Jewellery - Determination of silver in silver jewellery alloys - Volumetric (potentiometric) method using potassium bromide (ISO 11427:2014)

The method of ISO 11427:2014 describes a volumetric method for the determination of silver in jewellery alloys, preferably within the range of fineness stated in ISO 9202.
These alloys may contain copper, zinc, cadmium, and palladium. Apart from palladium, which must be precipitated before commencing titration, these elements do not interfere with this method of determination.
This method is intended to be used as the referee method for the determination of fineness in alloys covered by ISO 9202.

Schmuck - Bestimmung von Silber in Silberschmucklegierungen - Volumetrisches (potentiometrisches) Verfahren unter Verwendung von Kaliumbromid (ISO 11427:2014)

Diese Norm beschreibt ein volumetrisches Verfahren zur Bestimmung von Silber in Silberschmucklegierungen, vorzugsweise im Bereich der Feingehalte wie in ISO 9202 festgelegt.
Diese Legierungen dürfen Kupfer, Zink, Cadmium und Palladium enthalten. Abgesehen von Palladium, das vor der Durchführung der Titration ausgefällt werden muss, stören diese Elemente dieses Bestimmungsverfahren nicht.
Dieses Verfahren ist ein Schiedsverfahren zur Bestimmung der Reinheit in Legierungen wie in ISO 9202 angegeben.

Joaillerie, bijouterie - Dosage de l'argent dans les alliages d'argent pour la bijouterie-joaillerie - Méthode volumétrique (potentiométrique) utilisant le bromure de potassium (ISO 11427:2014)

La méthode de l'ISO 11427:2014 décrit une méthode volumétrique de dosage de l'argent dans les alliages utilisés en bijouterie-joaillerie, compris de préférence dans les limites de titre indiquées dans l'ISO 9202.
Ces alliages peuvent contenir du cuivre, du zinc, du cadmium et du palladium. À part le palladium qu'il faut précipiter avant de commencer le titrage, ces éléments ne gênent pas le dosage.
La présente méthode est destinée à servir de référence pour la détermination du titre des alliages traités dans l'ISO 9202.

Nakit - Določevanje srebra v zlitinah za srebrni nakit - Volumetrična (potenciometrična) metoda z uporabo kalijevega bromida (ISO 11427:2014)

Metoda standarda ISO 11427:2014 opisuje volumetrično metodo za določanje srebra v zlitinah za srebrni nakit, ki je po možnosti v razponu finosti, ki je naveden v standardu ISO 9202.
Te zlitine lahko vsebujejo baker, cink, kadmij in paladij. Poleg paladija, ki ga je treba izločiti pred začetkom titracije, ti elementi ne vplivajo na to metodo.
Metoda je namenjena za uporabo kot priporočena metoda za določanje finosti v zlitinah, ki je zajeta v standardu ISO 9202.

General Information

Status
Published
Public Enquiry End Date
29-Jun-2016
Publication Date
23-Oct-2016
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
20-Oct-2016
Due Date
25-Dec-2016
Completion Date
24-Oct-2016

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Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN ISO 11427:2016
01-december-2016
1DGRPHãþD
SIST EN 31427:1998
SIST EN 31427:1998/AC:2000
1DNLW'RORþHYDQMHVUHEUDY]OLWLQDK]DVUHEUQLQDNLW9ROXPHWULþQD
SRWHQFLRPHWULþQD PHWRGD]XSRUDERNDOLMHYHJDEURPLGD ,62
Jewellery - Determination of silver in silver jewellery alloys - Volumetric (potentiometric)
method using potassium bromide (ISO 11427:2014)
Schmuck - Bestimmung von Silber in Silberschmucklegierungen - Volumetrisches
(potentiometrisches) Verfahren unter Verwendung von Kaliumbromid (ISO 11427:2014)
Joaillerie, bijouterie - Dosage de l'argent dans les alliages d'argent pour la bijouterie-
joaillerie - Méthode volumétrique (potentiométrique) utilisant le bromure de potassium
(ISO 11427:2014)
Ta slovenski standard je istoveten z: EN ISO 11427:2016
ICS:
39.060 Nakit Jewellery
SIST EN ISO 11427:2016 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 11427:2016

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SIST EN ISO 11427:2016


EN ISO 11427
EUROPEAN STANDARD

NORME EUROPÉENNE

October 2016
EUROPÄISCHE NORM
ICS 39.060 Supersedes EN 31427:1994
English Version

Jewellery - Determination of silver in silver jewellery
alloys - Volumetric (potentiometric) method using
potassium bromide (ISO 11427:2014)
Joaillerie, bijouterie - Dosage de l'argent dans les Schmuck - Bestimmung von Silber in
alliages d'argent pour la bijouterie-joaillerie - Méthode Silberschmucklegierungen - Volumetrisches
volumétrique (potentiométrique) utilisant le bromure (potentiometrisches) Verfahren unter Verwendung
de potassium (ISO 11427:2014) von Kaliumbromid (ISO 11427:2014)
This European Standard was approved by CEN on 26 August 2016.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2016 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 11427:2016 E
worldwide for CEN national Members.

