CEN/TR 16417:2016
(Main)Footwear - Footwear industry guideline for substances of very high concern (Annex XIV of REACH)
Footwear - Footwear industry guideline for substances of very high concern (Annex XIV of REACH)
This Technical Report is intended to provide information on the chemicals listed in the Candidate List / Annex XIV of the Regulation (EC) 1907/2006, also known as REACH (Regulation, Evaluation and Authorisation of Chemicals) and their usage and presence in the footwear industry.
The Annex XIV, overseen by the ECHA (European Chemicals Agency), is a list of substances subject to authorization, substances of very high concern (SVHC). Before the inclusion of a substance in the Annex XIV, the procedure is strictly fixed:
- A European member state shall propose it to ECHA.
- ECHA inform all the members’ state and a first enquiry is done in order to include the substance to the candidate list of Annex XIV.
- After the agreement of the member’s state, ECHA includes the substances in the candidate list to Annex XIV. As soon as a substance has been included in the candidate list, it should be taken into account exactly as a SVHC.
- ECHA prioritises the substances from the Candidate List to determine which ones should be included in the Authorisation List (Annex XIV of REACH) and therefore, subject to authorisation. ECHA regularly submits recommendations to the European Commission, who will decide on the substances to be included in the Authorisation List.
Following the evaluation of the Annex XIV substances, ECHA can take the decision to restrict the substances. This restriction may take the form of an authorization for use, an authorisation only for specific applications in specified fields or, in some cases, a complete ban on the use of the substance.
During the evaluation process, these chemicals are not forbidden or limited in use. The regulation requires that the user shall be informed if one or more of these substances are present in any part of the article in quantity over 0,1 % by weight.
This Technical Report shows which of these chemicals may be present in footwear materials and the footwear industry in order to help shoe manufacturers to collect mandatory information from suppliers regarding the content of these chemicals and, at same time, allow them to provide accurate information to their customers.
The test methods reported in Annex 1 are informative only to identify where these chemicals may be found and control the use along the supply chain where their suppliers are not under the jurisdiction of the REACH Regulation.
Taking into account final decision of the European Commission, ECHA, implements the Annex XIV and the candidate list to Annex XIV of REACH, regularly. This revision interval is difficult to follow by the standardization procedures.
Therefore this document reflects the situation at the date of June 2014. This document will be annually revised.
This Technical Report does not concern the substances for which restriction have been already enacted under Annex XVII of REACH.
NOTE Chemicals that are restricted under Annex XVII, are identified as a category 1 chemical in CEN ISO/TR 16178.
Schuhe - Leitfaden für die Schuhindustrie für sehr bedenkliche Substanzen (Anhang XIV von REACH)
Chaussures - Lignes directrice pour l’industrie de la chaussure relatives aux substances extrêmement préoccupantes (annexe XIV de REACH)
Le présent Rapport technique est destiné à fournir des informations sur les produits chimiques figurant dans la liste candidate / Annexe XIV du Règlement (CE) n° 1907/2006, également connu sous le nom de REACH (enregistrement, évaluation et autorisation des substances chimiques, ainsi que restrictions applicables à ces substances), ainsi que sur leur usage et leur présence dans l’industrie de la chaussure.
L’Annexe XIV, supervisée par l’ECHA (Agence européenne des produits chimiques), est une liste des substances soumises à autorisation et des substances extrêmement préoccupantes (SVHC). Avant d’inclure une substance dans l’Annexe XIV, le mode opératoire à suivre est établi de manière stricte :
— Un État membre européen doit la proposer à l’ECHA.
— L’ECHA en informe tous les États membres et une première enquête est menée afin d’inclure la substance à la liste candidate de l’Annexe XIV.
— Après accord des États membres, l’ECHA inclut la substance à la liste candidate de l’Annexe XIV. Dès qu’une substance a été incluse à la liste candidate, il convient de la prendre en compte exactement de la même manière qu’une SVHC.
