Standard Classification System for Polyamide Molding and Extrusion Materials (PA)

SCOPE
1.1 This classification system covers polyamide materials suitable for molding and extrusion. Some of these compositions are also suitable for application from solution.
1.2 This classification system allows for the use of recycled polyamide materials provided that the requirements as stated in this classification system are met. The proportions of recycled material used, as well as the nature and amount of any contaminant, however, cannot be covered practically in this specification.
1.3 The properties included in this classification system are those required to identify the compositions covered. There may be other requirements necessary to identify particular characteristics important to specialized applications. These may be specified by using the suffixes as given in Section 5.
1.4 This classification system and subsequent line callout (specification) are intended to provide a means of calling out plastic materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection should be made by those having expertise in the plastic field after careful consideration of the design and the performance required of the part, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherent properties of the material other than those covered by this classification system.
1.5 The values stated in SI units are to be regarded as the standard.
1.6 The following precautionary caveat pertains only to the test methods portion, Section 11, of this classification system. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to use.
Note 1—This classification system is similar to ISO 1874-1/-2 1993, although the technical content is significantly different.

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NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 6779 – 02
Standard Classification System for
Polyamide Molding and Extrusion Materials (PA)
This standard is issued under the fixed designation D 6779; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope D 257 Test Methods for D-C Resistance or Conductance of
Insulating Materials
1.1 This classification system covers polyamide materials
D 789 Test Methods for Determination of Relative Viscos-
suitable for molding and extrusion. Some of these composi-
ity and Moisture Content of Polyamide (PA)
tions are also suitable for application from solution.
D 792 Test Methods for Density and Specific Gravity (Rela-
1.2 This classification system allows for the use of recycled
tive Density) of Plastics by Displacement
polyamide materials provided that the requirements as stated in
D 883 Terminology Relating to Plastics
this classification system are met. The proportions of recycled
D 1600 Terminology for Abbreviated Terms Relating to
material used, as well as the nature and amount of any
Plastics
contaminant, however, cannot be covered practically in this
D 3892 Practice for Packaging/Packing of Plastics
specification.
D 4000 Classification System for Specifying Plastic Mate-
1.3 The properties included in this classification system are
rials
those required to identify the compositions covered. There may
D 6260 Test Method for Gravimetric Determination of Car-
be other requirements necessary to identify particular charac-
bon Black in Nylon Materials (PA)
teristics important to specialized applications. These may be
E 29 Practice for Using Significant Digits in Test Data to
specified by using the suffixes as given in Section 5.
Determine Conformance with Specifications
1.4 This classification system and subsequent line callout
2.2 IEC/ISO Standards:
(specification) are intended to provide a means of calling out
IEC 60243-1:1998 Electrical Strength of Insulating
plastic materials used in the fabrication of end items or parts.
Materials—Test Methods—Part 1: Tests at Power Fre-
It is not intended for the selection of materials. Material
quencies
selection should be made by those having expertise in the
IEC 60250:1969 Recommended Methods for the Determi-
plastic field after careful consideration of the design and the
nation of the Permittivity and Dielectric Dissipation Fac-
performance required of the part, the environment to which it
tor of Electrical Insulating Materials at Power, Audio and
will be exposed, the fabrication process to be employed, the
Radio Frequencies Including Metre Wavelengths
costs involved, and the inherent properties of the material other
ISO 75-1:1993 Plastics—Determination of Temperature of
than those covered by this classification system.
Deflection Under Load—Part 1: General Test Methods
1.5 The values stated in SI units are to be regarded as the
ISO 75-2:1993 Plastics—Determination of Temperature of
standard.
Deflection Under Load—Part 2: Plastic and Ebonite
1.6 The following precautionary caveat pertains only to the
ISO 179-1:2000 Plastics—Determination of Charpy Impact
test methods portion, Section 11, of this classification system.
