Standard Specification for Zinc-Aluminum Alloys in Ingot Form for Hot-Dip Coatings

ABSTRACT
This specification covers three types of zinc-aluminum (Zn-Al) alloys in ingot form for re-melting for use in the production of hot-dip coatings on steel: Type 5 (95/5 Zn/Al), Type 10 (90/10 Zn/Al), and Type 15 (85/15 Zn/Al). Requirements prescribed by this specification cover ordering information; chemical, physical, and mechanical requirements; sampling for determination of chemical composition; methods for chemical analysis; material and manufacturing requirements; dimensions, mass, shapes, and sizes; workmanship, finish, and appearance; inspection and certification; product and package marking; and packaging and preparation for delivery.
SCOPE
1.1 This specification covers certain zinc-aluminum (Zn-Al) alloys in ingot form for re-melting for use in the production of hot-dip coatings on steel. Alloy compositions are specified below and in Table 1.    
ASTM  
Common  
UNS  
Type 5  
95/5 Zn/Al  
Z30507  
Type 10  
90/10 Zn/Al  
Z30600  
Type 15  
85/15 Zn/Al  
Z30706
Note 1: The zinc-aluminum alloys in Specification B997 are intended to be used primarily to create a molten zinc-aluminum bath and differ from the master alloys in Specification B860 which are intended primarily to adjust the concentration of certain elements in molten zinc galvanizing baths.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
31-Oct-2021
Drafting Committee
B02.04 - Zinc and Cadmium

Relations

Effective Date
01-Jun-2017
Effective Date
01-Oct-2016
Effective Date
01-May-2016
Effective Date
01-Oct-2015
Effective Date
01-Oct-2015
Effective Date
01-Jun-2015
Effective Date
01-Oct-2014
Effective Date
01-Aug-2013
Effective Date
01-Feb-2013
Effective Date
01-Feb-2013
Effective Date
01-May-2012
Effective Date
01-Oct-2009
Effective Date
01-Oct-2009
Effective Date
01-Oct-2009
Effective Date
01-Oct-2009

Overview

ASTM B997-16(2021), Standard Specification for Zinc-Aluminum Alloys in Ingot Form for Hot-Dip Coatings, establishes requirements for three specific types of zinc-aluminum (Zn-Al) alloys in ingot form for re-melting. These ingots are primarily used to create molten baths for hot-dip coatings on steel, offering enhanced protection and improved performance over pure zinc coatings. The standard defines alloy compositions, chemical and mechanical properties, sampling procedures, as well as requirements for packaging and marking, ensuring consistent quality throughout the industry.

Developed by ASTM International, this standard supports the needs of manufacturers, galvanizers, and quality assurance specialists involved in the production of hot-dip coated steel products. Compliance with ASTM B997 helps ensure that Zn-Al alloy ingots meet internationally recognized principles and requirements for performance and safety.

Key Topics

Alloy Types & Compositions

  • Type 5 (95/5 Zn/Al, UNS Z30507): 95% zinc, 5% aluminum.
  • Type 10 (90/10 Zn/Al, UNS Z30600): 90% zinc, 10% aluminum.
  • Type 15 (85/15 Zn/Al, UNS Z30706): 85% zinc, 15% aluminum.

Requirements Covered

  • Chemical Composition: Strict limits on lead, cadmium, tin, iron, silicon, and optional specifications for trace elements to prevent harmful contamination or intergranular corrosion.
  • Physical & Mechanical Properties: References general requirements for zinc and zinc alloys, ensuring ingots produced under ASTM B997 adhere to recognized standards for durability and mechanical performance.
  • Sampling and Analysis: Approved methods include ASTM E536, E1277 and relevant ISO 3815 standards for determining alloy composition.
  • Inspection & Certification: Clear procedures for material rejection and rehearing, product marking, packaging, and delivery, ensuring traceability and compliance.

Ordering & Manufacturing

  • Explicit guidelines for ordering, specifying required alloy types, dimensions, and optional elements.
  • The alloys may be made by any approved process, provided they are free from dross, slag, and other contaminants.

Applications

Primary Use: Hot-Dip Coatings on Steel

  • Structural Steel: Zn-Al alloy baths produced from compliant ingots are widely used for coating structural members, automotive parts, and fasteners, improving corrosion resistance and extending service life.
  • Galvanizing Plants: Ensures consistency in molten bath composition, maximizing adherence and longevity of the coating.
  • Infrastructure Projects: Bridges, power transmission, and other steel-based infrastructure projects benefit from enhanced protection provided by these zinc-aluminum coatings.

Benefits of Zn-Al Alloy Ingot Compliance

  • Uniformity: Assures manufacturers and end users of consistent alloy properties.
  • Corrosion Resistance: Specific compositions are chosen to optimize coating performance and protect steel from environmental degradation.
  • Global Trade Compatibility: Conformance with a recognized international standard facilitates acceptance of Zn-Al alloy ingots and coated products in cross-border projects.