— L’ECHA hiérarchise les substances de la liste candidate afin de déterminer celles qu’il convient d’inclure à la liste d’autorisation (Annexe XIV du REACH) et qui sont donc soumises à autorisation. L’ECHA soumet régulièrement des recommandations à la Commission européenne, qui décide ensuite des substances à inclure à la liste d’autorisation.
Après évaluation des substances figurant dans l’Annexe XIV, l’ECHA peut prendre la décision de limiter lesdites substances. Cette restriction peut prendre la forme d’une autorisation d’utilisation, d’une autorisation uniquement pour des applications spécifiques dans des domaines spécifiés ou, dans certains cas, d’une interdiction totale d’utilisation de la substance.
Au cours du processus d’évaluation, ces produits chimiques ne sont pas interdits ni leur utilisation limitée. Le règlement exige que l’utilisateur soit informé si une ou plusieurs de ces substances sont présentes dans une partie quelconque de l’article en quantité supérieure à 0,1 % en masse.
Le présent Rapport technique indique lesquels de ces produits chimiques peuvent être présents dans les matériaux de chaussures et dans l’industrie de la chaussure, afin d’aider les fabricants de chaussures à recueillir les informations obligatoires auprès des fournisseurs en ce qui concerne la teneur de ces produits chimiques et, dans le même temps, leur permettre de fournir des informations exactes à leurs clients.
Les méthodes d’essai mentionnées dans l’Annexe A sont informatives uniquement et servent à identifier où ces produits chimiques peuvent être présents et à maîtriser leur utilisation le long de la chaîne d’approvisionnement lorsque leurs fournisseurs ne sont pas sous la juridiction du Règlement REACH.
En tenant compte de la décision finale de la Commission européenne, l’ECHA met régulièrement à jour l’Annexe XIV et la liste candidate de l’Annexe XIV du REACH. Cet intervalle de révision est difficile à appliquer dans le cadre des procédures de normalisation.
Par conséquent, le présent document reflète la situation à la date de juin 2014. Le présent document sera révisé annuellement.
Le présent Rapport technique ne concerne pas les substances pour lesquelles une restriction est déjà en vigueur au titre de l’Annexe XVII du REACH.
Obutev - Smernica, namenjena obutveni industriji, o snoveh, ki zelo zbujajo skrb (Priloga XIV iz REACH)
To tehnično poročilo zagotavlja informacije o kemikalijah, navedenih na seznamu kandidatnih snovi/dodatku XIV Uredbe (ES) 1907/2006, poimenovane tudi REACH (Regulation, Evaluation and Authorisation of Chemicals; Registracija, evalvacija in avtorizacija kemikalij), ter o njihovi uporabi in prisotnosti v obutveni industriji.
Dodatek XIV, ki je pod nadzorom Evropske agencije za kemikalije (ECHA), je seznam snovi, ki čakajo na avtorizacijo, pri čemer gre za snovi, ki vzbujajo veliko zaskrbljenost (SVHC). Postopek vključitve snovi na seznam v dodatku XIV je strogo določen:
Država članica EU snov predlaga Evropski agenciji za kemikalije.
Evropska agencija za kemikalije obvesti vse države članice in izvede se prva raziskava za vključitev snovi na seznam kandidatnih snovi v dodatku XIV.
Evropska agencija za kemikalije po dogovoru z državo članico snovi vključi na seznam kandidatnih snovi v dodatku XIV. Takoj, ko je snov vključena na seznam kandidatnih snovi, naj bi jo obravnavali kot snov, ki vzbuja veliko zaskrbljenost.
Evropska agencija za kemikalije dodeljuje prednost snovem na seznamu kandidatnih snovi, da ugotovi, katere naj bi vključili na seznam za avtorizacijo (dodatek XIV uredbe REACH) in jih posledično avtorizirali. Evropska agencija za kemikalije svoja priporočila redno posreduje Evropski komisiji, ki odloči, katere snovi bodo vključene na seznam za avtorizacijo.
Po analizi snovi iz dodatka XIV Evropska agencija za kemikalije lahko sprejme sklep o omejitvah za snov. Ta omejitev je lahko implementirana kot avtorizacija za uporabo, avtorizacija zgolj za določene vrste in področja uporabe, ali v nekaterih primerih kot popolna prepoved za uporabo snovi.