Strength—Part 1: Non-instrumented Impact Test
This standard does not purport to address all of the safety
ISO 294-1:1996 Plastics—Injection Moulding of Test
concerns, if any, associated with its use. It is the responsibility
Specimens of Thermoplastic Materials—Part 1: General
of the user of this standard to establish appropriate safety and
Principles, Multipurpose-Test Specimens and Bars
health practices and determine the applicability of regulatory
ISO 307:1994 Determination of Viscosity Number of Polya-
requirements prior to use.
mides In Dilute Solutions
NOTE 1—This classification system is similar to ISO 1874-1/-2 1993,
ISO 527-1:1993 Plastics—Determination of Tensile
although the technical content is significantly different.
Properties—Part 1: General Principles
ISO 527-2:1993 Plastics—Determination of Tensile
2. Referenced Documents
2.1 ASTM Standards:
Annual ASTM Book of Standards, Vol 10.01.
Annual ASTM Book of Standards, Vol 08.01.
Annual ASTM Book of Standards, Vol 08.02.
1 5
This classification is under the jurisdiction of ASTM Committee D20 on Annual ASTM Book of Standards, Vol 08.03.
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic Annual ASTM Book of Standards, Vol 14.02.
Materials (Section D20.15.09). Available from American National Standards Institute, 25 W. 43rd St., 4th
Current edition approved March 10, 2002. Published May 2002. Floor, New York, NY 10036.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 6779
Properties—Part 2: Testing Conditions
PA = polyamide as found in Terminology D 1600,
ISO 1183:1987 Plastics—Methods for Determining the
01 (group) = polyamide 66,
Density and Relative Density of Non-Cellular Plastics 2 (class) = heat stabilized, and
ISO 1874-1:1992 Plastics—Polyamide (PA) Homopoly- G35 (grade) = nominal 35 % glass with the requirements
mers and Copolymers for Moulding and Extrusion—Part given in Table PA.
1: Designation
NOTE 4—This part of the classification system uses percent of rein-
ISO 1874-2.2:1996 Plastics—Polyamide (PA) Homopoly-
forcements or additives, or both, in the callout of the modified basic
mers and Copolymers for Moulding and Extrusion—Part
material. The types and percentages of reinforcements and additives
2: Preparation of Test Specimens and Determination of should be shown on the supplier’s technical data sheet unless they are
proprietary in nature. If necessary, additional control of these reinforce-
Properties
ments and additives can be accomplished by use of the suffix part of the
ISO 3167 Plastics, Multipurpose Test Specimens
system (see Section 5).
ISO 3451-4:1998 Plastics—Determination of Ash—Part 4:
NOTE 5—Materials containing reinforcements or fillers, or both, at
Polyamides
nominal levels not in multiples of 5 are included in the nearest PA grade
ISO 11357-1:1997 Plastics—Differential Scanning
designation. For example, a material with a nominal glass fiber level of
Calorimetry—Part 1: General Principles
33 % is included with Grade G35 as shown in Note 4.
ISO 11357-3:1999 Plastics—Differential Scanning
NOTE 6—Ash content of filled or reinforced materials may be deter-
mined using Test Method ISO 3451-4.
Calorimetry—Part 3: Determination of Temperature and
Enthalpy of Melting and Crystallization
4.2 Variations of polyamide materials that are not in Table
ISO 15512:1999 Plastics—Determination of Water Content
PA are classified in accordance with Tables PA and A or B.
Table PA is used to specify the group of polyamide and Table
3. Terminology
A or B is used to specify property requirements.
3.1 The terminology used in this classification system is in
4.2.1 Specific requirements for variations of polyamide
accordance with Terminologies D 883 and D 1600.
materials shall be shown by a six-character designator. The
designation will consist of the letter “A” or “B” and the five
4. Classification
digits comprising the cell numbers for the property require-
4.1 Polyamide materials are classified into groups in accor-
ments in the order as they appear in Tables A and B.
dance with their composition. These groups are subdivided into
4.2.1.1 Although the values listed are necessary to include
classes and grades as shown in the Basic Property Table (Table
the range of properties available in existing material, users
PA).
should not infer that every possible combination of the
properties exists or can be obtained.
