ASTM D6065-21
(Practice)Standard Practice for Handling, Transportation, and Storage of HFC-227ea 1,1,1,2,3,3,3-Heptafluoropropane (CF3CHFCF3)
Standard Practice for Handling, Transportation, and Storage of HFC-227ea 1,1,1,2,3,3,3-Heptafluoropropane (CF<inf>3</inf>CHFCF<inf>3</inf>)
SIGNIFICANCE AND USE
4.1 This practice provides requirements for the handling, transportation, and storage of HFC-227ea encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-227ea is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air.
SCOPE
1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of HFC-227ea.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
- Status
- Published
- Publication Date
- 31-May-2021
- Technical Committee
- D26 - Halogenated Organic Solvents and Fire Extinguishing Agents
- Drafting Committee
- D26.09 - Fire Extinguishing Agents
Relations
- Effective Date
- 01-Aug-2011
- Effective Date
- 10-Jun-2003
- Effective Date
- 01-Jan-1996
Overview
ASTM D6065-21, titled Standard Practice for Handling, Transportation, and Storage of HFC-227ea (1,1,1,2,3,3,3-Heptafluoropropane; CF₃CHFCF₃), provides comprehensive requirements to guide suppliers, reclaimers, purchasers, and users involved with HFC-227ea. This international standard ensures that HFC-227ea maintains its integrity and effectiveness throughout its lifecycle in both commercial and military supply chains. By following this practice, organizations can safeguard the physical properties of HFC-227ea as it is handled, transported, and stored by land, sea, rail, or air. The standard underscores the importance of proper training, compliance with related regulatory documents, and robust safety, health, and environmental practices when working with this critical fire suppressant and explosion hazard mitigation agent.
Key Topics
- Personnel Training
- Personnel involved in handling, transporting, or storing HFC-227ea must be trained according to Compressed Gas Association (CGA) publications and the relevant sections of Title 49 CFR.
- Handling Guidance
- Proper recognition of the characteristics of HFC-227ea and safe handling of full, partial, and empty cylinders is required.
- Transfers between storage and recycling processes should only be performed by trained staff, in ventilated, heater-free, nonsmoking conditions.
- Cylinders must not be overfilled as stipulated by DOT and ASTM requirements to prevent pressure or thermal hazards.
- Transportation Requirements
- Shipment of HFC-227ea must comply with Department of Transportation (DOT) regulations, using approved containers and marking systems.
- Protective measures must be in place to prevent cylinder damage from vibration, shock, freezing, or excessive heat during transport.
- Storage Practices
- Storage must follow CGA guidance and DOT requirements, ensuring protection from physical and environmental damage.
- Pressure-release mechanisms and clear labeling are mandated to promote both safety and regulatory compliance.
- Segregation of conforming and non-conforming product must be practiced in shared storage environments.
- Inspection and Reclamation
- Reclaimed HFC-227ea released for reissue must pass validation tests to confirm compliance with HFC-227ea specifications.
Applications
- Fire Suppression Systems
HFC-227ea (commercially known as FM-200® or FE-227™) is widely used as a clean agent fire suppressant in data centers, telecommunication facilities, museums, and many other high-value environments. - Explosion Hazard Mitigation
As an inerting agent, HFC-227ea is utilized to suppress explosion hazards in military, industrial, and commercial settings. - Regulated Shipping and Logistics
Organizations handling the interstate or international distribution of HFC-227ea use this standard to ensure compliant packaging, labeling, and transportation across various modes. - Recycling and Reclamation Operations
Programs for the recovery and recycling of halocarbons benefit from standardized protocols that safeguard both personnel and product purity.
Related Standards
- ASTM D6064 - Specification for HFC-227ea, 1,1,1,2,3,3,3-Heptafluoropropane
Defines purity and quality criteria for HFC-227ea. - CGA C-1, C-6, C-7, P-1, SB-1, SB-5, SB-18
CGA publications provide guidance on hydrostatic testing, visual inspection, labeling, and safe handling of compressed gas cylinders. - 49 CFR Parts 172, 173, 178, 180
U.S. Department of Transportation regulations governing hazardous materials, container specifications, and shipping requirements. - 40 CFR Part 82.106
EPA labeling requirements for hazardous materials related to ozone-depleting substances.