V času analize kemikalij slednje niso prepovedane oziroma njihova uporaba ni omejena. Uredba zahteva, da je treba uporabnika obvestiti, če je ena ali več teh snovi prisotna v katerem koli delu izdelka v količini, večji od 0,1 % glede na težo izdelka.
To tehnično poročilo navaja, katere od teh kemikalij so lahko prisotne v materialu za obutev in obutveni industriji, s čimer proizvajalcem čevljev pomaga pri zbiranju obveznih informacij od dobaviteljev v zvezi z vsebnostjo teh kemikalij in jim obenem omogoča, da strankam zagotovijo natančne informacije.
Preskusne metode, navedene v dodatku A, so zgolj informativne narave in pomagajo določiti mesta prisotnosti teh kemikalij ter omogočajo nadzor uporabe v dobavni verigi, v kateri dobavitelji teh kemikalij niso v pristojnosti uredbe REACH.
Evropska agencija za kemikalije ob upoštevanju končne odločitve Evropske komisije redno implementira dodatek XIV in seznam kandidatnih snovi v dodatku XIV uredbe REACH. Standardizacijski postopki le stežka upoštevajo ta interval revizije,
zato ta dokument odraža položaj iz junija 2013. Ta dokument bo letno revidiran.
To tehnično poročilo ne zajema snovi, za katere je bila omejitev v skladu z dodatkom XVII uredbe REACH že uzakonjena.
OPOMBA: Kemikalije, omejene na podlagi dodatka XVII, so v standardu CEN ISO/TR 16178 opredeljene kot kemikalije 1. kategorije.
General Information
- Status
- Withdrawn
- Publication Date
- 12-Jan-2016
- Withdrawal Date
- 20-Jan-2026
- Technical Committee
- CEN/TC 309 - Footwear
- Drafting Committee
- CEN/TC 309/WG 2 - Footwear and environmental aspects
- Current Stage
- 9960 - Withdrawal effective - Withdrawal
- Start Date
- 03-Jul-2024
- Completion Date
- 21-Jan-2026
Relations
- Effective Date
- 20-Jan-2016
Frequently Asked Questions
CEN/TR 16417:2016 is a technical report published by the European Committee for Standardization (CEN). Its full title is "Footwear - Footwear industry guideline for substances of very high concern (Annex XIV of REACH)". This standard covers: This Technical Report is intended to provide information on the chemicals listed in the Candidate List / Annex XIV of the Regulation (EC) 1907/2006, also known as REACH (Regulation, Evaluation and Authorisation of Chemicals) and their usage and presence in the footwear industry. The Annex XIV, overseen by the ECHA (European Chemicals Agency), is a list of substances subject to authorization, substances of very high concern (SVHC). Before the inclusion of a substance in the Annex XIV, the procedure is strictly fixed: - A European member state shall propose it to ECHA. - ECHA inform all the members’ state and a first enquiry is done in order to include the substance to the candidate list of Annex XIV. - After the agreement of the member’s state, ECHA includes the substances in the candidate list to Annex XIV. As soon as a substance has been included in the candidate list, it should be taken into account exactly as a SVHC. - ECHA prioritises the substances from the Candidate List to determine which ones should be included in the Authorisation List (Annex XIV of REACH) and therefore, subject to authorisation. ECHA regularly submits recommendations to the European Commission, who will decide on the substances to be included in the Authorisation List. Following the evaluation of the Annex XIV substances, ECHA can take the decision to restrict the substances. This restriction may take the form of an authorization for use, an authorisation only for specific applications in specified fields or, in some cases, a complete ban on the use of the substance. During the evaluation process, these chemicals are not forbidden or limited in use. The regulation requires that the user shall be informed if one or more of these substances are present in any part of the article in quantity over 0,1 % by weight. This Technical Report shows which of these chemicals may be present in footwear materials and the footwear industry in order to help shoe manufacturers to collect mandatory information from suppliers regarding the content of these chemicals and, at same time, allow them to provide accurate information to their customers. The test methods reported in Annex 1 are informative only to identify where these chemicals may be found and control the use along the supply chain where their suppliers are not under the jurisdiction of the REACH Regulation. Taking into account final decision of the European Commission, ECHA, implements the Annex XIV and the candidate list to Annex XIV of REACH, regularly. This revision interval is difficult to follow by the standardization procedures. Therefore this document reflects the situation at the date of June 2014. This document will be annually revised. This Technical Report does not concern the substances for which restriction have been already enacted under Annex XVII of REACH. NOTE Chemicals that are restricted under Annex XVII, are identified as a category 1 chemical in CEN ISO/TR 16178.
