -
Méthode par l'ICP-OES, utilisant un étalon interne (ISO 11495:2019)
Ta slovenski standard je istoveten z: EN ISO 11495:2019
ICS:
39.060 Nakit Jewellery
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 11495
EUROPEAN STANDARD
NORME EUROPÉENNE
August 2019
EUROPÄISCHE NORM
ICS 39.060 Supersedes EN ISO 11495:2016
English Version
Jewellery and precious metals - Determination of
palladium in palladium alloys - ICP-OES method using an
internal standard element (ISO 11495:2019)
Joaillerie, bijouterie et métaux précieux - Dosage du Schmuck und Edelmetalle - Bestimmung von Palladium
palladium dans les alliages de palladium - Méthode par in Palladiumschmucklegierungen - ICP-OES-Verfahren
ICP-OES utilisant un étalon interne (ISO 11495:2019) unter Verwendung eines internen Standardelements
(ISO 11495:2019)
This European Standard was approved by CEN on 21 April 2019.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 11495:2019 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 11495:2019) has been prepared by Technical Committee ISO/TC 174 "Jewellery
and precious metals" in collaboration with CCMC.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by February 2020, and conflicting national standards
shall be withdrawn at the latest by February 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 11495:2016.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 11495:2019 has been approved by CEN as EN ISO 11495:2019 without any modification.

INTERNATIONAL ISO
STANDARD 11495
Third edition
2019-07
Jewellery and precious metals —
Determination of palladium in
palladium alloys — ICP-OES method
using an internal standard element
Joaillerie et métaux précieux — Dosage du palladium dans les alliages
de palladium — Méthode par ICP-OES utilisant un étalon interne
Reference number
ISO 11495:2019(E)
©
ISO 2019
ISO 11495:2019(E)
© ISO 2019
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
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Phone: +41 22 749 01 11
Fax: +41 22 749 09 47
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2019 – All rights reserved

ISO 11495:2019(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 1
6 Equipment . 2
7 Sampling . 2
8 Procedure. 2
8.1 Internal standard solution . 2
8.2 Calibration solutions . 2
8.3 Sample solutions . 2
8.4 Measurements . 2
9 Calculation and expression of results . 3
9.1 Calculation . 3
9.2 Repeatability . 4
10 Test report . 4
Bibliography . 6
ISO 11495:2019(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see www .iso
.org/iso/foreword .html.
This document was prepared by Technical Committee ISO/TC 174, Jewellery and precious metals.
This third edition cancels and replaces the second edition (ISO 11495:2014), which has been technically
revised. The main changes compared to the previous edition are as follows:
a) the definition of bracketing in Clause 3 has been removed;
b) the recommended lines in Clause 4 have been removed;
c) reagents in Clause 5 have been changed and removed, and the requirements about yttrium in 5.4
have been removed;
d) the preparation of the internal standard solution in 8.1 has been changed;
e) the list of standards to be prepared and precisions about qualification of them by linearity as well
as way to choose the low and high standards in 8.2 have been changed;
f) the way of preparation by aliquots for both standard and sample solutions in 8.2 and 8.3 has been
removed;
g) the preparation of both standard and sample solutions in 8.2 and 8.3 has been changed;
h) the definition of bracketing and recommended lines in 8.4 has been added;
i) the formulae in 9.1 have been adapted after having removed the way of preparation by aliquots;
j) the emission line as an information to be mentioned in the test report in Clause 10 has been
removed;
k) the document has been editorially revised.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/members .html.
iv © ISO 2019 – All rights reserved

INTERNATIONAL STANDARD ISO 11495:2019(E)
Jewellery and precious metals — Determination of
palladium in palladium alloys — ICP-OES method using an
internal standard element
1 Scope
This document describes an analytical procedure for the determination of palladium in palladium alloys
with a nominal content up to 990 ‰ (parts per thousand), including alloys according to ISO 9202.
2 Normative references
There are no normative references in this document.
3 Terms and definitions
No terms and definitions are listed in this document.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https: //www .iso .org/obp
— IEC Electropedia: available at http: //www .electropedia .org/
4 Principle
At least two accurately weighed samples are dissolved in aqua regia and made up to an exactly weighed
mass. These sample solutions are mixed with the internal standard and made up to the standard
measuring volume.
Using ICP-OES, the palladium content of the sample solution is measured by comparison of the r
...