Keywords: HFC-227ea, heptafluoropropane, FM-200, fire suppressant, explosion suppressant, compressed gas, cylinder handling, hazardous material transport, ASTM D6065-21, storage safety, halocarbon recovery, DOT regulations, CGA, reclamation, recycling.
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ASTM D6065-21 - Standard Practice for Handling, Transportation, and Storage of HFC-227ea 1,1,1,2,3,3,3-Heptafluoropropane (CF<inf>3</inf>CHFCF<inf>3</inf>)
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Frequently Asked Questions
ASTM D6065-21 is a standard published by ASTM International. Its full title is "Standard Practice for Handling, Transportation, and Storage of HFC-227ea 1,1,1,2,3,3,3-Heptafluoropropane (CF<inf>3</inf>CHFCF<inf>3</inf>)". This standard covers: SIGNIFICANCE AND USE 4.1 This practice provides requirements for the handling, transportation, and storage of HFC-227ea encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-227ea is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air. SCOPE 1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of HFC-227ea. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
SIGNIFICANCE AND USE 4.1 This practice provides requirements for the handling, transportation, and storage of HFC-227ea encountered in distribution through both commercial and military channels. It is intended to ensure that HFC-227ea is handled, transported, and stored in such a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway, rail, water, and air. SCOPE 1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and storage of HFC-227ea. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
ASTM D6065-21 is classified under the following ICS (International Classification for Standards) categories: 13.220.10 - Fire-fighting. The ICS classification helps identify the subject area and facilitates finding related standards.
ASTM D6065-21 has the following relationships with other standards: It is inter standard links to ASTM D6064-11, ASTM D6064-03, ASTM D6064-96. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
ASTM D6065-21 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D6065 −21
Standard Practice for
Handling, Transportation, and Storage of HFC-227ea
1,1,1,2,3,3,3-Heptafluoropropane (CF CHFCF )
3 3
This standard is issued under the fixed designation D6065; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope P-1 Standard for Safe Handling of Compressed Gases in
Containers
1.1 This practice covers guidance and direction to suppliers,
SB-1 Hazards of Refilling or Reusing Compressed Refriger-
reclaimers, purchasers, and users in the handling,
ant (Halogenated Hydrocarbon) Gas Cylinders
transportation, and storage of HFC-227ea.
SB-5 Hazards of Reusing Disposable Refrigerant (Haloge-
1.2 The values stated in inch-pound units are to be regarded
nated Hydrocarbon) Gas Cylinders
as standard. The values given in parentheses are mathematical
SB-18 Use of Refrigerant (Halogenated Hydrocarbons) Re-
conversions to SI units that are provided for information only
covery Cylinders
and are not considered standard. 4
2.3 U.S. Government Standards:
1.3 This standard does not purport to address all of the 49 CFR Part 172 Hazardous Materials Table, Special
safety concerns, if any, associated with its use. It is the
Provisions, Hazardous Materials Communications, Emer-
responsibility of the user of this standard to establish appro- gency Response Information, Training Requirements, and
priate safety, health, and environmental practices and deter-
Security Plans
mine the applicability of regulatory limitations prior to use. 49 CFR Part 172.101 Purpose and Use of Hazardous Mate-
1.4 This international standard was developed in accor-
rials Table
dance with internationally recognized principles on standard- 49 CFR Part 173 Shippers—General Requirements for Ship-
ization established in the Decision on Principles for the
ments and Packagings
Development of International Standards, Guides and Recom- 49 CFR Part 178 Specifications for Packagings
mendations issued by the World Trade Organization Technical
49 CFR Part 180 Continuing Qualification and Maintenance
Barriers to Trade (TBT) Committee. of Packagings
2. Referenced Documents
3. Terminology
2.1 ASTM Standard:
3.1 Definitions of Terms Specific to This Standard:
D6064 Specification for HFC-227ea, 1,1,1,2,3,3,3-
3.1.1 containers, n—storage vessels for HFC-227ea.
Heptafluoropropane (CF CHFCF )
3 3
3.1.2 cylinders, n—containers of HFC-227ea.