This Technical Report is intended to provide information on the chemicals listed in the Candidate List / Annex XIV of the Regulation (EC) 1907/2006, also known as REACH (Regulation, Evaluation and Authorisation of Chemicals) and their usage and presence in the footwear industry. The Annex XIV, overseen by the ECHA (European Chemicals Agency), is a list of substances subject to authorization, substances of very high concern (SVHC). Before the inclusion of a substance in the Annex XIV, the procedure is strictly fixed: - A European member state shall propose it to ECHA. - ECHA inform all the members’ state and a first enquiry is done in order to include the substance to the candidate list of Annex XIV. - After the agreement of the member’s state, ECHA includes the substances in the candidate list to Annex XIV. As soon as a substance has been included in the candidate list, it should be taken into account exactly as a SVHC. - ECHA prioritises the substances from the Candidate List to determine which ones should be included in the Authorisation List (Annex XIV of REACH) and therefore, subject to authorisation. ECHA regularly submits recommendations to the European Commission, who will decide on the substances to be included in the Authorisation List. Following the evaluation of the Annex XIV substances, ECHA can take the decision to restrict the substances. This restriction may take the form of an authorization for use, an authorisation only for specific applications in specified fields or, in some cases, a complete ban on the use of the substance. During the evaluation process, these chemicals are not forbidden or limited in use. The regulation requires that the user shall be informed if one or more of these substances are present in any part of the article in quantity over 0,1 % by weight. This Technical Report shows which of these chemicals may be present in footwear materials and the footwear industry in order to help shoe manufacturers to collect mandatory information from suppliers regarding the content of these chemicals and, at same time, allow them to provide accurate information to their customers. The test methods reported in Annex 1 are informative only to identify where these chemicals may be found and control the use along the supply chain where their suppliers are not under the jurisdiction of the REACH Regulation. Taking into account final decision of the European Commission, ECHA, implements the Annex XIV and the candidate list to Annex XIV of REACH, regularly. This revision interval is difficult to follow by the standardization procedures. Therefore this document reflects the situation at the date of June 2014. This document will be annually revised. This Technical Report does not concern the substances for which restriction have been already enacted under Annex XVII of REACH. NOTE Chemicals that are restricted under Annex XVII, are identified as a category 1 chemical in CEN ISO/TR 16178.
CEN/TR 16417:2016 is classified under the following ICS (International Classification for Standards) categories: 61.060 - Footwear. The ICS classification helps identify the subject area and facilitates finding related standards.
CEN/TR 16417:2016 has the following relationships with other standards: It is inter standard links to CEN/TR 16417:2012. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
CEN/TR 16417:2016 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.
