SIST-TP CEN/TR 16741:2015
(Main)Textiles and textile products - Guidance on health and environmental issues related to chemical content of textile products intended for clothing, interior textiles and upholstery
Textiles and textile products - Guidance on health and environmental issues related to chemical content of textile products intended for clothing, interior textiles and upholstery
This Technical Report specifies environmental and health recommendations for textile products (including
accessories) with direct skin contact and in the proximity of the human body.
This Technical Report facilitates the understanding of chemicals with intended uses in the manufacturing of
goods in the fields of textile products intended to clothing, interior textiles and upholstery, to comply with the
European chemical regulations and recommendations in force in EU.
WARNING — This Technical Report is not intended to substitute the existing regulations. The reader is
requested to check the current existing regulation.
By suggesting that the textile market follows the ethos of this Technical Report, and thereby avoiding the use
of unwanted substances in the manufacture of textile products, the level of protection of human health and of
environment will be increased.
The distinguishing properties of the chemicals and the processes in which they are used (intended use
substances) or they occur (unintended release substances) are described in this technical report.
This Technical Report mentions, when relevant, the existing standardized test methods commonly in use, as
well as, the related limit values which are generally accepted. Only the standard identification number is given
in the main text and the related title is listed in Bibliography.
NOTE 1 When limit values are given, possible contamination by the external environment and inaccuracy in the
measurement of very low concentration may be taken into consideration.
The listed substances of this Technical Report can be categorised in two: one related to intended use, another
one related to unintended release.
NOTE 2 Inclusion in the candidate list of EU REACH Regulation (EC) n°1907/2006 has been mentioned in this
Technical Report for some substances. This does not necessarily mean that a substance, for which such a note is not
made, would not be included in the candidate list in the future (new substances are regularly included in the list).
NOTE 3 For filling material such as “feather & down”, refer to CEN TC 222 and, for other material used in clothing such
as leather, refer to CEN TC 309, for toys, refer to CEN TC 252.
Textilien und textile Erzeugnisse - Anleitung für Gesundheits-und Umweltfragen in Bezug auf den Chemikaliengehalt von Textilerzeugnissen für Bekleidung, Heimtextilien und Polstermöbel
Textiles et produits textiles - Guide sur les conséquences environnementales et sur la santé liées aux substances chimiques présentes dans les produits textiles destinés à l’habillement, aux textiles d’intérieur et à l’ameublement
Le présent Rapport technique spécifie des recommandations environnementales et sanitaires applicables aux produits textiles (y compris les accessoires) en contact direct avec la peau et présents au voisinage du corps humain.
Il facilite la compréhension des substances chimiques prévues pour être utilisées dans la fabrication d’articles dans les domaines des produits textiles destinés à l’habillement, aux textiles d’intérieur et à l’ameublement, afin de se conformer à la réglementation européenne sur les substances chimiques et aux recommandations en vigueur dans l’Union européenne.
AVERTISSEMENT : le présent Rapport technique n’est pas destiné à remplacer les réglementations existantes. Le lecteur est invité à vérifier la réglementation actuellement en vigueur.
En recommandant au secteur du textile de s’inscrire dans l’esprit du présent Rapport technique, et en évitant ainsi que les produits contiennent des substances indésirables, la santé humaine et l’environnement seront protégés dans les pays producteurs, fournisseurs et importateurs dans l’UE.
Les propriétés particulières des substances chimiques et les processus dans lesquels elles sont utilisées (utilisation prévue des substances) ou au cours desquels elles apparaissent (libération involontaire des substances) sont décrits dans le présent Rapport technique.
Le présent Rapport technique mentionne, le cas échéant, les méthodes d’essai normalisées existantes communément utilisées, ainsi que les valeurs limites correspondantes, qui sont généralement reconnues.
NOTE 1 Lorsque des valeurs limites sont indiquées, il est possible de prendre en compte une contamination éventuelle par l’environnement extérieur de même que l’inexactitude de mesure de concentrations très faibles.
Les substances mentionnées dans le présent Rapport technique peuvent être divisées en deux catégories : l’une se rapportant à l’utilisation prévue, l’autre à la libération involontaire.
NOTE 2 Pour les matériaux de remplissage tels que « plumes et duvets », se référer au CEN/TC 222 et pour les autres matériaux utilisés dans l’habillement, tels que le cuir, se référer au CEN/TC 309 ; pour les jouets, se référer au CEN/TC 252.