2.2 CGA Standards:
3.1.3 HFC-227ea, n—1,1,1,2,3,3,3-Heptafluoropropane; a
C-1 Methods for Pressure Testing Compressed Gas Cylin-
compound used to inert or suppress a fire or explosion hazard.
ders
3.1.4 insulated, adj—placed in an isolated situation to pro-
C-6 Standards for Visual Inspection of Steel Compressed
tect and prevent the transfer of damage.
Gas Cylinders
C-7 Guide to Classification and Labeling of Compressed
4. Significance and Use
Gases
4.1 This practice provides requirements for the handling,
transportation, and storage of HFC-227ea encountered in
This practice is under the jurisdiction of ASTM Committee D26 on Haloge-
distribution through both commercial and military channels. It
nated Organic Solvents and Fire Extinguishing Agents and is the direct responsi-
bility of Subcommittee D26.09 on Fire Extinguishing Agents.
is intended to ensure that HFC-227ea is handled, transported,
Current edition approved June 1, 2021. Published June 2021. Originally
and stored in such a way that its physical property virtues are
approved in 1996. Last previous edition approved in 2015 as D6065 – 11 (2015).
not degraded. Transport may be by various means, such as, but
DOI: 10.1520/D6065-21.
not limited to, highway, rail, water, and air.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. Code of Federal Regulations (CFR) documents are available from U.S.
Available from Compressed GasAssociation, 8484 Westpark Drive, Suite 220, Government Publishing Office (GPO), 732, N. Capitol St., NW, Washington, DC
McLean, VA 22102, http://www.cganet.com. 20401-0001, http://www.gpo.gov.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D6065 − 21
5. Practice nitrogen to 360 psig (25.8 bar) at 70 °F (21 °C) shall be 72
3 3
lb/ft (1153 kg/m ). The maximum filling density for HFC-
5.1 To ensure safe handling, loading, unloading, storing,
227ea super pressurized with nitrogen to 600 psig (42.4 bar) at
and transporting of material, personnel shall be trained in the
70 °F shall be 68 lb/ft . Filling density requirements are
CGApublications and CFR regulations as listed in 2.2 and 2.3,
specified in 49 CFR Part 173.304 and 49 CFR Part 173.305.
respectively.
5.2.6 Handling of materials should be done in a manner that
5.2 Handling:
prevents contamination or comingling of materials other than
5.2.1 Handling shall be in accordance with CGA Publica-
HFC-227ea.
tion P-1 and as specified by the manufacturer.
5.2.7 Cylinders shall be free of dirt and contamination that
5.2.1.1 Personnel who handle or store, or both, cylinders of
would contribute to or would cause deterioration of product
HFC-227ea shall be trained properly to recognize and identify
during shipment or storage. Precautions should be taken to
the characteristics of the product and the proper methods of
prevent the entry of oil, water, or any other foreign matter into
safely handling full, partially full, and empty cylinders.
containers. Unique coatings or preservatives applied prior to
5.2.2 All HFC-227ea transfers between storage containers
shipment to protect the containers are not considered contami-
and recycling processes shall be performed by personnel
nation.
trained in
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D6065 − 11 (Reapproved 2015) D6065 − 21
Standard Practice for
Handling, Transportation, and Storage of HFC-227ea
1,1,1,2,3,3,3-Heptafluoropropane (CF CHFCF )
3 3
This standard is issued under the fixed designation D6065; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This practice covers guidance and direction to suppliers, reclaimers, purchasers, and users in the handling, transportation, and
storage of HFC-227ea.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical
conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2.1 ASTM Standards:Standard:
D6064 Specification for HFC-227ea, 1,1,1,2,3,3,3-Heptafluoropropane (CF CHFCF )
3 3
2.2 CGA Standards:
C-1 Methods for HydrostaticPressure Testing of Compressed Gas Cylinders
C-6 Standards for Visual Inspection of Steel Compressed Gas Cylinders
C-7 Guide to Preparation of Precautionary Labeling and Marking of Compressed Gas ContainersClassification and Labeling of
Compressed Gases
P-1 Standard for Safe Handling of Compressed Gases in Containers
SB-1 Hazards of Refilling or Reusing Compressed Refrigerant (Halogenated Hydrocarbon) Gas Cylinders
SB-5 Hazards of Reusing Disposable Refrigerant (Halogenated Hydrocarbon) Gas Cylinders
SB-18 Use of Refrigerant (Halogenated Hydrocarbons) Recovery Cylinders
This practice is under the jurisdiction of ASTM Committee D26 on Halogenated Organic Solvents and Fire Extinguishing Agents and is the direct responsibility of
Subcommittee D26.09 on Fire Extinguishing Agents.
