Standard Test Method for Testing Alkyd Compatibility with Resin or Resin Solutions

SIGNIFICANCE AND USE
5.1 Incompatibility of the system can lead to loss of gloss, decreased color strength, rheological problems and grind issues in the flush or pigment base.  
5.2 This method is used in the lithographic industry, especially in pigment wetting applications, where the alkyd may or may not be totally compatible with the resin selected for the application.
SCOPE
1.1 This test method covers the procedure for determining the degree of compatibility of an alkyd with a specific resin or resin solution.  
1.2 The most common use of this method is to test alkyd compatibility with a hydrocarbon resin or a solution of the resin in an aliphatic solvent, for lithographic ink vehicle applications.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-May-2020
Drafting Committee
D01.37 - Ink Vehicles

Relations

Effective Date
01-Jun-2020
Effective Date
01-Jul-2005
Effective Date
01-Jul-2005
Effective Date
01-Jan-1996

Overview

ASTM D6887-03(2020), titled "Standard Test Method for Testing Alkyd Compatibility with Resin or Resin Solutions," provides a systematic procedure to evaluate the compatibility of alkyds with specific resins or resin solutions. This standard is widely used in the lithographic ink industry to ensure that combinations of alkyds and resins result in stable, homogenous mixtures essential for optimal performance in pigment wetting and ink vehicle applications. Determining compatibility is crucial, as incompatibility can lead to several issues, including loss of gloss, decreased color strength, rheological problems, and grinding difficulties in pigment bases.

Key Topics

  • Purpose: Provides a test method for determining the degree of compatibility between alkyds and resins or their solutions, especially for use in lithographic ink vehicles.
  • Procedure Overview:
    • Specific resin-to-alkyd ratios are prepared and mixed in a controlled environment.
    • Mixtures are heated and then cooled to assess compatibility based on clarity and stability.
    • Observations are made at two intervals: after 30 minutes and after 24 hours.
  • Compatibility Definitions:
    • Compatibility: A resin and solvent mixture forms a clear, homogeneous, and stable solution.
    • Incompatibility: The mixture fails to form a clear, stable solution.
  • Significance: This test helps manufacturers avoid product failures caused by incompatible ink vehicles, leading to higher quality outputs and efficient pigment dispersion.
  • Safety and Compliance: Users must establish appropriate safety, health, and environmental practices, ensuring alignment with local regulations.

Applications

ASTM D6887-03(2020) is especially relevant for:

  • Lithographic Ink Manufacturing: Key for manufacturers selecting alkyd and resin (particularly hydrocarbon resin) blends for lithographic printing inks.
  • Pigment Wetting Applications: Ensures effective wetting and dispersion of pigments, resulting in improved color consistency and strength.
  • Quality Control in Coatings: Enables quality assurance teams to verify and document the compatibility of new resin/alkyd formulations before mass production.
  • Product Development: R&D teams use this standard to innovate and refine formulations in response to evolving industry needs or regulatory requirements.
  • Technical Assessments: Provides a consistent method for evaluating product performance and troubleshooting blending issues between alkyds and resin solutions in aliphatic solvents.

Related Standards

  • ASTM D6038: Test Methods for Determining the Compatibility of Resin/Solvent Mixtures by Precipitation Temperature (Cloud Point)
  • Other ASTM Ink and Coating Standards: Ensures comprehensive evaluation when paired with standards covering pigment dispersion, gloss, and rheology.
  • WTO TBT Principles: This standard was developed in compliance with internationally recognized principles for standardization, as set out by the World Trade Organization Technical Barriers to Trade Committee.

Practical Value

Implementing ASTM D6887-03(2020) helps ink and coating formulators to:

  • Reduce the risk of costly formulation errors by systematically screening resin-alkyd compatibility.
  • Maintain product excellence in color reproduction, gloss, and stability, critical in lithographic printing.
  • Uphold international quality assurance by referencing a widely recognized ASTM test method.
  • Streamline compliance with both industry best practices and regulatory requirements related to chemical safety and standardization.

Keywords: alkyd compatibility, resin solution, lithographic inks, pigment wetting, hydrocarbon resins, aliphatic solvents, ASTM D6887-03, ink vehicle quality, pigment dispersion, resin blend stability.

