CEN/TS 13130-10:2005
(Main)Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 10: Determination of acrylamide in food simulants
Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 10: Determination of acrylamide in food simulants
This Technical Specification, part of EN 13031, specifies an analytical procedure for the determination of acrylamide in the food simulants water, 3 % w/v aqueous acetic acid, 15 % v/v aqueous ethanol and fat simulant. The level of acrylamide monomer determined is expressed as milligrams of acrylamide/kg of food simulant. The method is appropriate for the quantitative determination of acrylamide in approximate analyte concentration range of 0,01 mg/kg to 0,1 mg/kg of food simulants.
The method should also be applicable to other fat simulants.
NOTE The suitability of the fat simulant should be assessed prior to setting up migration tests - it may be found necessary to use sunflower oil or a mixture of synthetic triglycerides if unacceptable interferences are found with olive oil.
Werkstoffe und Gegenstände in Kontakt mit Lebensmitteln - Substanzen in Kunststoffen, die Beschränkungen unterliegen - Teil 10: Bestimmung von Acrylamid in Prüflebensmitteln
Dieses Dokument, Teil der EN 13130, legt ein Analyseverfahren zur Bestimmung von Acrylamid in den Prüflebensmitteln Wasser, 3 %ige Essigsäure (m/V) in wässriger Lösung, 15 %iges Ethanol (Volumenanteil) in wässriger Lösung und in einer Fettsimulanz fest. Der ermittelte Gehalt an monomerem Acrylamid wird in Milligramm Acrylamid je Kilogramm Prüflebensmittel angegeben. Das Verfahren eignet sich zur quantitativen Bestimmung von Acrylamid im angenäherten Konzentrationsbereich des Analyten von 0,01 mg/kg bis 0,1 mg/kg Prüflebensmittel.
Das Verfahren sollte auch auf weitere Fettsimulantien anwendbar sein.
ANMERKUNG Die Eignung der Fettsimulanz sollte vor Beginn der Migrationsprüfungen beurteilt werden - es kann sich als erforderlich herausstellen, Sonnenblumenöl oder eine Mischung synthetischer Triglyceride zu verwenden, wenn bei der Verwendung von Olivenöl unannehmbare Störwirkungen auftreten.
Matériaux et objets en contact avec les denrées alimentaires - Substances dans les matières plastiques soumises à des limitations - Partie 10 : Détermination de l'acrylamide dans les simulants d'aliments
Le présent document, qui fait partie de l'EN 13130, spécifie un mode opératoire d'analyse pour la détermination de l'acrylamide dans les quatre simulants d'aliments suivants : eau, solution aqueuse d'acide acétique à 3 % (m/v), solution aqueuse d'éthanol à 15 % (v/v) et simulant gras. La quantité de monomère d'acrylamide déterminée est exprimée en milligrammes d'acrylamide par kilogramme de simulant d'aliments. Cette méthode convient pour la détermination quantitative de l'acrylamide dans une gamme de concentrations d'analyte comprise approximativement entre 0,01 mg/kg et 0,1 mg/kg de simulant d'aliments.
Il convient que cette méthode puisse également être appliquée à d'autres simulants gras.
NOTE Il convient d'évaluer l'aptitude à l'emploi du simulant gras avant de conduire les essais de migration (l'utilisation d'huile de tournesol ou d'un mélange de triglycérides synthétiques peut s'avérer nécessaire en cas d'identification d'interférences inacceptables dans l'huile d'olive).
Materiali in predmeti v stiku z živili - Snovi v polimernih materialih, katerih koncentracija je omejena - 10. del: Določevanje akrilamida v modelnih raztopinah za živila
General Information
- Status
- Published
- Publication Date
- 22-Feb-2005
- Technical Committee
- CEN/TC 194 - Utensils in contact with food
- Drafting Committee
- CEN/TC 194/SC 1/WG 2 - Methods of test for monomers
- Current Stage
- 6060 - Definitive text made available (DAV) - Publishing
- Start Date
- 23-Feb-2005
- Completion Date
- 23-Feb-2005
Overview
CEN/TS 13130-10:2005 specifies an analytical procedure for the determination of acrylamide migrating from plastics into food simulants. It is part of the EN 13130 series on materials and articles in contact with foodstuffs and addresses quantification of residual acrylamide monomer in the official EU food simulants: water, 3% w/v aqueous acetic acid, 15% v/v aqueous ethanol and a fat simulant. Results are expressed as mg acrylamide/kg simulant and the method targets an approximate quantitation range of 0.01–0.1 mg/kg.