Current edition approved June 1, 2015June 1, 2021. Published June 2015June 2021. Originally approved in 1996. Last previous edition approved in 20112015 as
D6065 – 11.D6065 – 11 (2015). DOI: 10.1520/D6065-11R15.10.1520/D6065-21.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’sstandard’s Document Summary page on the ASTM website.
Available from Compressed Gas Association, 14501 George Carter Way, Suite 103, Chantilly VA 20151-1788,8484 Westpark Drive, Suite 220, McLean, VA 22102,
http://www.cganet.com.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D6065 − 21
2.3 U.S. Government Standards:
49 CFR Part 172 Hazardous Materials Table, Special Provisions, Hazardous Materials Communications, Emergency Response
Information, Training Requirements, and Security Plans
Code of Federal Regulations (CFR) Title 40,49 CFR Part 172.101 Part 82.106Purpose and Use of Hazardous Materials Table
Code of Federal Regulations (CFR) Title 49,49 CFR Part 173 Part 173, U.S. Department of Transportation (DOT) Specifications,
Shippers-General Requirements for ShippingShippers—General Requirements for Shipments and Packagings
Code of Federal Regulations (CFR) Title 49,49 CFR Part 178 Part 178, U.S. DOT Specifications, Specifications for Packagings
Code of Federal Regulations (CFR) Title 49,49 CFR Part 180 Part 180, U.S. DOT, Continuing QualificationsContinuing
Qualification and Maintenance of Packagings
3. Terminology
3.1 Definitions of Terms Specific to This Standard:
3.1.1 containers—containers, n—storage vessels for HFC-227ea.
3.1.2 cylinders—cylinders, n—containers of HFC-227ea.
3.1.3 HFC-227ea—HFC-227ea, n—1,1,1,2,3,3,3-Heptafluoropropane; a compound used to inert or suppress a fire or explosion
hazard.
3.1.4 insulated—insulated, adj—placed in an isolated situation to protect and prevent the transfer of damage.
4. Significance and Use
4.1 This practice provides requirements for the handling, transportation, and storage of HFC-227ea encountered in distribution
through both commercial and military channels. It is intended to ensure that HFC-227ea is handled, transported, and stored in such
a way that its physical property virtues are not degraded. Transport may be by various means, such as, but not limited to, highway,
rail, water, and air.
5. Practice
5.1 To ensure safe handling, loading, unloading, storing, and transporting of material, personnel shall be trained in the CGA
publications and Title 49 CFR regulations as listed in 2.2 and 2.3, respectively.
5.2 Handling:
5.2.1 Handling shall be in accordance with CGA Publication No. P-1, P-1 and as specified by the manufacturer.
5.2.1.1 Personnel who handle or store, or both, cylinders of HFC-227ea shall be trained properly to recognize and identify the
characteristics of the product and the proper methods of safely handling full, partially full, and empty cylinders.
5.2.2 All HFC-227ea transfers between storage containers and recycling processes shall be performed by personnel trained in
handling procedures.
5.2.3 The HFC-227ea recycling and transfer processes shall be in conjunction with the equipment specified by the manufacturer.
5.2.4 HFC-227eaThe handling of HFC-227ea shall be in nonsmoking, heater-free, ventilated areas to preclude product
accumulation. Provisions shall be made to ensure that service areas limit area HFC-227ea concentrations do not exceed 10.5 %
for 1 min and 0.1 % for 8 h.
5.2.5 Cylinders shall not be overfilled. The liquid portion of the liquefied gases must not completely fill the container’scontainer’s
internal volume at any temperature up to and including 130°F (54°C).130 °F (54 °C). The maximum permitted filling density for
3 3
pure HFC-227ea shall be 79 lb/ft (1265 kg/m ). The maximum permitted filling density for HFC-227ea super pressurized with
3 3
nitrogen to 600360 psig (25.8 bar) at 70°F (21°C)70 °F (21 °C) shall be 72 lb/ft (1153 kg
...
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