Standards Content (Sample)
SLOVENSKI STANDARD
kSIST-TP FprCEN/TR 16417:2014
01-november-2014
Obutev – Smernica, namenjena obutveni industriji, o snoveh, ki zelo zbujajo skrb
(Priloga XIV iz REACH)
Footwear - Footwear industry guideline for substances of very high concern (Annex XIV
of REACH)
Schuhe - Leitfaden für die Schuhindustrie für sehr bedenkliche Substanzen (Anhang XIV
von REACH)
Chaussures - Lignes directrice de l’industrie de la chaussure concernant les substances
extrêmement préoccupantes (annexe XIV de REACH)
Ta slovenski standard je istoveten z: FprCEN/TR 16417
ICS:
61.060 Obuvala Footwear
kSIST-TP FprCEN/TR 16417:2014 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
kSIST-TP FprCEN/TR 16417:2014
kSIST-TP FprCEN/TR 16417:2014
TECHNICAL REPORT
FINAL DRAFT
FprCEN/TR 16417
RAPPORT TECHNIQUE
TECHNISCHER BERICHT
September 2014
ICS 61.060 Will supersede CEN/TR 16417:2012
English Version
Footwear - Footwear industry guideline for substances of very
high concern (Annex XIV of REACH)
Chaussures - Lignes directrice de l'industrie de la Schuhe - Leitfaden für die Schuhindustrie für sehr
chaussure concernant les substances extrêmement bedenkliche Substanzen (Anhang XIV von REACH)
préoccupantes (annexe XIV de REACH)
This draft Technical Report is submitted to CEN members for Technical Committee Approval. It has been drawn up by the Technical
Committee CEN/TC 309.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are aware and to
provide supporting documentation.
Warning : This document is not a Technical Report. It is distributed for review and comments. It is subject to change without notice and
shall not be referred to as a Technical Report.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. FprCEN/TR 16417:2014 E
worldwide for CEN national Members.
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
Contents Page
Foreword .3
1 Scope .4
2 Terms and definitions .5
3 SVHC potentially present in the footwear industry .6
3.1 General .6
3.2 SVHC included in Annex XIV of REACH .6
3.3 SVHC included in the candidate list of Annex XIV of REACH . 10
Annex A (informative) Available test methods for the identification of the substances of very high
concern given in the future REACH- Annex XIV . 29
Bibliography . 41
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
Foreword
This document (FprCEN/TR 16417:2014) has been prepared by Technical Committee CEN/TC 309
“Footwear”, the secretariat of which is held by AENOR.
This document is currently submitted to the Technical Committee Approval.
This document will supersede CEN/TR 16417:2012.
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
1 Scope
This Technical Report is intended to provide information on the chemicals listed in the Candidate List /
Annex XIV of the Regulation (EC) 1907/2006, also known as REACH (Regulation, Evaluation and
Authorisation of Chemicals) and their usage and presence in the footwear industry.
The Annex XIV, overseen by the ECHA (European Chemicals Agency), is a list of substances subject to
authorization, substances of very high concern (SVHC). Before the inclusion of a substance in the Annex XIV,
the procedure is strictly fixed :
A European member state shall propose it to ECHA.
ECHA inform all the members’ state and a first enquiry is done in order to include the substance to the
candidate list of Annex XIV.
After the agreement of the member’s state, ECHA includes the substances in the candidate list to Annex XIV.
As soon as a substance has been included in the candidate list, it should be taken into account exactly as a
SVHC.
ECHA prioritizes the substances from the Candidate List to determine which ones should be included in the
Authorisation List (Annex XIV of REACH) and therefore, subject to authorization. ECHA regularly submits
recommendations to the European Commission, who will decide on the substances to be included in the
Authorisation List.
Following the evaluation of the Annex XIV substances, ECHA can take the decision to restrict the substances.
This restriction may take the form of an authorization for use, an authorization only for specific applications in
specified fields or, in some cases, a complete ban on the use of the substance.
During the evaluation process, these chemicals are not forbidden or limited in use. The regulation requires
that the user shall be informed if one or more of these substances are present in any part of the Article in
quantity over 0,1% by weight.
This Technical Report shows which of these chemicals may be present in footwear materials and the footwear
industry in order to help shoe manufacturers to collect mandatory information from suppliers regarding the
content of these chemicals and, at same time, allow them to provide accurate information to their customers.
The test methods reported in Annex A are informative only to identify where these chemicals may be found
and control the use along the supply chain where their suppliers are not under the jurisdiction of the REACH
Regulation.
Taking into account final decision of the European Commission, ECHA, implements the Annex XIV
and the candidate list to Annex XIV of REACH, regularly. This revision interval is difficult to follow by
the standardization procedures.
