ISO 24483:2023
(Main)Epoxidized natural rubber - Specifications
Epoxidized natural rubber - Specifications
This document specifies the physical and chemical requirements of epoxidized natural rubber (ENR) based on the epoxidation level of the natural rubber.
Caoutchouc naturel époxydé — Spécifications
General Information
- Status
- Published
- Publication Date
- 08-Jun-2023
- Drafting Committee
- ISO/TC 45/SC 3/WG 4 - Natural rubber
- Current Stage
- 6060 - International Standard published
- Start Date
- 09-Jun-2023
- Due Date
- 23-Jun-2023
- Completion Date
- 09-Jun-2023
Overview
ISO 24483:2023 - Epoxidized natural rubber (ENR) - Specifications defines the physical and chemical requirements for epoxidized natural rubber (ENR) based on its epoxidation level. The first edition (2023) standard covers grade structure, material composition, sampling, packaging and the test methods needed to verify key properties of ENR grades (notably ENR 25, ENR 50 and their field-latex variants ENR 25 FL / ENR 50 FL). This standard provides a uniform reference for manufacturers, buyers and testing laboratories to specify and verify ENR quality.
Key topics and requirements
- Grades and identification
- ENR 25, ENR 50 (centrifuged latex origin) and ENR 25 FL, ENR 50 FL (field latex origin).
- Numerals indicate mole percentage epoxidation (25 mol% and 50 mol% ± 2 mol%).
- Chemical and physical limits
- Epoxidation level: 25 ± 2 % or 50 ± 2 % (mole fraction) - ISO 5260.
- Ring opening level (max): ENR 25 → 2.0 %; ENR 50 → 4.0 % (mole fraction).
- Ash content (max): 0.25 % (mass fraction) - ISO 247-1.
- Mooney viscosity (ML (1+4) at 100 °C): 70 to 100 - ISO 289-1.
- Glass transition temperature (Tg): ENR 25: −45 ± 2 °C; ENR 50: −22 ± 2 °C - ASTM D3418.
- Nitrogen content (field-latex grades only): max 0.15 % - ISO 1656.
- Lovibond colour index (optional): max 4.0 - ISO 4660.
- Quality control
- Sampling per ISO 1795; each lot must meet agreed grade requirements.
- Packaging typically in bales of nominal 33.3 kg or 35 kg, identified and wrapped (ISO 20299-2 recommended).
Applications and users
ISO 24483:2023 is used by:
- Rubber compounders and product manufacturers specifying ENR feedstock for formulation control.
- Quality assurance and testing laboratories performing conformity checks (epoxidation, ring opening, viscosity, Tg).
- Procurement and specification engineers drafting material purchase requirements.
- Standards bodies and certification organizations harmonizing ENR specifications for trade.
The standard helps ensure consistent ENR quality and supports broader use of chemically modified natural rubber grades across rubber product applications where controlled epoxidation levels and reproducible physical properties are required.
Related standards
Relevant normative references cited in ISO 24483:2023 include:
- ISO 5260 (epoxidation by NMR), ISO 247-1, ISO 289-1, ISO 1656, ISO 1795, ISO 4660, ISO 20299-2; also ASTM D3418 and ISO 2000 for broader NR specification guidance.
Frequently Asked Questions
ISO 24483:2023 is a standard published by the International Organization for Standardization (ISO). Its full title is "Epoxidized natural rubber - Specifications". This standard covers: This document specifies the physical and chemical requirements of epoxidized natural rubber (ENR) based on the epoxidation level of the natural rubber.
This document specifies the physical and chemical requirements of epoxidized natural rubber (ENR) based on the epoxidation level of the natural rubber.
ISO 24483:2023 is classified under the following ICS (International Classification for Standards) categories: 83.060 - Rubber. The ICS classification helps identify the subject area and facilitates finding related standards.
You can purchase ISO 24483:2023 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of ISO standards.
Standards Content (Sample)
INTERNATIONAL ISO
STANDARD 24483
First edition
2023-04
Epoxidized natural rubber —
Specifications
Caoutchouc naturel époxydé — Spécifications
Reference number
© ISO 2023
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Published in Switzerland
ii
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Material composition .2
5 Grade structure . 2
6 Specification of requirement .2
7 Sampling . 3
8 Packaging. 3
Bibliography . 4
iii
Foreword
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electrotechnical standardization.
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This document was prepared by Technical Committee ISO/TC 45, Rubber and rubber products,
Subcommittee SC 3, Raw materials (including latex) for use in the rubber industry.
Any feedback or questions on this document should be directed to the user’s national standards body. A
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iv
Introduction
Significant developments have taken place in the supply of raw natural rubber, especially in relation to
the number of different grades that are technically specified. The constant viscosity (CV), latex (L) and
gel content (LoV) grades have been added in addition to the initial grades covered in the first edition
of ISO 2000. The development and availability of physical and/or chemically modified grades are now
reported in the technical literature with the aim to expand natural rubber (NR) applications in rubber
products. Demand and acknowledgment of these modified grades grow from year to year. On this note,
it is important to establish a standard reference for the specification related to these modified natural
rubber grades. In this document the emphasis is given to the epoxidized natural rubber (ENR) grade
produced through a chemical modification route on natural rubber.
This document encompasses natural raw rubber specification for ENR produced through a chemical
modification route known as epoxidation reaction. Typically, the most economical epoxidation reaction
route is through the in situ peracid method. Through the process the peracid is formed from hydrogen
peroxide and formic acid. The epoxidation reaction involves with substitution of the NR double bond
structure (C=C) with epoxy ring structure (C-O-C) which later determines the grade of the ENR rubber.
In general, any level of epoxidati
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