ASTM D7504-17
(Test Method)Standard Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography and Effective Carbon Number
Standard Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography and Effective Carbon Number
SIGNIFICANCE AND USE
5.1 Determining the type and amount of hydrocarbon impurities remaining from the manufacture of toluene, mixed xylenes, p-xylene, o-xylene, ethylbenzene, benzene, and styrene used as chemical intermediates and solvents is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used. Typical impurities are: alkanes containing 1 to 10 carbons atoms, benzene, toluene, ethylbenzene (EB), xylenes, and aromatic hydrocarbons containing nine carbon atoms or more.
5.2 This method may not detect all components and there may be unknown components that would be assigned inappropriate correction factors and thus, the results may not be absolute.
SCOPE
1.1 This test method covers the determination of total nonaromatic hydrocarbons and monocyclic aromatic hydrocarbons in benzene, toluene, ethylbenzene, p-xylene, o-xylene, styrene and mixed xylenes by gas chromatography. The purity of benzene, toluene, ethylbenzene, p-xylene, o-xylene, styrene and mixed xylenes is also calculated. Similar test methods, using the internal standard calibration technique and the external standard calibration technique, are Test Methods D2360, D3797, D4492, D5060, D5135, D5917, and D6563 respectively.
1.2 The limit of detection (LOD) is 0.0002 wt % and limit of quantitation (LOQ) is 0.0006 wt % for impurities in toluene, mixed xylenes, p-xylene, o-xylene, ethylbenzene, benzene, and styrene.
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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Designation: D7504 − 17
Standard Test Method for
Trace Impurities in Monocyclic Aromatic Hydrocarbons by
1
Gas Chromatography and Effective Carbon Number
This standard is issued under the fixed designation D7504; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 2. Referenced Documents
2
2.1 ASTM Standards:
1.1 This test method covers the determination of total
nonaromatic hydrocarbons and monocyclic aromatic hydrocar- D841 Specification for Nitration Grade Toluene
D1555M TestMethodforCalculationofVolumeandWeight
bons in benzene, toluene, ethylbenzene, p-xylene, o-xylene,
styrene and mixed xylenes by gas chromatography. The purity of Industrial Aromatic Hydrocarbons and Cyclohexane
[Metric]
of benzene, toluene, ethylbenzene, p-xylene, o-xylene, styrene
and mixed xylenes is also calculated. Similar test methods, D2360 Test Method for Trace Impurities in Monocyclic
Aromatic Hydrocarbons by Gas Chromatography (With-
using the internal standard calibration technique and the
3
external standard calibration technique, are Test Methods drawn 2016)
D3437 Practice for Sampling and Handling Liquid Cyclic
D2360, D3797, D4492, D5060, D5135, D5917, and D6563
respectively. Products
D3797 Test Method for Analysis of o-Xylene by Gas Chro-
1.2 The limit of detection (LOD) is 0.0002 wt % and limit
3
matography (Withdrawn 2014)
of quantitation (LOQ) is 0.0006 wt % for impurities in toluene,
D4492 Test Method for Analysis of Benzene by Gas Chro-
mixedxylenes, p-xylene, o-xylene,ethylbenzene,benzene,and
matography
styrene.
D4790 Terminology ofAromatic Hydrocarbons and Related
1.3 In determining the conformance of the test results using
Chemicals
this method to applicable specifications, results shall be
D5060 Test Method for Determining Impurities in High-
rounded off in accordance with the rounding-off method of
Purity Ethylbenzene by Gas Chromatography
Practice E29.
D5135 Test Method for Analysis of Styrene by Capillary
Gas Chromatography
1.4 The values stated in SI units are to be regarded as
D5136 Specification for High Purity p-Xylene
standard. No other units of measurement are included in this
D5211 Specification for Xylenes for p-Xylene Feedstock
standard.
D5917 Test Method for Trace Impurities in Monocyclic
1.5 This standard does not purport to address all of the
Aromatic Hydrocarbons by Gas Chromatography and
safety concerns, if any, associated with its use. It is the
External Calibration
responsibility of the user of this standard to establish appro-
D6229 Test Method for Trace Benzene in Hydrocarbon
priate safety and health practices and determine the applica-
Solvents by Capillary Gas Chromatography
bility of regulatory limitations prior to use.