Tekstilije in tekstilni izdelki - Napotki o zdravstvenih in okoljskih vprašanjih, povezanih s kemijsko vsebnostjo tekstilnih izdelkov, namenjenih za oblačila, notranje tekstilije in oblazinjenje
To tehnično poročilo določa okoljska in zdravstvena priporočila za tekstilne izdelke (vključno z dodatki), ki so v neposrednem stiku s kožo in blizu človeškega telesa.
To tehnično poročilo olajša razumevanje kemikalij, ki so predvidene za uporabo v proizvodnji blaga na področju tekstilnih izdelkov, namenjenih za oblačila, notranje tekstilije in oblazinjenje, za skladnost z evropskimi predpisi in priporočili glede kemikalij, ki veljajo v EU.
OPOZORILO – To tehnično poročilo ni namenjeno kot nadomestilo za obstoječe predpise. Bralec naj preveri trenutne obstoječe predpise.
Če bo tekstilni trg upošteval moralna načela iz tega tehničnega poročila in se izogibal uporabi neželenih snovi v proizvodnji tekstilnih izdelkov, se bo povečala stopnja zaščite človeškega zdravja in okolja.
V tem tehničnem poročilu so opisane razlikovalne lastnosti kemikalij in postopkov, v katerih se uporabljajo (predvideno uporabljene snovi) ali v katerih nastanejo (nenamerno sproščene snovi). To tehnično poročilo, kjer je ustrezno, navaja obstoječe najpogosteje uporabljane standardizirane metode preskušanja in povezane splošno sprejete mejne vrednosti. V glavnem besedilu je navedena samo identifikacijska številka standarda, povezan naslov pa je naveden v bibliografiji.
OPOMBA 1: Ko so podane mejne vrednosti, se lahko upošteva morebitno onesnaženje zaradi zunanjega okolja in nenatančnosti pri meritvah zelo nizkih koncentracij.
Navedene snovi iz tega tehničnega poročila je mogoče razvrstiti na dva dela: prvi je povezan s predvideno uporabo, drugi pa z nenamernim izpustom.
OPOMBA 2: V tem tehničnem poročilu je za nekatere snovi navedena vključitev na seznam kandidatnih snovi Uredbe EU REACH (ES) št. 1907/2006. To ne pomeni nujno, da snov, pri kateri takšne navedbe ni, ne bo vključena na seznam kandidatnih snovi v prihodnosti (redno poteka vključevanje novih snovi na seznam).
OPOMBA 3: Za polnilni material, kot sta »perje in puh«, glej CEN TC 222 in za drug material, uporabljen za oblačila, kot je usnje, glej CEN TC 309, za igrače glej CEN TC 252.
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
SIST-TP CEN/TR 16741:2015
01-oktober-2015
7HNVWLOLMHLQWHNVWLOQLL]GHONL1DSRWNLR]GUDYVWYHQLKLQRNROMVNLKYSUDãDQMLK
SRYH]DQLKVNHPLMVNRYVHEQRVWMRWHNVWLOQLKL]GHONRYQDPHQMHQLK]DREODþLOD
QRWUDQMHWHNVWLOLMHLQREOD]LQMHQMH
Textiles and textile products - Guidance on health and environmental issues related to
chemical content of textile products intended for clothing, interior textiles and upholstery
Textilien und textile Erzeugnisse - Anleitung für Gesundheits-und Umweltfragen in Bezug
auf den Chemikaliengehalt von Textilerzeugnissen für Bekleidung, Heimtextilien und
Polstermöbel
Textiles et produits textiles - Guide sur les conséquences environnementales et sur la
santé liées aux substances chimiques présentes dans les produits textiles destinés à
l’habillement, aux textiles d’intérieur et à l’ameublement
Ta slovenski standard je istoveten z: CEN/TR 16741:2015
ICS:
59.080.01 Tekstilije na splošno Textiles in general
SIST-TP CEN/TR 16741:2015 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
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SIST-TP CEN/TR 16741:2015
TECHNICAL REPORT
CEN/TR 16741
RAPPORT TECHNIQUE
TECHNISCHER BERICHT
August 2015
ICS 59.080.01
English Version
Textiles and textile products - Guidance on health and
environmental issues related to chemical content of textile
products intended for clothing, interior textiles and upholstery
Textiles et produits textiles - Guide sur les conséquences Textilien und textile Erzeugnisse - Anleitung für
environnementales et sur la santé liées aux substances Gesundheits-und Umweltfragen in Bezug auf den
chimiques présentes dans les produits textiles destinés à Chemikaliengehalt von Textilerzeugnissen für Bekleidung,
l'habillement, aux textiles d'intérieur et à l'ameublement Heimtextilien und Polstermöbel
This Technical Report was approved by CEN on 14 May 2015. It has been drawn up by the Technical Committee CEN/TC 248.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2015 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 16741:2015 E
worldwide for CEN national Members.