Key topics and technical requirements
- Analytical principle: direct injection of aqueous simulants and HPLC analysis using an ion-exclusion column with UV detection; fat simulants are extracted to water before HPLC.
- Typical chromatographic conditions (example):
- Ion-exclusion column (styrene–divinylbenzene with sulfonated groups)
- Mobile phase: dilute sulfuric acid / acetonitrile mixture
- Flow ~1.5 ml/min, UV detection at 202 nm, injection loop 25 µl
- Standards and reagents: acrylamide reference (>99% purity), HPLC-grade acetonitrile, methanol, water, 0.05 mol/l sulfuric acid; preparation of stock and intermediate calibration standards.
- Performance & limits: method is intended for quantitative determination between 0.01 and 0.1 mg/kg. Laboratories should verify they can achieve the 0.01 mg/kg detection limit - some labs have reported baseline stability and sensitivity issues.
- Validation status & limitations: pre-validated by the developing laboratory; limited interlaboratory validation exists. Confirmation by a reversed-phase HPLC method using a column of different polarity is recommended for identity confirmation.
- Fat simulant caution: suitability of olive oil should be assessed; sunflower oil or synthetic triglyceride mixtures may be required if interferences occur.
Applications and users
This Technical Specification is intended for:
- Analytical and QC laboratories performing migration testing of plastics and food contact materials.
- Manufacturers of food-contact plastics verifying residual monomer levels.
- Regulatory and compliance teams assessing conformity with EU plastics-in-food legislation.
- Use cases include migration testing during product development, batch release testing, regulatory compliance auditing, and safety assessment of plastic packaging.
Related standards and context
- Read in conjunction with EN 13130-1 (Guide to test methods and selection of simulant conditions) and other parts of the EN 13130 series covering specific monomers and migration methods.
- Developed to support EU legislation on plastics in contact with food (see referenced Directives in the Technical Specification).
Keywords: CEN/TS 13130-10:2005, acrylamide, food simulants, migration testing, HPLC, ion-exclusion column, food contact materials, plastics compliance.
Frequently Asked Questions
CEN/TS 13130-10:2005 is a technical specification published by the European Committee for Standardization (CEN). Its full title is "Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 10: Determination of acrylamide in food simulants". This standard covers: This Technical Specification, part of EN 13031, specifies an analytical procedure for the determination of acrylamide in the food simulants water, 3 % w/v aqueous acetic acid, 15 % v/v aqueous ethanol and fat simulant. The level of acrylamide monomer determined is expressed as milligrams of acrylamide/kg of food simulant. The method is appropriate for the quantitative determination of acrylamide in approximate analyte concentration range of 0,01 mg/kg to 0,1 mg/kg of food simulants. The method should also be applicable to other fat simulants. NOTE The suitability of the fat simulant should be assessed prior to setting up migration tests - it may be found necessary to use sunflower oil or a mixture of synthetic triglycerides if unacceptable interferences are found with olive oil.
This Technical Specification, part of EN 13031, specifies an analytical procedure for the determination of acrylamide in the food simulants water, 3 % w/v aqueous acetic acid, 15 % v/v aqueous ethanol and fat simulant. The level of acrylamide monomer determined is expressed as milligrams of acrylamide/kg of food simulant. The method is appropriate for the quantitative determination of acrylamide in approximate analyte concentration range of 0,01 mg/kg to 0,1 mg/kg of food simulants. The method should also be applicable to other fat simulants. NOTE The suitability of the fat simulant should be assessed prior to setting up migration tests - it may be found necessary to use sunflower oil or a mixture of synthetic triglycerides if unacceptable interferences are found with olive oil.
CEN/TS 13130-10:2005 is classified under the following ICS (International Classification for Standards) categories: 67.250 - Materials and articles in contact with foodstuffs. The ICS classification helps identify the subject area and facilitates finding related standards.
You can purchase CEN/TS 13130-10:2005 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of CEN standards.