Related Standards

Several ASTM and ISO standards are referenced for complete quality assurance and chemical analysis procedures, including:

  • ASTM B750: Specification for GALFAN (Zinc-5% Aluminum-Mischmetal) Alloy in Ingot Form for Hot-Dip Coatings
  • ASTM B860: Specification for Zinc Master Alloys for Use in Hot Dip Galvanizing
  • ASTM B949: General Requirements for Zinc and Zinc Alloy Products
  • ASTM E536/E1277: Chemical analysis of zinc and zinc alloys
  • ISO 3815-1 & ISO 3815-2: Methods for analysis of zinc and zinc alloys

Summary

By specifying requirements for zinc-aluminum alloy ingots intended for hot-dip coatings, ASTM B997-16(2021) supports steel manufacturers, galvanizers, and quality auditors with a comprehensive, internationally recognized approach to producing durable and high-performance coatings. Use of this standard ensures your products meet stringent industry and safety expectations in a globally competitive environment.

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Frequently Asked Questions

ASTM B997-16(2021) is a technical specification published by ASTM International. Its full title is "Standard Specification for Zinc-Aluminum Alloys in Ingot Form for Hot-Dip Coatings". This standard covers: ABSTRACT This specification covers three types of zinc-aluminum (Zn-Al) alloys in ingot form for re-melting for use in the production of hot-dip coatings on steel: Type 5 (95/5 Zn/Al), Type 10 (90/10 Zn/Al), and Type 15 (85/15 Zn/Al). Requirements prescribed by this specification cover ordering information; chemical, physical, and mechanical requirements; sampling for determination of chemical composition; methods for chemical analysis; material and manufacturing requirements; dimensions, mass, shapes, and sizes; workmanship, finish, and appearance; inspection and certification; product and package marking; and packaging and preparation for delivery. SCOPE 1.1 This specification covers certain zinc-aluminum (Zn-Al) alloys in ingot form for re-melting for use in the production of hot-dip coatings on steel. Alloy compositions are specified below and in Table 1. ASTM Common UNS Type 5 95/5 Zn/Al Z30507 Type 10 90/10 Zn/Al Z30600 Type 15 85/15 Zn/Al Z30706 Note 1: The zinc-aluminum alloys in Specification B997 are intended to be used primarily to create a molten zinc-aluminum bath and differ from the master alloys in Specification B860 which are intended primarily to adjust the concentration of certain elements in molten zinc galvanizing baths. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT This specification covers three types of zinc-aluminum (Zn-Al) alloys in ingot form for re-melting for use in the production of hot-dip coatings on steel: Type 5 (95/5 Zn/Al), Type 10 (90/10 Zn/Al), and Type 15 (85/15 Zn/Al). Requirements prescribed by this specification cover ordering information; chemical, physical, and mechanical requirements; sampling for determination of chemical composition; methods for chemical analysis; material and manufacturing requirements; dimensions, mass, shapes, and sizes; workmanship, finish, and appearance; inspection and certification; product and package marking; and packaging and preparation for delivery. SCOPE 1.1 This specification covers certain zinc-aluminum (Zn-Al) alloys in ingot form for re-melting for use in the production of hot-dip coatings on steel. Alloy compositions are specified below and in Table 1. ASTM Common UNS Type 5 95/5 Zn/Al Z30507 Type 10 90/10 Zn/Al Z30600 Type 15 85/15 Zn/Al Z30706 Note 1: The zinc-aluminum alloys in Specification B997 are intended to be used primarily to create a molten zinc-aluminum bath and differ from the master alloys in Specification B860 which are intended primarily to adjust the concentration of certain elements in molten zinc galvanizing baths. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM B997-16(2021) is classified under the following ICS (International Classification for Standards) categories: 77.150.60 - Lead, zinc and tin products. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM B997-16(2021) has the following relationships with other standards: It is inter standard links to ASTM B860-17, ASTM B899-16, ASTM B860-16, ASTM B860-15, ASTM B899-15, ASTM E536-15, ASTM B899-14, ASTM B949-13, ASTM B899-13, ASTM B860-13, ASTM B750-12, ASTM B899-09e1, ASTM B750-09, ASTM B860-09ae1, ASTM B899-09. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM B997-16(2021) is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: B997 −16 (Reapproved 2021)
Standard Specification for
Zinc-Aluminum Alloys in Ingot Form for Hot-Dip Coatings
This standard is issued under the fixed designation B997; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 2.2 ASTM Standards:
B750 Specification for GALFAN (Zinc-5 % Aluminum-
1.1 Thisspecificationcoverscertainzinc-aluminum(Zn-Al)
,
Mischmetal) Alloy in Ingot Form for Hot-Dip Coatings
alloys in ingot form for re-melting for use in the production of
B860 Specification for Zinc Master Alloys for Use in Hot
hot-dip coatings on steel. Alloy compositions are specified
Dip Galvanizing
below and in Table 1.
B899 Terminology Relating to Non-ferrous Metals and Al-
ASTM Common UNS
loys
Type 5 95/5 Zn/Al Z30507
B949 Specification for General Requirements for Zinc and
Type 10 90/10 Zn/Al Z30600
Type 15 85/15 Zn/Al Z30706
Zinc Alloy Products
E29 Practice for Using Significant Digits in Test Data to
NOTE 1—The zinc-aluminum alloys in Specification B997 are intended
tobeusedprimarilytocreateamoltenzinc-aluminumbathanddifferfrom Determine Conformance with Specifications
the master alloys in Specification B860 which are intended primarily to
E527 Practice for Numbering Metals and Alloys in the
adjust the concentration of certain elements in molten zinc galvanizing
Unified Numbering System (UNS)
baths.
E536 Test Methods for Chemical Analysis of Zinc and Zinc
1.2 The values stated in inch-pound units are to be regarded
Alloys
as standard. The values given in parentheses are mathematical
E1277 Test Method for Analysis of Zinc-5 % Aluminum-
conversions to SI units that are provided for information only
Mischmetal Alloys by ICP Emission Spectrometry
and are not considered standard.
2.3 ISO Standards:
1.3 This standard does not purport to address all of the
ISO 3815-1 Zinc and zinc alloys — Part 1:Analysis of solid
safety concerns, if any, associated with its use. It is the
samples by optical emission spectrometry
responsibility of the user of this standard to establish appro-
ISO 3815-2 Zinc and zinc alloys — Part 2: Analysis by
priate safety, health, and environmental practices and deter-
inductively coupled plasma optical emission spectrometry
mine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accor-
3. Terminology
dance with internationally recognized principles on standard-
3.1 Terminology:
ization established in the Decision on Principles for the
3.1.1 Type 5, n—95 % zinc – 5 % aluminum alloy.
Development of International Standards, Guides and Recom-
mendations issued by the World Trade Organization Technical 3.1.2 Type 10, n—90 % zinc – 10 % aluminum alloy.
Barriers to Trade (TBT) Committee.
3.1.3 Type 15, n—85 % zinc – 15 % aluminum alloy.
3.2 Abbreviations:
2. Referenced Documents
3.2.1 95/5 Zn/Al—95 % zinc – 5 % aluminum alloy.
2.1 The following documents of the issue in effect on date
3.2.2 90/10 Zn/Al—90 % zinc – 10 % aluminum alloy.
of order acceptance form a part of this specification to the
extent referenced herein: 3.2.3 85/15 Zn/Al—85 % zinc – 15 % aluminum alloy.
1 2
This specification is under the jurisdiction of ASTM Committee B02 on For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Nonferrous Metals and Alloys and is the direct responsibility of Subcommittee contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
B02.04 on Zinc and Cadmium. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved Nov. 1, 2021. Published December 2021. Originally the ASTM website.
ɛ1 3
approved in 2015. Last previous edition approved in 2016 as B997 – 16 . DOI: Available fromAmerican National Standards Institute (ANSI), 25 W. 43rd St.,
10.1520/B0997-16R21. 4th Floor, New York, NY 10036, http://www.ansi.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
B997 − 16 (2021)
A,B,C,D,E,F,G
TABLE 1 Zn-Al Alloy Ingot Chemical Requirements
7.2.1 Approved methods include: Test Methods E536,
Composition, %
E1277, ISO 3815-1, or ISO 3815-2.
F E E
Type 5 Type 10 Type 15
Element
NOTE 2—Test Method E1277 is directly applicable up to 8 %Al, in an
95/5 Zn/Al 90/10 Zn/Al 85/15 Zn/Al
UNS Z30507 UNS Z30600 UNS Z30706
unmodified form. ISO 3815-1 and ISO 3815-2 are generic methods
Aluminum 4.2-6.2 9.5-10.5 14.1-15.9 applied to zinc and zinc alloys. Each of the methods may be modified and
Iron, max 0.075 0.075 0.075
formatted for the alloy to be assayed. An experienced chemist, using
Silicon, max 0.015 0.015 0.015
suitable and/or traceable standards along with valid quality assurance
H
Lead, max 0.005 0.005 0.005
techniques, will be able to perform and validate the methods and
H
Cadmium, max 0.005 0.005 0.005
demonstrate acceptable precision and accuracy.
H
Tin, max 0.002 0.002 0.002
I
Others, each, max 0.02 0.02 0.02
I 8. Materials and Manufacture
Others, total, max 0.04 0.04 0.04
Zinc Remainder Remainder Remainder
8.1 The alloys may be made by any approve
...

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