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Contents Page
European foreword .4
Introduction .5
1 Scope .6
2 Terms and definitions .6
3 General recommendations .7
3.1 CMR chemicals .7
3.2 PBT and vPvB substances .7
3.3 SVHC (“Substances of Very High Concern”) .7
4 Specific criteria for textile products .8
4.1 Formaldehyde . 14
4.1.1 General . 14
4.1.2 Why is it a critical substance? . 14
4.1.3 Regulation/Specific tests method . 15
4.2 Chlorophenols (pentachlorophenol, isomers of tetrachlorophenol) . 15
4.2.1 General . 15
4.2.2 Why is PCP a critical substance? . 15
4.2.3 Regulation/Specific tests method . 15
4.3 Orthophenylphenol (OPP) . 16
4.3.1 General . 16
4.3.2 Why is it a critical substance? . 16
4.3.3 Tests method . 16
4.4 Heavy metals . 16
4.4.1 General . 16
4.4.2 Extractable heavy metals . 17
4.4.3 Total heavy metal . 17
4.4.4 Antimony -Sb . 17
4.4.5 Arsenic – As . 18
4.4.6 Barium – Ba . 19
4.4.7 Cadmium – Cd . 20
4.4.8 Chromium – Cr . 21
4.4.9 Cobalt – Co . 22
4.4.10 Copper – Cu . 23
4.4.11 Lead – Pb . 24
4.4.12 Mercury – Hg . 26
4.4.13 Nickel – Ni . 27
4.4.14 Selenium – Se . 30
4.5 Flame retardants . 30
4.5.1 General . 30
4.5.2 Why is it a critical substance? . 30
4.5.3 Regulation/Specific test methods . 31
4.6 Carcinogenic dyes, suspected dyes and derived substances . 31
4.6.1 General . 31
4.6.2 Carcinogenic amines derived from azo colorants . 32
4.6.3 Carcinogenic colorants and colorants suspected to be carcinogenic, mutagenic or toxic
to reproduction . 32
4.6.4 Sensitizing colorants . 33
4.7 Sensitizing substances (others than colorants) . 34
4.8 Pesticides, herbicides and fungicides . 34
4.8.1 General . 34
2
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4.8.2 Why is it a critical substance? . 35
4.8.3 Regulation/Specific test methods . 35
4.9 Chloroorganics including carriers (chlorinated benzenes, chlorinated toluenes and
chlorinated naphtalenes) . 37
4.9.1 General . 37
4.9.2 Why is it a critical substance? . 37
4.9.3 Regulation/Specific tests method . 37
4.10 Phthalates. 38
4.10.1 General . 38
4.10.2 Why is it critical? . 38
4.10.3 Regulations / Specific test method . 38
4.11 Organotin compounds . 39
4.11.1 General . 39
4.11.2 Why is it critical? . 39
4.11.3 Regulations / Specific test method . 39
4.12 Perfluorooctanesulfonates (PFOS) and perfluorooctanoic acid (PFOA) . 40
4.12.1 General . 40
4.12.2 Why is it a critical substance? . 40
4.12.3 Regulations/Test method. 41
4.13 Dimethylfumarate (DMFu) . 41
4.13.1 General . 41
4.13.2 Why is it a critical substance? . 41
4.13.3 Regulation/Specific test methods . 42
4.14 Alkyl phenol ethoxylates (APEO) . 42
4.14.1 General . 42
4.14.2 Why are APEO critical substances? . 43
4.14.3 Regulations/Test methods. 43
4.15 Residual solvents . 43
4.15.1 General . 43
4.15.2 Why is it critical? . 43
4.15.3 Regulations / Specific test method . 44
5 Others . 44
5.1 pH . 44
5.1.1 General . 44
5.1.2 Why is it critical? . 44
5.1.3 Regulation/Specific tests method . 44
5.2 Colour fastness in relation to acidic and alkaline perspiration (recommendation for
screening). 44
5.3 Polycyclic aromatic hydrocarbons (PAH) (screening when strong odour) . 44
5.3.1 General . 44
5.3.2 Why is it critical? . 45
5.3.3 Regulations / Specific test method . 45
Annex A (informative) Risk phrases . 46
Annex B (informative) Criteria for the identification of persistent, bioaccumulative and toxic
substances, and very persistent and very bioaccumulative substances . 47
B.1 General . 47
B.2 PBT substances . 47
B.3 vPvB substances . 48
Bibliography . 49
3
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European foreword
This document (CEN/TR 16741:2015) has been prepared by Technical Committee CEN/TC 248 “Textiles and
textile products”, the secretariat of which is held by BSI.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
4
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Introduction
In 2003, the company CREM (Consultancy and Research for Environmental Management, Amsterdam, The
Netherlands) started reviewing a selected number of European standards to identify relevant environmental
concerns which should be addressed. Horizontal requirements were drafted during the continuing work on
draft standards. These horizontal requirements comprise, among others, CMR chemicals (carcinogenic,
mutagenic and toxic to reproduction), PBTs and vPvB substances (persistent, bioaccumulative and toxic and
very persistent and very bioaccumulative substances) and substances identified as causing serious and
irreversible effects to humans or the environment equivalent to the effects mentioned on a case-by-case
basis, such as endocrine disrupters.