Standards Content (Sample)
SLOVENSKI STANDARD
01-april-2005
0DWHULDOLLQSUHGPHWLYVWLNX]åLYLOL6QRYLYSROLPHUQLKPDWHULDOLKNDWHULK
NRQFHQWUDFLMDMHRPHMHQDGHO 'RORþHYDQMHDNULODPLGDYPRGHOQLKUD]WRSLQDK
]DåLYLOD
Materials and articles in contact with foodstuffs - Plastics substances subject to limitation
- Part 10: Determination of acrylamide in food simulants
Werkstoffe und Gegenstände in Kontakt mit Lebensmitteln - Substanzen in Kunststoffen,
die Beschränkungen unterliegen - Teil 10: Bestimmung von Acrylamid in
Prüflebensmitteln
Matériaux et objets en contact avec les denrées alimentaires - Substances dans les
matieres plastiques soumises a des limitations - Partie 10 : Détermination de
l'acrylamide dans les simulants d'aliments
Ta slovenski standard je istoveten z: CEN/TS 13130-10:2005
ICS:
67.250 Materiali in predmeti v stiku z Materials and articles in
živili contact with foodstuffs
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
TECHNICAL SPECIFICATION
CEN/TS 13130-10
SPÉCIFICATION TECHNIQUE
TECHNISCHE SPEZIFIKATION
February 2005
ICS 67.250
English version
Materials and articles in contact with foodstuffs - Plastics
substances subject to limitation - Part 10: Determination of
acrylamide in food simulants
Matériaux et objets en contact avec les denrées Werkstoffe und Gegenstände in Kontakt mit Lebensmitteln
alimentaires - Substances dans les matières plastiques - Substanzen in Kunststoffen, die Beschränkungen
soumises à des limitations - Partie 10 : Détermination de unterliegen - Teil 10: Bestimmung von Acrylamid in
l'acrylamide dans les simulants d'aliments Prüflebensmitteln
This Technical Specification (CEN/TS) was approved by CEN on 16 December 2004 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their
comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available
promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS)
until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,
Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36 B-1050 Brussels
© 2005 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 13130-10:2005: E
worldwide for CEN national Members.
Contents
page
Foreword .3
Introduction.5
1 Scope.6
2 Normative references.6
3 Principle .6
4 Reagents .6
5 Apparatus.7
6 Samples.8
7 Procedure.9
8 Expression of results.11
9 Confirmation .13
10 Test report.14
Bibliography.15
CEN/TS 13130-10: 2005 (E)
Foreword
This document (CEN/TS 13130-10:2005) has been prepared by Technical Committee CEN/TC 194 “Utensils
in contact with food”, the secretariat of which is held by BSI.
This part of EN 13130 has been prepared within the Standards, Measurement and Testing project, MAT1-
CT92-0006, “Development of Methods of Analysis for Monomers” and has been prepared by Subcommittee
(SC 1) of TC 194 "Utensils in contact with food" as one of a series of test methods for plastics materials and
articles in contact with foodstuffs.
This standard is intended to support Directives 2002/72/EC [1], 89/109/EEC [2], 82/711/EEC [3] and its
amendments 93/8/EEC [4] and 97/48/EC [5], and 85/572/EEC [6].
At the time of preparation and publication of this part of EN 13130 the European Union legislation relating to
plastics materials and articles intended to come into contact with foodstuffs is incomplete. Further Directives
and amendments to existing Directives are expected which could change the legislative requirements which
this standard supports. It is therefore strongly recommended that users of this standard refer to the latest
relevant published Directive(s) before commencement of a test or tests described in this standard.
This part of EN 13130 should be read in conjunction with EN 13130-1.
Further parts of EN 13130, under the general title Materials and articles in contact with foodstuffs - Plastics
substances subject to limitation, have been prepared, and others are in preparation, concerned with the
determination of specific migration from plastics materials into foodstuffs and food simulants and the
determination of specific monomers and additives in plastics. The parts of EN 13130 are as follows.