Therefore, this document reflects the situation at the date of June 2013. This document will be
annually revised.
This Technical Report does not concern the substances for which restriction have been already enacted under
Annex XVII of REACH.
NOTE Chemicals that are restricted under Annex XVII, are identified as a category 1 chemical in
CEN ISO/TR 16178.
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
2 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
2.1
Very Persistent and Very Bioaccumulative substance
vPvB
substance that fulfils the criteria of both the sections below:
a) Persistence
1) the half-life in marine, fresh- or estuarine water is higher than 60 d, or
2) the half-life in marine, fresh- or estuarine water sediment is higher than 180 d, or
3) the half-life in soil is higher than 180
b) Bioaccumulation
1) the bioconcentration factor is greater than 5 000
2.2
Persistent, Bioaccumulative and Toxic substance
PBT
substance that fulfils all three of the criteria of the sections below:
a) Persistence
1) the half-life in marine water is higher than 60 d, or
2) the half-life in fresh- or estuarine water is higher than 40 d, or
3) the half-life in marine sediment is higher than 180 d, or
4) the half-life in fresh- or estuarine water sediment is higher than 120 d, or
5) the half-life in soil is higher than 120 d
b) Bioaccumulation
1) the bioconcentration factor (BCF) is higher than 2 000
c) Toxicity
1) the long-term no-observed effect concentration (Noec) for marine or freshwater organisms is less
than 0,01 mg/l, or
2) the substance is classified as carcinogenic (category 1 or 2), mutagenic (category 1 or 2) or toxic for
reproduction (category 1, 2, or 3), or
3) there is other evidence of chronic toxicity, as identified by the classifications: T, R48, or Xn, R48
according to Directive 67/548/EEC
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
3 SVHC potentially present in the footwear industry
3.1 General
The following subclauses contain tables with the substances of very high concern (SVHC) that could be found
in the footwear or in the footwear components.
3.2 SVHC included in Annex XIV of REACH
Table 1 includes the substances of very high concern included, at the moment of publication of this Technical
th
Report, in Annex XIV of REACH (see Regulation (EU) N°348/2013 17 April 2013).
Table 1 — Identification of substances of very high concern included in Annex XIV of REACH —
th
Regulation (EU) N°348/2013 17 April 2013
CAS EC Reason for Occurrence
Substance name Group
number number inclusion in Footwear
Not used in
5-tert-butyl-2,4,6-trinitro- 201-329- vPvB (Article footwear or
1.1 81-15-2
m-xylene (musk xylene) 4 57e) footwear
components
Not used as a
free
compound
This
substance
can be
detected after
the
degradation
of:
4,4’- 202-974- Carcinogenic
azo colorant,
1.2 101-77-9 Aryl amine
Diaminodiphenylmethane 4 (Article 57a)
see Annex
XVII of
Reach)
PU material,
(false positive
result is
possible,
generated as
a marker in
testing of PU
material)
25637-
99-4 and
Not used in
3194-55-
Hexabromocyclododecane
247-148- footwear or
(HBCDD) and all major
4 footwear
diastereoisomers PBT (Article
and components
(134237-
1.3
identified 57d)
51-7,
221-695- (flame
(α – HBCDD, β-HBCDD,
134237-
9 retardant for
γ-HBCDD)
50-6,
electronics)
134237-
52-8)
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
CAS EC Reason for Occurrence
Substance name Group
number number inclusion in Footwear
Possible
Bis (2- Toxic for
(concentration
204-211-
a
1.4 ethyl(hexyl)phthalate) 117-81-7 phthalate reproduction
higher than
(DEHP) (Article 57c)
0,1%
possible)
Possible
Toxic for
(concentration
Benzyl butyl phthalate 201-622-
a
1.5 85-68-7 phthalate reproduction
higher than
(BBP) 7
(Article 57c)
0,1%
possible)
Possible
Toxic for
(concentration
201-557-
a
1.6 Dibutyl phthalate (DBP) 84-74-2 phthalate reproduction
higher than