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Frequently Asked Questions

ASTM D6887-03(2020) is a standard published by ASTM International. Its full title is "Standard Test Method for Testing Alkyd Compatibility with Resin or Resin Solutions". This standard covers: SIGNIFICANCE AND USE 5.1 Incompatibility of the system can lead to loss of gloss, decreased color strength, rheological problems and grind issues in the flush or pigment base. 5.2 This method is used in the lithographic industry, especially in pigment wetting applications, where the alkyd may or may not be totally compatible with the resin selected for the application. SCOPE 1.1 This test method covers the procedure for determining the degree of compatibility of an alkyd with a specific resin or resin solution. 1.2 The most common use of this method is to test alkyd compatibility with a hydrocarbon resin or a solution of the resin in an aliphatic solvent, for lithographic ink vehicle applications. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

SIGNIFICANCE AND USE 5.1 Incompatibility of the system can lead to loss of gloss, decreased color strength, rheological problems and grind issues in the flush or pigment base. 5.2 This method is used in the lithographic industry, especially in pigment wetting applications, where the alkyd may or may not be totally compatible with the resin selected for the application. SCOPE 1.1 This test method covers the procedure for determining the degree of compatibility of an alkyd with a specific resin or resin solution. 1.2 The most common use of this method is to test alkyd compatibility with a hydrocarbon resin or a solution of the resin in an aliphatic solvent, for lithographic ink vehicle applications. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D6887-03(2020) is classified under the following ICS (International Classification for Standards) categories: 87.060.20 - Binders. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM D6887-03(2020) has the following relationships with other standards: It is inter standard links to ASTM D6887-03(2013), ASTM D6038-05e1, ASTM D6038-05, ASTM D6038-96. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM D6887-03(2020) is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D6887 − 03 (Reapproved 2020)
Standard Test Method for
Testing Alkyd Compatibility with Resin or Resin Solutions
This standard is issued under the fixed designation D6887; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 3.1.2 incompatibility, n—resin and solvent mixture does not
form a clear, homogenous, and stable solution.
1.1 This test method covers the procedure for determining
the degree of compatibility of an alkyd with a specific resin or
4. Summary of Test Method
resin solution.
4.1 The required resin to alkyd ratio is mixed into a 150-mL
1.2 The most common use of this method is to test alkyd
beaker and heated to 160°C until clear and homogenous.
compatibility with a hydrocarbon resin or a solution of the
4.2 The solution is placed into pre-labeled jars and cooled.
resin in an aliphatic solvent, for lithographic ink vehicle
applications.
4.3 Degree of compatibility is reported at 30 min and 24 h
after cooling to room temperature.
1.3 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this
5. Significance and Use
standard.
5.1 Incompatibility of the system can lead to loss of gloss,
1.4 This standard does not purport to address all of the
decreasedcolorstrength,rheologicalproblemsandgrindissues
safety concerns, if any, associated with its use. It is the
in the flush or pigment base.
responsibility of the user of this standard to establish appro-
5.2 This method is used in the lithographic industry, espe-
priate safety, health, and environmental practices and deter-
cially in pigment wetting applications, where the alkyd may or
mine the applicability of regulatory limitations prior to use.
may not be totally compatible with the resin selected for the
1.5 This international standard was developed in accor-
application.
dance with internationally recognized principles on standard-
ization established in the Decision on Principles for the
6. Apparatus
Development of International Standards, Guides and Recom-
6.1 Beakers, 150 mL (4).
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
6.2 Jars, with lids, 4 oz (4).
6.3 Balance, capacity of at least 200 g, accurate to 60.1 g.
2. Referenced Documents
6.4 Hot Plate, capable of heating to a minimum of 200°C.
2.1 ASTM Standards:
D6038 Test Methods for Determining the Compatibility of
6.5 Thermometer, 0 to 200°C, 61°C.
Resin/Solvent Mixtures by Precipitation Temperature
6.6 Spatula, or stirrer rods.
(Cloud Point)
7. Test Samples
3. Terminology
7.1 Alkyd to be tested.
3.1 Definitions:
7.2 Resin or resin solution.
3.1.1 compatibility, n—resin and solvent mixture forms a
clear, homogenous, and stable solution. D6038
8. Procedure
8.1 Label each jar and beaker with the resin, alkyd and ratio
This test method is under the jurisdiction of ASTM Committee D01 on Paint
being tested.
and Related Coatings, Materials, andApplications and is the direct responsibility of
8.2 Weigh into the beaker the following materials:
Subcommittee D01.37 on Ink Vehi
...

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