Part 1: Guide to test methods for the specific migration of substances from plastics to foods and food
simulants and the determination of substances in plastics and the selection of conditions of exposure to food
simulants
Part 2: Determination of terephthalic acid in food simulants
Part 3: Determination of acrylonitrile in food and food simulants
Part 4: Determination of 1,3-butadiene in plastics
Part 5: Determination of vinylidene chloride in food simulants
Part 6: Determination of vinylidene chloride in plastics
Part 7: Determination of monoethylene glycol and diethylene glycol in food simulants
Part 8: Determination of isocyanates in plastics
Part 9: Determination of acetic acid, vinyl ester in food simulants
Part 10: Determination of acrylamide in food simulants
Part 11: Determination of 11-aminoundecanoic acid in food simulants
Part 12: Determination of 1,3-benzenedimethanamine in food simulants
Part 13: Determination of 2,2-bis(4-hydroxyphenyl)propane (Bisphenol A) in food simulants
Part 14: Determination of 3,3-bis(3-methyl-4-hydroxyphenyl)-2-indoline in food simulants
Part 15: Determination of 1,3-butadiene in food simulants
Part 16: Determination of caprolactam and caprolactam salt in food simulants
Part 17: Determination of carbonyl chloride in plastics
Part 18: Determination of 1,2-dihydroxybenzene, 1,3-dihydroxybenzene,
1,4-dihydroxybenzene, 4,4’-dihydroxybenzophenone and 4,4’dihydroxybiphenyl in food simulants
Part 19: Determination of dimethylaminoethanol in food simulants
Part 20: Determination of epichlorohydrin in plastics
Part 21: Determination of ethylenediamine and hexamethylenediamine in food simulants
Part 22: Determination of ethylene oxide and propylene oxide in plastics
Part 23: Determination of formaldehyde and hexamethylenetetramine in food simulants
Part 24: Determination of maleic acid and maleic anhydride in food simulants
Part 25: Determination of 4-methyl-pentene in food simulants
Part 26: Determination of 1-octene and tetrahydrofuran in food simulants
Part 27: Determination of 2,4,6-triamino-1,3,5-triazine in food simulants
Part 28: Determination of 1,1,1-trimethylolpropane in food simulants
Parts 1 to 8 are European Standards. Parts 9 to 28 are Technical Specifications.
WARNING All chemicals are hazardous to health to a greater or lesser extent. It is beyond the
scope of this Technical Specification to give instructions for the safe handling of all chemicals, that
meet, in full, the legal obligations in all countries in which this Technical Specification may be
followed. Therefore, specific warnings are not given and users of this Technical Specification should
ensure that they meet all the necessary safety requirements in their own country.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to announce this CEN Technical Specification: Austria, Belgium, Cyprus, Czech Republic,
Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland
and United Kingdom.
CEN/TS 13130-10: 2005 (E)
Introduction
Acrylamide, PM/Ref. No 10630, is a monomer used in the manufacture of certain plastics materials and articles
intended to come into contact with foodstuffs. After the manufacture, residual acrylamide can remain in the
polymer and may migrate into foodstuffs coming into contact with that product.
The method has been pre-validated in a validation experiment only by one laboratory (developing laboratory).
NOTE 1 The analytical method described in this part of EN 13130 is the result of a study for the determination of the
migration of acrylamide from plastic materials into food simulants. In the course of the study several problems were
encountered and solutions for these problems were incorporated in the final method. The most suitable and
straightforward method is described in this part of EN 13130. The method was successfully pre-validated by the developing
laboratory, using the four official EU food simulants to establish the precision data at the restriction criterion. Also migration
tests were performed with samples containing acrylamide as monomer in contact with the four simulants for 10 d at 40 °C.
Recovery of acrylamide from fortified simulants at the restriction level was found satisfactory. On testing of the method by a
second laboratory it appeared that the testing laboratory was not able to achieve the required detection limit of 0,01 mg/kg.
Therefore determination of the reproducibility was not performed by the testing lab. In addition the testing laboratory
experienced difficulties with the stability of the base line when operating the HPLC UV detector at 202 nm. Based on the
problems encountered by the testing laboratory the method description was modified to make critical points more clear.
NOTE 2 The confirmation method as given in this method description could be followed by the testing laboratory for
water and olive oil, although again the detection limit could not be achieved. The lowest possible level was approximately
0,02 mg/kg. In the determination of acrylamide in 15 % v/v aqueous ethanol and 3 % w/v aqueous acetic acid, separation
of the simulant and acrylamide was problematic. The testing laboratory concluded that the method was not suitable for the
intended purpose. When however, the migration experiment is carried out in a more favourable ratio of contact area to
simulant then the level of determination can be increased by -at most- a factor of five. In that case problems with detection
limit and base line stability will be much less, and the method may appear to be suitable for the intended purpose.