(Article 57c)
0,1%
possible)
Not used in
2,4 – Dinitrotoluene (2,4- 204-450- Aromatic Carcinogenic footwear or
1.7 121-14-2
DNT) 0 hydrocarbons (Article 57a) footwear
components
Not used in
footwear or
footwear
components
Tris(2- Tris(2- Toxic for
204-118-
1.8 chloroethyl)phosphate 115-96-8 chloroethyl)phosphate reproduction
(flame
(TCEP) (TCEP) (Article 57c)
retardant for
furniture,
plasticizer for
PU-PVC)
Not used in
1303-28- 215-116- Carcinogenic footwear or
1.9 Diarsenic pentaoxide Arsenic compounds
2 9 (Article 57a) footwear
components
Carcinogenic possible
and toxic for pigment in
Lead sulfochromate yellow 1344-37- 215-693- Substances
a
1.10 reproduction certain
(C.I. Pigment Yellow 34) 2 7 containing lead
(Articles 57 a surface
and 57 c) coating
Carcinogenic possible
Lead chromate molybdate and toxic for pigment in
12656- 235-759- Substances
a
1.11 sulphate red (C.I. Pigment reproduction certain
85-8 9 containing lead
Red 104) (Articles 57 a surface
and 57 c) coating
Not used in
1327-53- 215-481- Carcinogenic
footwear or
1.12 Diarsenic trioxide Arsenic compounds
3 4 (Article 57a) footwear
components
Carcinogenic possible
a 7758-97- 231-846- Substances
1.13 Lead chromate
and toxic for pigment in
6 0 containing chromate
reproduction certain
kSIST-TP FprCEN/TR 16417:2014
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CAS EC Reason for Occurrence
Substance name Group
number number inclusion in Footwear
(Articles 57 a surface
and 57 c) coating
Possible
Toxic for
(concentration
a Diisobutyl phthalate 201-553-
1.14 84-69-5 phthalate reproduction
higher than
(DIBP) 2
(Article 57c)
0,1%
possible)
Solvent used
in not
flammable
adhesive,
volatile
product can
be present
201-167- Carcinogenic
only as a
1.15 Trichloroethylene 79-01-6 Chlorinated aliphates
4 (Article 57 a)
residue.
More possible
to detect in
the packaging
of footwear
than in the
footwear itself
Not used in
footwear or
Carcinogenic
footwear
and
1333-82- 215-607- Substances components
1.16 Chromium trioxide mutagenic
0 8 containing chromium (Cr VI
(Articles 57a
possible in
and 57b)
leather at low
concentration)
Not used in
7738-94- footwear or
231-801-
5, footwear
Chromic acid, Dichromic 5, 236-
Substances Carcinogenic
13530- components
1.17 acid, Oligomers of chromic 881-5,
68-2, not containing chromium (Article 57a) (Cr VI
acid and dichromic acid not yet
yet possible in
assigned
assigned leather at low
concentration)
Not used in
Carcinogenic, footwear or
7789-12-
mutagenic footwear
0 and 234-190- Substances and toxic for components
1.18 Sodium dichromate
10588- 3 containing chromate reproduction (Cr VI
01-9 (Articles 57a, possible in
57b and 57c) leather at low
concentration)
Carcinogenic, Not used in
mutagenic footwear or
7778-50- 231-906- Substances
and toxic for footwear
1.19 Potassium dichromate
9 6 containing chromate
reproduction components
(Articles 57a, (Cr VI
57b possible in
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CAS EC Reason for Occurrence
Substance name Group
number number inclusion in Footwear
and 57c) leather at low
concentration)
Not used in
Carcinogenic,
footwear or
mutagenic
footwear
and toxic for
7789-09- 232-143- Substances components
1.20 Ammonium dichromate reproduction
5 1 containing chromate (Cr VI
(Articles 57a,
possible in
57b
leather at low
and 57c)
concentration)
Not used in
footwear or
Carcinogenic
footwear
and
7789-00- 232-140- Substances
components
1.21 Potassium chromate mutagenic
6 5 containing chromate (Cr VI
(Articles 57a
possible in
and 57b).
leather at low
concentration)
Not used in
Carcinogenic,
footwear or
mutagenic
footwear
and toxic for
7775-11- 231-889- Substances components
1.22 Sodium chromate reproduction
3 5 containing chromate (Cr VI
(Articles 57 a,
possible in
57 b
leather at low
and 57 c)
concentration)
a
These substances are especially important for footwear and footwear components.
