ISO 21014:2019

INTERNATIONAL ISO
STANDARD 21014
Second edition
2019-10
Cryogenic vessels — Cryogenic
insulation performance
Récipients cryogéniques — Performances d'isolation cryogénique
Reference number
©
ISO 2019
© ISO 2019
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ii © ISO 2019 – All rights reserved

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 General conditions for all methods . 2
5 Measuring the heat leak by the loss of product method . 3
5.1 General . 3
5.2 Test procedure . 3
5.3 Determination of the heat leak in units of energy per unit time . 4
5.4 Determination of the heat leak as a percentage loss of product per 24 h . 4
6 Determination of the holding time for open systems from heat-leak data .4
7 Holding times for closed systems . 4
7.1 Determination of the equilibrium holding time from heat-leak data . 4
7.2 Determination of the optimum equilibrium holding time from heat-leak data . 5
7.3 Static experimental holding time . 6
8 Test report . 6
Annex A (normative) Conversion of measured volumetric gaseous flow to mass flow .8
Annex B (normative) Correction of measured mass flow rate with regard to deviation from
reference conditions .10
Annex C (normative) Equivalent loss determination for products other than the test product .16
Bibliography .17
Foreword
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electrotechnical standardization.
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described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
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iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 220, Cryogenic vessels.
This second edition cancels and replaces the first edition (ISO 21014:2006), which has been technically
revised.
The main changes compared to the previous edition are as follows:
— Clause 2 has been added and subsequent clauses and cross-references updated.
— For clarity, “set pressure of the pressure-limiting device” has been reworded to “set pressure of the
lowest set pressure-limiting device on stream” in subclauses 3.5, 3.5.3, and 3.6.
— “(100 % for helium)” has been added to 7.2 b) 1).
— In subclause 7.2 c), the denominator in the formula for m has been corrected from v to v .
ig el il
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/ members .html.
iv © ISO 2019 – All rights reserved

Introduction
Traditionally, there have been different methods of defining the insulation performance of cryogenic
vessels. It is therefore necessary to harmonize such methods for different cryogenic vessels.
Figure 1 shows a logic diagram to help in the understanding of this document.
Figure 1 — Logic diagram
INTERNATIONAL STANDARD ISO 21014:2019(E)
Cryogenic vessels — Cryogenic insulation performance
1 Scope
This document defines practical methods for determining the heat-leak performance of cryogenic
vessels. The methods include measurement on both open and closed systems.
This document neither specifies the requirement levels for insulation performance nor when the
defined methods are applied.
2 Normative references
There are no normative references in this document.
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http:// www .electropedia .org/
— ISO Online browsing platform: available at https:// www .iso .org/ obp
3.1
open system
system kept at a constant pressure (e.g. atmospheric pressure) in which the gas produced
by the evaporation of the test fluid is continuously released to atmosphere
3.2
closed system
system in which the mass of the contents is kept constant with no input or output of product
3.3
heat-leak rate
quantity of heat transferred per unit time from the ambient air to the contents of the inner vessel
Note 1 to entry: In an open system, the heat leak causes a loss of product; in a closed system, it causes a rise in
pressure.
3.4
holding time for open system
time expected to elapse, for a specified degree of filling, from initial filling level until the vessel is empty
(no more liquid) calculated from heat-leak data
3.5
holding time for closed system
time elapsed, for a specified degree of filling, from establishing the initial filling condition until the
pressure has risen, due to heat leak, to the set pressure of the lowest set pressure-limiting device
on stream
Note 1 to entry: For transportable vessels, this holding time is determined without the effects of stratification.
Note 2 to entry: Pressure-limiting devices include: a safety valve, a rupture disc, a back-pressure regulator, or
any other device installed to limit the system pressure under normal operating conditions.
3.5.1
equilibrium holding time
holding time calculated from a specified heat leak assuming that liquid and vapour are constantly in
equilibrium (without stratification)
3.5.2
longest equilibrium holding time
equilibrium holding time calculated from heat-leak data for a vessel when filled with the quantity of
product giving the longest holding time
3.5.3
static experimental holding time
time it takes starting from atmospheric pressure, or from a stated pressure in the case of fluids
where the starting pressure cannot be atmospheric pressure (e.g. 10 bar gauge for CO ), to reach the
set pressure of the lowest set pressure-limiting device on stream with the tank initially filled to its
maximum allowable filling mass
3.6
maximum allowable filling mass
initial mass that results in the tank becoming hydraulically full (98 % for all fluids except helium and
100 % for helium) at the point that the lowest set pressure-limiting device on stream operates
Note 1 to entry: For fluids in a supercritical condition, the maximum allowable filling mass will be a function of
the holding time and will be stated.
4 General conditions for all methods
4.1 The cryogenic fluid used for testing shall be agreed upon between the involved parties. Liquid
nitrogen may normally be used, except in cases where the vessel to be tested is designed for a specific
cryogenic fluid.
4.2 The liquid and gaseous phases shall be in equilibrium at the beginning of a test. When a test is
carried out at a higher pressure than atmospheric pressure, it is important that the liquid equilibrium
pressure is not lower than this test pressure.
4.3 The test environment shall be stable and constant during the test. It shall be as close as possible to
the following reference conditions:
— ambient temperature, 15 °C (288,15 K);
— atmospheric pressure, 1,013 bar (101,3 MPa) (absolute).
For products other than carbon dioxide and nitrous oxide:
— vessel reference pressure, 1,013 bar (101,3 MPa) (absolute).
For carbon dioxide and nitrous oxide:
— vessel reference pressure, 15 bar (1,5 MPa) (gauge).
4.4 The vessel and its contents shall have reached a stable temperature before the beginning of the
measuring period. Equilibrium conditions are obtained after a period of stabilization, the duration of
which depends on the size of the vessel and the type and configuration of the insulation.
4.5 All accessories of the vessel which can influence the result of the measurement shall be clearly
defined and specified in the report.
4.6 All instrumentation used shall be verified by calibration.
2 © ISO 2019 – All rights reserved

4.7 It is not necessary to use the method defined in this document to evaluate the insulation
performance resulting from small modifications; this may be done by simple extrapolation.
5 Measuring the heat leak by the loss of product method
5.1 General
There are two methods of measuring the heat leak:
— direct measurement of loss of mass;
— indirect measurement of loss of mass by measuring the gaseous volumetric discharge rate.
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The filling level shall be 50 % of the maximum filling level at the start of measurement, unless
otherwise stated.
The ambient temperature, ambient barometric pressure and the operating pressure at the top of the
vessel shall be recorded throughout the test so as to be used for correction purposes. The temperature
sensor(s) shall be placed in the immediate proximity of the tank being tested, but sited such that they
are unaffected directly by cold gas discharged from the vents.
The minimum measurement duration shall be 24 h after stable conditions have been reached.
During the test, precautions shall be taken to avoid agitation of the liquid, except for tanks designed for
land transport mode.
When measuring the rate of discharge of gas escaping from the vessel by a flow meter, it is essential
that the entire gas flow passes through the meter. The gas flow rate shall be determined as a mass flow
rate by using either of the following:
— mass flow meter;
— volumetric flow meter (an appropriate method is shown in Annex A).
5.2 Test procedure
The test procedure shall be as follows:
a) pre-cool the vessel;
b) leave for a first stabilization period;
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c) adjust the filling to the intended starting level (e.g. 50 % );
d) con
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