Within the scope of the Standards, Measurement and Testing project “Monomers” it was not possible to re-test
the method and therefore the method described is considered to be a useful analytical method, with limited
validation data. Further testing is required to demonstrate that the method can be applied with the required
accuracy and limit of detection.
1 Scope
This document, part of EN 13130, specifies an analytical procedure for the determination of acrylamide in the
food simulants water, 3 % w/v aqueous acetic acid, 15 % v/v aqueous ethanol and fat simulant. The level of
acrylamide monomer determined is expressed as milligrams of acrylamide/kg of food simulant. The method is
appropriate for the quantitative determination of acrylamide in approximate analyte concentration range of
0,01mg/kg to 0,1 mg/kg of food simulants.
The method should also be applicable to other fat simulants.
NOTE The suitability of the fat simulant should be assessed prior to setting up migration tests - it may be found
necessary to use sunflower oil or a mixture of synthetic triglycerides if unacceptable interferences are found with olive oil.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
EN 13130-1:2004, Materials and articles in contact with foodstuffs – Plastics substances subject to limitation –
Part 1: Guide to test methods for the specific migration of substances from plastics to foods and food
simulants and the determination of substances in plastics and the selection of conditions of exposure to food
simulants.
3 Principle
The level of acrylamide in food simulants is determined by direct injection of aqueous food simulants for
analysis by high performance liquid chromatography with an ion exclusion column and ultra violet, UV,
detection. Fat simulants are extracted with water and the aqueous extracts than analyzed by high
performance liquid chromatography (HPLC). Quantification is achieved using external standards.
Confirmation of the identity of acrylamide is established by means of reversed phase HPLC using a column of
different polarity but the same detection as used in the quantitative determination.
4 Reagents
NOTE All reagents should be of recognized analytical quality unless otherwise stated.
4.1 Analyte
Acrylamide, CH :CH CONH , molecular weight 71,08, purity greater than 99 %.
2 2
CEN/TS 13130-10: 2005 (E)
4.2 Chemicals
4.2.1 Acetonitrile HPLC grade, suitable for low UV wavelength applications.
4.2.2 Methanol HPLC grade
4.2.3 Water HPLC grade
4.2.4 Sulfuric acid 0,05 mol/l in water
4.3 Solutions
4.3.1 Stock solution of acrylamide in methanol (500 µµµµg/ml)
Weigh to the nearest 0,1 mg approximately 0,05 g of acrylamide into a 100 ml volumetric flask. Dissolve the
acrylamide in methanol and fill up to the mark with methanol. Close and mix thoroughly.
Calculate the actual concentration in µg acrylamide/ml solution.
Repeat the procedure to provide a second stock solution.
Store the stock solutions at 5 °C for up to 3 months protected from light in septum capped glass vials with
minimum headspace.
4.3.2 Diluted stock solution (10 µµµµg/ml)
Using a graduated pipette, transfer 1,0 ml of the acrylamide stock solution (4.3.1) to a 50 ml volumetric flask
and fill to the mark with methanol. This solution contains nominally 10 µg per millilitre of acrylamide.
Repeat the procedure using the second stock solution.
4.3.3 Intermediate standards
Using graduated pipettes, transfer 0 ml, 0,5 ml, 1,0 ml, 2,0 ml, 3,0 ml and 4,0 ml of the 10 µg/ml diluted stock
solution (4.3.2) to a series of 10 ml volumetric flasks. Dilute to the mark with methanol and mix. These
standards correspond nominally to 0 µg/ml, 0,5 µg/ml, 1,0 µg/ml, 2,0 µg/ml, 3,0 µg/ml and 4,0 µg/ml
acrylamide.
4.3.4 HPLC mobile phase
Using a measuring cylinder, transfer 70 ml of 0,05 mol/l sulfuric acid (4.2.4) to a 1 litre volumetric flask and
dilute to about 500 ml with water (4.2.3). Add, using a measuring cylinder, 70 ml of acetonitrile (4.2.1) and
dilute to the mark with water (4.2.3).
NOTE This solution may require de-gassing prior to use.
5 Apparatus
NOTE An instrument or item of apparatus is listed only where it is special, or made to a particular specification, usual
laboratory glassware and equipment being assumed to be available.