D6563 Test Method for Benzene, Toluene, Xylene (BTX)
1.6 This international standard was developed in accor-
Concentrates Analysis by Gas Chromatography
dance with internationally recognized principles on standard-
D6809 Guide for Quality Control and Quality Assurance
ization established in the Decision on Principles for the
Procedures for Aromatic Hydrocarbons and Related Ma-
Development of International Standards, Guides and Recom-
terials
mendations issued by the World Trade Organization Technical
E29 Practice for Using Significant Digits in Test Data to
Barriers to Trade (TBT) Committee.
Determine Conformance with Specifications
E177 Practice for Use of the Terms Precision and Bias in
1
This test method is under the jurisdiction of ASTM Committee D16 on
2
Aromatic, Industrial, Specialty and Related Chemicals and is the direct responsi- For referenced ASTM standards, visit the ASTM website, www.astm.org, or
bility of Subcommittee D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Their Derivatives. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved April 1, 2017. Published April 2017. Originally the ASTM website.
3
approved in 2009. Last previous edition approved in 2016 as D7504 – 16. DOI: The last approved version of this historical standard is referenced on
10.1520/D7504-17. www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
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D7504 − 17
TABLE 1 Recommended Method Parameters
ASTM Test Methods
E260 Practice for Packed Column Gas Chromatography Inlet Split
Temperature, °C 270
E355 Practice for Gas ChromatographyTerms and Relation-
Co
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D7504 − 16 D7504 − 17
Standard Test Method for
Trace Impurities in Monocyclic Aromatic Hydrocarbons by
1
Gas Chromatography and Effective Carbon Number
This standard is issued under the fixed designation D7504; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This test method covers the determination of total nonaromatic hydrocarbons and monocyclic aromatic hydrocarbons in
benzene, toluene, ethylbenzene, p-xylene, o-xylene, styrene and mixed xylenes by gas chromatography. The purity of benzene,
toluene, ethylbenzene, p-xylene, o-xylene, styrene and mixed xylenes is also calculated. Similar test methods, using the internal
standard calibration technique and the external standard calibration technique, are Test Methods D2360, D3797, D4492, D5060,
D5135, D5917, and D6563 respectively.
1.2 A small amount of benzene in toluene, ethylbenzene, p-xylene, o-xylene, styrene and mixed xylenes may not be
distinguished from the non-aromatics and the concentrations are determined as a composite (see 6.1).
1.2 The limit of detection (LOD) is 0.0002 wt % and limit of quantitation (LOQ) is 0.0006 wt % for impurities in toluene, mixed
xylenes, p-xylene, o-xylene, ethylbenzene, benzene, and styrene.
1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded
off in accordance with the rounding-off method of Practice E29.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D841 Specification for Nitration Grade Toluene
D1555M Test Method for Calculation of Volume and Weight of Industrial Aromatic Hydrocarbons and Cyclohexane [Metric]
3
D2360 Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography (Withdrawn 2016)
D3437 Practice for Sampling and Handling Liquid Cyclic Products
3
D3797 Test Method for Analysis of o-Xylene by Gas Chromatography (Withdrawn 2014)
D4492 Test Method for Analysis of Benzene by Gas Chromatography
D4790 Terminology of Aromatic Hydrocarbons and Related Chemicals
D5060 Test Method for Determining Impurities in High-Purity Ethylbenzene by Gas Chromatography
D5135 Test Method for Analysis of Styrene by Capillary Gas Chromatography
D5136 Specification for High Purity p-Xylene
D5211 Specification for Xylenes for p-Xylene Feedstock
1
This test method is under the jurisdiction of ASTM Committee D16 on Aromatic Hydrocarbons Aromatic, Industrial, Specialty and Related Chemicals and is the direct
responsibility of Subcommittee D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives.
Current edition approved Aug. 1, 2016April 1, 2017. Published August 2016April 2017. Originally approved in 2009. Last previous edition approved in 20152016 as
ɛ1
D7504 – 15D7504 – 16. . DOI: 10.1520/D7504-16.10.1520/D7504-17.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
The last approved version of this historical standard is referenced on www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D7504 − 17
D5917 Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography and External
Calibration
D6229 Test Method for Trace Benzene in Hydrocarbon Solvents by Capillary Gas Chr
...
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