CEN/TC248 has decided to adopt the proposal included in the study as a technical report with general
requirements for textile products with direct skin contact.
The working group extended the scope of the technical report to textile products in the proximity of the human
body .
In this technical report, the wording ‘textile product’ is used, as defined in the Textile Fibre Regulation (EU) No
1007/2011. In the parts where REACH is described, the wording ‘textile article’ is used in the same meaning.
Thus, in the context of this technical report ‘textile product’ and ‘textile article’ are the same.
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1 Scope
This Technical Report specifies environmental and health recommendations for textile products (including
accessories) with direct skin contact and in the proximity of the human body.
This Technical Report facilitates the understanding of chemicals with intended uses in the manufacturing of
goods in the fields of textile products intended to clothing, interior textiles and upholstery, to comply with the
European chemical regulations and recommendations in force in EU.
WARNING — This Technical Report is not intended to substitute the existing regulations. The reader is
requested to check the current existing regulation.
By suggesting that the textile market follows the ethos of this Technical Report, and thereby avoiding the use
of unwanted substances in the manufacture of textile products, the level of protection of human health and of
environment will be increased.
The distinguishing properties of the chemicals and the processes in which they are used (intended use
substances) or they occur (unintended release substances) are described in this technical report.
This Technical Report mentions, when relevant, the existing standardized test methods commonly in use, as
well as, the related limit values which are generally accepted. Only the standard identification number is given
in the main text and the related title is listed in Bibliography.
NOTE 1 When limit values are given, possible contamination by the external environment and inaccuracy in the
measurement of very low concentration may be taken into consideration.
The listed substances of this Technical Report can be categorised in two: one related to intended use, another
one related to unintended release.
NOTE 2 Inclusion in the candidate list of EU REACH Regulation (EC) n°1907/2006 has been mentioned in this
Technical Report for some substances. This does not necessarily mean that a substance, for which such a note is not
made, would not be included in the candidate list in the future (new substances are regularly included in the list).
NOTE 3 For filling material such as “feather & down”, refer to CEN TC 222 and, for other material used in clothing such
as leather, refer to CEN TC 309, for toys, refer to CEN TC 252.
2 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
2.1
textile clothing and accessories
clothing and accessories (such as handkerchiefs, scarves, bags, shopping bags, rucksacks, belts etc.)
consisting of at least 80 % by weight of textile fibres
[SOURCE: EU fibre composition Regulation (EC) n°1007/2011]
2.2
interior textiles, textile products for interior use
textile products for interior use: textile products for interior use consisting of at least 80 % by weight of textile
fibres; wall and floor coverings are excluded
[SOURCE: EU fibre composition Regulation (EC) n°1007/2011]
2.3
fibres, yarn and fabric
intended for use in textile clothing and accessories or interior textiles
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Note 1 to entry: For ‘textile clothing and accessories’ and for ‘interior textiles’: down, feathers, membranes and
coatings need not be taken into account in the calculation of the percentage of textile fibres.
2.4
CMR chemical
chemical (substance or substance mixtures) belonging to at least one of three different categories:
Carcinogenic, Mutagenic and Reprotoxic (toxic to reproduction)
Note 1 to entry: CMR chemicals are classified according to EU Classification Labelling Packaging Regulation (EC)
n°1272/2008 and are covered by the following R-phrases: R40, R45, R46 R49, R60, R61, R62, R63 and R68 (see
Annex A).
2.5
PBT and vPvB substances
Persistent, Bio accumulative and Toxic substances and very Persistent and very Bio accumulative substances
Note 1 to entry: The terms of PBT and vPvB substances are defined in EU REACH Regulation (EC) n°1907/2006
2.6
Substances of Very High Concern (SVHC)
substances which should be treated with equivalent concern as CMR chemical and PBT and vPvB
substances.