5.1 High performance liquid chromatograph, equipped with a ultraviolet det
...
La norme CEN/TS 13130-10:2005 joue un rôle essentiel dans la sécurité alimentaire en fournissant une méthode analytique standardisée pour la détermination de l'acrylamide dans les simulants alimentaires. Son champ d'application couvre des simulants tels que l'eau, l'acide acétique aqueux à 3 % et l'éthanol aqueux à 15 %, ainsi qu'un simulant de graisse, ce qui en fait un outil crucial pour évaluer la migration de substances potentiellement nocives dans les matériaux en contact avec les aliments. Parmi les forces de cette norme, on trouve sa capacité à réaliser une détermination quantitative de l'acrylamide dans une plage de concentration d'environ 0,01 mg/kg à 0,1 mg/kg. Cela permet aux laboratoires de s'assurer que les niveaux d'acrylamide demeurent sous les limites réglementaires, contribuant ainsi à la protection de la santé publique. La méthode est également conçue pour être applicable à d'autres simulants de graisse, ce qui en augmente la polyvalence et la pertinence dans divers contextes d'analyse. Un autre point fort est la mention de la nécessité d'évaluer la compatibilité des simulants de graisse avant la mise en place des tests de migration, offrant ainsi des recommandations pratiques aux utilisateurs afin d'éviter des interférences potentielles lors des analyses. Cette norme est donc pertinente non seulement pour les laboratoires d'analyse, mais aussi pour les fabricants de matériaux et d'articles en contact avec les aliments, car elle leur permet de valider la conformité de leurs produits aux exigences de sécurité alimentaire. En somme, la norme CEN/TS 13130-10:2005 représente un cadre fiable et complet pour la gestion du risque lié à l'acrylamide dans les matériaux en contact avec les aliments.
CEN/TS 13130-10:2005 표준 문서는 식품과 접촉하는 재료 및 식품 시뮬란트에서의 아크릴아미드 측정을 위한 체계적인 접근 방식을 제시합니다. 이 표준의 범위는 다양한 식품 시뮬란트에서 아크릴아미드의 정량적 분석 절차를 명확히 규명하고 있으며, 이는 물, 3% w/v 아세트산, 15% v/v 에탄올 및 지방 시뮬란트에 적용됩니다. 아크릴아미드 모노머의 함량은 식품 시뮬란트 1kg당 밀리그램으로 표현되며, 측정 가능한 농도 범위는 0.01 mg/kg에서 0.1 mg/kg까지입니다. 이 표준의 강점 중 하나는 아크릴아미드의 정량적 측정이 정밀하고 재현 가능하다는 점입니다. 또한, 표준은 지방 시뮬란트에 대한 적용 가능성도 덧붙이고 있으며, 필요할 경우 해바라기유나 합성 트리글리세리드의 혼합물을 사용할 것을 권장하여 상충되는 간섭을 최적화할 수 있습니다. 이러한 점은 지방 시뮬란트의 적합성을 평가하는 과정에서 큰 장점으로 작용할 수 있습니다. CEN/TS 13130-10:2005는 특히 식품의 안전성과 품질 관리에 중대한 관련성을 가지며, 아크릴아미드와 같은 잠재적으로 유해한 물질의 안전성을 보장하기 위한 귀중한 도구가 됩니다. 따라서, 이 표준은 식품 산업 관계자 및 연구자들에게 필수적이며, 식품 시뮬란트 내 아크릴아미드의 모니터링을 통해 소비자의 건강을 보호하는 데 기여할 것입니다.