NOTE 2—An example of this classification system for unreinforced
4.2.2 When the grade of the basic material is not known, is
polyamide is given as follows: The designation PA0123 indicates the
following: not important or does not meet the Table PA requirements, the
use of “0” grade classification shall be used for reinforced
materials in this classification system.
PA = polyamide as found in Terminology D 1600,
NOTE 7—An example of this classification system for a reinforced
01 (group) = polyamide 66,
polyamide material is given as follows. The designation
2 (class) = heat stabilized, and
PA0110G30A42270 would indicate the following material requirements:
3 (grade) = with a minimum viscosity number of 210 and
the requirements given in Table PA.
4.1.1 Grades of reinforced or filled versions, or both, of the
PA0110 = Polyamide 66, from Table PA,
basic materials are identified by a single letter that indicates the
G30 = Glass reinforced at 30 % nominal,
reinforcement or filler used and two digits, in multiples of 5,
A = Table A property requirements,
that indicate the nominal quantity in percent by weight. Thus,
4 = Tensile strength, 140 MPa, min,
a letter designation G for glass reinforced and 35 for percent or
2 = Tensile modulus, 4500 MPa, min,
reinforcement, G35, specifies a material with a nominal glass 2 = Charpy impact, 5.0 kJ/m , min,
7 = Deflection temperature at 1.8 MPa, 200°C, min,
level of 35 %. The reinforcement letter designations and
associated tolerance levels are shown as follows: and
0 = Unspecified.
Tolerance
Symbol Material
(Based on the Total Mass)
If no properties are specified, the designation would be
C carbon- and graphite-fiber-reinforced 62%
PA0110G30A00000.
G glass-reinforced 62%
L lubricants (such as PTFE, graphite, Depends upon material and
NOTE 8—When a grade of polyamide is not fully identified by a
silicone, and molybdenum disulfide) process—to be specified.
standard callout, it is possible to specify all table properties by the use of
M mineral-reinforced 62%
an addition of Classification D 4000 suffixes. Suffix values will override
R combinations of reinforcements or 63%
the PA table values. An example of an unreinforced polyamide material is
fillers, or both
given as follows: PA0212KN023. This example is a general purpose, low
NOTE 3—An example of this classification system for reinforced
viscosity PA6 material where K denotes tensile properties, N denotes
polyamide is given as follows: The designation PA012G35 indicates the
tensile modulus with ISO 527 as the test method, and 023 denotes a value
following:
of 2300 MPa. This value for tensile modulus overrides the normal table
value. This example can be applied to replace all table values, that is,
tensile stress, notched Charpy impact, and heat deflection temperature.
NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 6779
4.3 To facilitate the specification of special materials where
the basic property table does not reflect the properties required,
PA0220 = Polyamide 6, heat stabilized, from Table PA,
Table B has been incorporated into this classification system. B = Table B property requirements,
This table will be used in a manner similar to Table A. 5 = Tensile strength, 70 MPa, min,
4 = Tensile modulus, 2400 MPa, min,
NOTE 9—Pigmented or colored polyamides can differ significantly 2
2 = Charpy impact, 4.0 kJ/m , min,
from the natural polymers in mechanical properties depending on the
2 = Deflection temperature at 1.8 MPa, 55°C, min,
choice of colorants and concentrations. The main property affected is
and
ductility, as illustrated by a reduction in Charpy impact and elongation
0 = unspecified.
values. In a typical white pigmented polyamide, elongation losses of up to
50 % and Charpy impact losses of up to 30 % are common. If specific
properties of pigmented materials are necessary, Table B may be em-
ployed to specify property requirements.