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SIST EN ISO 11427:2016
EN ISO 11427:2016 (E)
Contents Page
European foreword . 3

2

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SIST EN ISO 11427:2016
EN ISO 11427:2016 (E)
European foreword
The text of ISO 11427:2014 has been prepared by Technical Committee ISO/TC 174 “Jewellery” of the
International Organization for Standardization (ISO) and has been taken over as EN ISO 11427:2016.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by April 2017, and conflicting national standards shall be
withdrawn at the latest by April 2017.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
This document supersedes EN 31427:1994.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 11427:2014 has been approved by CEN as EN ISO 11427:2016 without any modification.


3

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SIST EN ISO 11427:2016

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SIST EN ISO 11427:2016
INTERNATIONAL ISO
STANDARD 11427
Second edition
2014-11-01
Jewellery — Determination of silver in
silver jewellery alloys — Volumetric
(potentiometric) method using
potassium bromide
Joaillerie, bijouterie — Dosage de l’argent dans les alliages
d’argent pour la bijouterie-joaillerie — Méthode volumétrique
(potentiométrique) utilisant le bromure de potassium
Reference number
ISO 11427:2014(E)
©
ISO 2014

---------------------- Page: 7 ----------------------

SIST EN ISO 11427:2016
ISO 11427:2014(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2014
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Case postale 56 • CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail copyright@iso.org
Web www.iso.org
Published in Switzerland
ii © ISO 2014 – All rights reserved

---------------------- Page: 8 ----------------------

SIST EN ISO 11427:2016
ISO 11427:2014(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Principle . 1
4 Reagents . 1
5 Apparatus . 2
6 Sampling . 2
7 Procedure. 2
7.1 Determination of potassium bromide factor . 2
7.2 Determination . 3
8 Calculation and expression of results . 3
8.1 Calculation . 3
8.2 Repeatability . 3
9 Test report . 4
Bibliography . 5
© ISO 2014 – All rights reserved iii

---------------------- Page: 9 ----------------------

SIST EN ISO 11427:2016
ISO 11427:2014(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives,
...

SLOVENSKI STANDARD
oSIST prEN ISO 11427:2016
01-junij-2016
1DNLW'RORþHYDQMHVUHEUDY]OLWLQDK]DVUHEUQLQDNLW9ROXPHWULþQD
SRWHQFLRPHWULþQD PHWRGD]XSRUDERNDOLMHYHJDEURPLGD ,62
Jewellery - Determination of silver in silver jewellery alloys - Volumetric (potentiometric)
method using potassium bromide (ISO 11427:2014)
Schmuck - Bestimmung von Silber in Silberschmucklegierungen - Volumetrisches
(potentiometrisches) Verfahren unter Verwendung von Kaliumbromid (ISO 11427:2014)
Joaillerie, bijouterie - Dosage de l'argent dans les alliages d'argent pour la bijouterie-
joaillerie - Méthode volumétrique (potentiométrique) utilisant le bromure de potassium
(ISO 11427:2014)
Ta slovenski standard je istoveten z: prEN ISO 11427
ICS:
39.060 Nakit Jewellery
oSIST prEN ISO 11427:2016 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN ISO 11427:2016

---------------------- Page: 2 ----------------------
oSIST prEN ISO 11427:2016
INTERNATIONAL ISO
STANDARD 11427
Second edition
2014-11-01
Jewellery — Determination of silver in
silver jewellery alloys — Volumetric
(potentiometric) method using
potassium bromide
Joaillerie, bijouterie — Dosage de l’argent dans les alliages
d’argent pour la bijouterie-joaillerie — Méthode volumétrique
(potentiométrique) utilisant le bromure de potassium
Reference number
ISO 11427:2014(E)
©
ISO 2014

---------------------- Page: 3 ----------------------
oSIST prEN ISO 11427:2016
ISO 11427:2014(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2014
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Case postale 56 • CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail copyright@iso.org
Web www.iso.org
Published in Switzerland
ii © ISO 2014 – All rights reserved

---------------------- Page: 4 ----------------------
oSIST prEN ISO 11427:2016
ISO 11427:2014(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Principle . 1
4 Reagents . 1
5 Apparatus . 2
6 Sampling . 2
7 Procedure. 2
7.1 Determination of potassium bromide factor . 2
7.2 Determination . 3
8 Calculation and expression of results . 3
8.1 Calculation . 3
8.2 Repeatability . 3
9 Test report . 4
Bibliography . 5
© ISO 2014 – All rights reserved iii

---------------------- Page: 5 ----------------------
oSIST prEN ISO 11427:2016
ISO 11427:2014(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the meaning of ISO specific terms and expressions related to conformity
assessment, as well as information about ISO’s adherence to the WTO principles in the Technical Barriers
to Trade (TBT) see the following URL: Foreword - Supplementary information
The committee responsible for this document is ISO/TC 174, Jewellery.
This second edition cancels and replaces the first edition (ISO 11427:1993) which has been technically
revised with the following changes:
a) change of requirement for sampling in Clause 6;
b) addition of a warning in Clause 7 that suitable health and safety procedures should be followed;
c) addition of the possibility to use watch glasses in 7.1.1 to cover the beaker;
d) deletion of the specified volume of water in 7.1.1;
e) addition in 7.1.3 that a potassium bromide standard solution is used;
f) change in 8.1 from potassium chloride to potassium bromide;
g) standard editorially revised.
iv © ISO 2014 – All rights reserved

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oSIST prEN ISO 11427:2016
ISO 11427:2014(E)

Introduction
The following definitions apply in understanding how to implement an ISO International Standard and
other normative ISO deliverables (TS, PAS, IWA).
— “shall” indicates a requirement
— “
...

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