Die technische Spezifikation CEN/TS 13130-10:2005 behandelt Materialien und Artikel, die mit Lebensmitteln in Kontakt kommen, und behandelt insbesondere die Bestimmung von Acrylamid in Lebensmittelsimulanten. Diese Norm ist ein wichtiger Bestandteil der EN 13031 und legt ein analytisches Verfahren zur quantitativen Bestimmung von Acrylamid in verschiedenen Lebensmittelsimulanten fest, darunter Wasser, 3 % w/v Essigsäure, 15 % v/v Ethanol und Fett-Simulanten. Ein entscheidender Aspekt der Norm ist ihr Anwendungsbereich. Die Methode ist geeignet für die quantitative Bestimmung von Acrylamid in einem Konzentrationsbereich von etwa 0,01 mg/kg bis 0,1 mg/kg der Lebensmittelsimulanten. Dies stellt sicher, dass die Norm für eine Vielzahl von Anwendungen in der Lebensmittelindustrie relevant ist, da sie die sichere Nutzung von Materialien gewährleistet, die mit Lebensmitteln in Kontakt kommen. Die Stärken dieser Norm liegen in ihrer spezifischen und präzisen Analysemethodik. Die Möglichkeit, den Acrylamidgehalt präzise in Lebensmittelsimulanten zu bestimmen, ist von großem Wert für die Verbraucher- und Lebensmittelsicherheit. Darüber hinaus wird in der Norm darauf hingewiesen, dass die Eignung des Fett-Simulanten vor der Durchführung von Migrationstests bewertet werden sollte. Dies zeigt die Flexibilität und Anpassungsfähigkeit der Methode, um den unterschiedlichen Anforderungen der Produkte gerecht zu werden. Zusammenfassend kann gesagt werden, dass die CEN/TS 13130-10:2005 eine unverzichtbare Ressource für Fachleute in der Lebensmittelindustrie darstellt, die sicherstellen wollen, dass ihre Produkte den gesetzlichen Anforderungen bezüglich Acrylamid in Lebensmitteln entsprechen. Die Norm bekräftigt die Bedeutung der Sicherheit von Lebensmitteln und leistet einen bedeutenden Beitrag zur Wahrung des Verbraucherschutzes.
CEN/TS 13130-10:2005の文書は、食品と接触する材料および製品に関する重要な技術仕様であり、特にアクリルアミドの定量的測定に関する明確な分析手法を提供しています。この標準は、食品シミュラントとしての水、3% w/v水性酢酸、15% v/v水性エタノール、及び脂肪シミュラントを対象としています。この範囲内でのアクリルアミドモノマーのレベルは、ミリグラム/kgの食品シミュラントとして表現されます。 この技術仕様の強みは、0.01 mg/kgから0.1 mg/kgという広範なアナリート濃度範囲での定量的測定が可能である点です。この精度により、食品業界においてアクリルアミドのリスクを評価し、適切な対策を講じる上で不可欠な基準となります。また、アクリルアミドの評価にあたり、異なる脂肪シミュラントへの応用も考慮されており、柔軟性と汎用性を兼ね備えています。 さらに、脂肪シミュラントの適合性を評価する必要があり、特にオリーブオイルで悪影響を及ぼす場合には、ひまわり油や合成トリグリセリドの混合物を使用する可能性があります。この点も、アクリルアミドの測定精度に重大な影響を及ぼすため、重要な留意点です。 以上の理由から、CEN/TS 13130-10:2005は、食品業界における安全性基準を強化するために極めて重要な文書であり、アクリルアミドの監視および管理に関する適切な指針を提供しています。
The standard CEN/TS 13130-10:2005 offers a comprehensive framework for the determination of acrylamide in food simulants, a critical aspect in ensuring food safety and compliance with regulations. This Technical Specification is notable for its detailed analytical procedure, which enables accurate measurement of acrylamide levels in various food simulants such as water, aqueous acetic acid, aqueous ethanol, and fat simulants. The specified concentration range of 0.01 mg/kg to 0.1 mg/kg is particularly relevant for industries involved in food production and packaging, as it supports stringent quality control measures. One of the strengths of this standard is its flexibility in determining acrylamide concentrations, allowing for the assessment of other fat simulants beyond the initially tested options. This adaptability is crucial for manufacturers who may encounter unacceptable interferences with specific fats, such as olive oil. The guidance provided regarding the suitability of fat simulants ensures that migration tests yield reliable results, thereby reinforcing the standard's application across diverse food processing scenarios. The relevance of CEN/TS 13130-10:2005 extends beyond mere compliance. The ability to accurately assess acrylamide levels directly influences consumer safety and public health policies. As acrylamide is a recognized concern in the food industry, this standard plays a pivotal role in the ongoing effort to mitigate risks associated with foodstuffs in contact with plastic substances. Overall, the clarity and rigor of this standard underscore its importance in the specialized field of food safety, presenting a well-defined approach to managing acrylamide content in food packaging materials.
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