Note 1 to entry: These substances for which there is scientific evidence of probable serious effect to human health or
the environment which give rise to an equivalent level of concern to CMR and/or PBT and/or vPvB substances.
3 General recommendations
3.1 CMR chemicals
The product should not contain or release any carcinogenic, mutagenic or reprotoxic chemicals (CMR
chemicals) in amounts exceeding 0,1 % by weight of the whole product.
3.2 PBT and vPvB substances
The product should not contain any PBT and vPvB substances which meet the criteria in Annex XIII of EU
REACH Regulation (EC) n°1907/2006, in amounts exceeding 0,1 % by weight of the whole product.
3.3 SVHC (“Substances of Very High Concern”)
SVHC are defined in Article 57 of EU REACH Regulation (EC) n°1907/2006 and include substances which
are:
— Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category
1 or 2 in accordance with Directive 67/548/EEC. This directive was recently replaced by the new EU
Classification Labelling Packaging Regulation (EC) n°1272/2008 on classification, labelling and
packaging of chemical substances and mixtures, the so-called CLP Regulation. According to the new
CLP Regulation these substances shall be classified as 1a or 1b.
— Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB)
according to the criteria in Annex XIII of EU REACH Regulation (EC) n°1907/2006,
— Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to
human health or the environment of an equivalent level of concern as those above (e.g. endocrine
disrupters, allergenic substances and sensitizing substances)
NOTE The list of identified substances of very high concern is updated regularly. The current listing can be found at
http://echa.europa.eu/candidate-list-table. The obligations relating to placing on the market articles containing SVHC
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substances can be reviewed on ECHA webpages. Uses of some SVHCs in the EU require authorization. More information
on this can also be found at http://echa.europa.eu/ .
4 Specific criteria for textile products
The criteria are listed in Table 1 in relation to the type of fibres and in Table 2 in relation to the type of finishing
and accessories.
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Table 1 — Criteria in relation to the type of fibres
a)
Type of fibres
natural fibres man-made fibres
Criteria Animal fibres Cellulose Polyester Polyamide Acetate; Acrylic Viscose Elastane Elastodiene
fibres
Triacetate
Formaldehyde X X X
Azo dyes X X X X X X X
Extractable heavy metals
Cd X X X X X X
As X
Hg X
Ni X
Cu X X
Pb X X
Cr X X
Co X X X
Sb X
Chromium (VI) X X
Chlorinated Phenols
PCP, TeCP, TriCP X X X X X X X
OPP X X X X X X X
Carcinogenic dyes X X X X X X X
Allergenic Disperse X X X X
dyes
Chlorinated benzenes X X X X
and toluenes
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Organotin compounds X X X X X X X X
Flame retardants X X X X X X X
Acrylonitrile X
Pesticides X X
Herbicides X
Dimethylformamide
X
(DMF)
Dimethylfumarate
X x X X X X X
(DMFu)
APEO X X X X X X X
DMA X X X
b)
PFOS X X X X X X X
PAH X X X X X X X
a)
In case of fibre blends, all criteria related to the fibre of the blends have to be considered.
b)
only for water-, oil- and dirt- repellent finish or coated
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Table 2 — Criteria in relation to the type of finishing and components used on textile products (buttons, slide fasteners, buckles, etc.)
Type of finishing or accessories
galvani Polyure Glass
Criteria
rubbers
Leather coated Coated painted
Prints a) metalic zed Plastic wood thane
fabrics metal metal
ABS (foam)
Formaldehyde X X X X X
Azo dyes X X X X X
4,4'-Diaminodiphenylmethane X X
Extractable heavy metals
Cd X X X X X X X X
As X X X X
Hg X
Ba X
Se X
Ni X X X X X X
Cu X X
Pb X X X
Cr X X
Co X X
Sb X X X
Chromium (VI) X X X X X (glue)
Soluble mineral tanning agents Al, Cr,
X
Ti, Zr
Ni X X X X
Ni wear X X X
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Total Cd X X X X X X X X
Lead in paint X
Total lead X X X X X X X X
Phthalates X X
Phthalates (Child care articles) X X X
Chlorinated Phenols:PCP, TeCP X X X X
OPP X X X
Allergenic Disperse dyes X
Chlorinated benzenes and toluenes X X
Organic Tin compounds X X X X X X
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Table 3 — Criteria in relation to the type of finishing and components used on textile products (buttons, slide fasteners, buckles, etc.)
Type of finishing or accessories
Criteria
rub
...
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