NOTE 10—An example of a special material using this classification
system is as follows: The designation PA0220B54220 would indicate the
following material requirements from Table B:
A,B
TABLE PA Requirements for Polyamides Dry-as-Molded
Deflection
Tensile Tensile Charpy
F
Temperature,
E
Viscosity Strength, Modulus, Impact
D
Density, ISO 75-1
Number, ISO 527-1 ISO 527-1 Resistance,
C
Group Description Class Description Grade Description ISO 1183 and
ISO 307, and and ISO 179/
g/cm ISO 75-2,
min, mL/g ISO 527-2, ISO 527-2, 1eA, kJ/m ,
at 1.8 MPa,
MPa, min MPa, min min
°C, min
01 PA66 1 General- 1 135 1.13 to 1.15 70 2300 3.3 60
purpose 2 165 1.13 to 1.15 70 2300 3.3 60
3 210 1.13 to 1.15 70 2300 3.3 60
4 270 1.13 to 1.15 70 2300 3.3 60
5 recycled 115 1.13 to 1.15 70 2300 3.3 60
6 recycled 135 1.13 to 1.15 70 2300 3.3 60
G15 15 % glass . . . 1.20 to 1.26 100 4000 3.0 215
G20 20 % glass . . . 1.25 to 1.33 115 5000 4.0 220
G25 25 % glass . . . 1.29 to 1.37 140 6000 5.0 225
G35 35 % glass . . . 1.35 to 1.45 170 8000 7.0 235
G40 40 % glass . . . 1.42 to 1.52 175 9000 8.0 235
G45 45 % glass . . . 1.45 to 1.55 180 10 000 9.0 240
M40 40 % mineral . . . 1.45 to 1.55 80 5000 2.0 100
0 other
2 Heat- 1 135 1.13 to 1.15 70 2300 3.0 60
stabilized 2 165 1.13 to 1.15 70 2300 3.0 60
3 210 1.13 to 1.15 70 2300 3.0 60
4 270 1.13 to 1.15 70 2300 3.0 60
5 recycled 115 1.13 to 1.15 70 2300 3.0 60
6 recycled 135 1.13 to 1.15 70 2300 3.0 60
G15 15 % glass . . . 1.20 to 1.26 100 4000 3.0 220
G25 25 % glass . . . 1.29 to 1.37 140 6000 5.0 225
G30 30 % glass . . . 1.32 to 1.42 160 7000 6.0 230
G35 35 % glass . . . 1.35 to 1.45 170 8000 7.0 235
G40 40 % glass . . . 1.43 to 1.53 175 9000 8.0 235
G45 45 % glass . . . 1.45 to 1.55 180 10 000 9.0 240
M40 40 % mineral . . . 1.45 to 1.55 80 5000 2.0 100
R20 20 % filler . . . 1.23 to 1.31 70 3200 1.5 . . .
R40 40 % filler . . . 1.43 to 1.53 100 5500 2.5 200
0 other
3 Nucleated 1 135 1.13 to 1.15 80 2500 2.8 60
2 165 1.13 to 1.15 80 2500 2.8 60
3 210 1.13 to 1.15 80 2500 2.8 60
4 270 1.13 to 1.15 80 2500 2.8 60
5 recycled 115 1.13 to 1.15 80 2500 2.8 60
6 recycled 135 1.13 to 1.15 80 2500 2.8 60
0 other
4 Nucleated, 1 Requirements the same as corresponding grades under Group 01, Class 3
heat- 2
stabilized 3
0 other
5 Impact- 1 . . . 1.06 to 1.12 52 1700 9.0 50
modified 2 recycled . . . 1.06 to 1.12 50 1600 8.0 50
G15 15 % glass . . . 1.15 to 1.23 85 3000 6.0 210
G35 35 % glass . . . 1.31 to 1.41 110 5500 6.0 225
0 other
NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
D 6779
A,B
...

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