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3.3 SVHC included in the candidate list of Annex XIV of REACH
The following tables include the substances of very high concern included, at the moment of publication of this
technical report, in the candidate list of Annex XIV of REACH. Different tables have been drafted to identify
the date of inclusion in the candidate list.
Table 2 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 28 October 2008
ID Substance name CAS EC Group Reason for Occurrence in
Number Number inclusion Footwear
2.1 Bis(tributyltin) 56-35-9 200-268-0 Substances PBT (Article Not used in
oxide (TBTO) containing tin 57d) footwear or
footwear
components
Use in the
pass as a
preservative
agent
a
2.2 Anthracene 120-12-7 204-371-1 PAHs PBT (Article PAH
57d) compound
Possible
contaminant
(recycled
materials or
leather fat
liquor)
2.3 Lead hydrogen 7784-40-9 232-064-2 Arsenic Carcinogenic Not used in
arsenate compounds and toxic for footwear or
reproduction footwear
(Articles 57 a components
and 57 c)
2.4 Triethyl arsenate 15606-95- 427-700-2 Arsenic Carcinogenic Not used in
8 compounds (Article 57a) footwear or
footwear
components
a
2.8 Alkanes, C10- 85535-84- 287-476-5 Chlorinated PBT and vPvB Possible
13,chloro [Short 8 aliphates (Articles 57 d
(flame
Chain and 57 e)
retardant for
Chlorinated
textile or fat
paraffins] (SCCP)
liquor for
leather)
a
These substances are especially important for footwear and footwear components.
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Table 3 — Identification of substances of very high concern included in the candidate list for
th
January 2010
Annex XIV of REACH — Dates of inclusion 13
ID Substance name CAS EC Group Reason for Occurrence in
Numb Number inclusion Footwear
er
3.1 Coal tar pitch, high 65996- 266-028- PAHs Carcinogenic, Not used in
temperature 93-2 2 PBT and vPvB footwear or
(Articles 57a, 57d footwear
and 57e) components
3.5 Anthracene oil 90640- 292-602- PAHs Carcinogenic[1], Not used in
80-5 7 PBT and vPvB footwear or
(Articles 57a, 57d footwear
and 57e) components
3.6 Anthracene oil, 91995- 295-278- PAHs Carcinogenic[2],
anthracene paste, 17-4 5 mutagenic[3],
distn. Lights PBT and vPvB
(Articles 57a,
57b, 57d and
57e)
3.7 Anthracene oil, 91995- 295-275- PAHs Carcinogenic[2],
anthracene paste, 15-2 9 mutagenic[3],
anthracene fraction PBT and vPvB
(Articles 57a,
57b, 57d and
57e)
3.8 Anthracene oil, 90640- 292-604- PAHs Carcinogenic[2],
anthracene-low 82-7 8 mutagenic[3],
PBT and vPvB
(Articles 57a,
57b, 57d and
57e)
3.9 Anthracene oil, 90640- 292-603- PAHs Carcinogenic[2],
anthracene paste 81-6 2 mutagenic[3],
PBT and vPvB
(Articles 57a,
57b, 57d and
57e)
3.10 Aluminosilicate — — Refractory Carcinogenic Not used in
Refractory Ceramic Ceramic (Article 57a) footwear or
Fibres Fibres footwear
components
3.11 Zirconia — — Refractory Carcinogenic Not used in
Aluminosilicate Ceramic (Article 57a) footwear or
Refractory Ceramic Fibres footwear
Fibres components
a
These substances are especially important for footwear and footwear components.
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Table 4 — Identification of substances of very high concern included in the candidate list for
th
March 2010
Annex XIV of REACH — Dates of inclusion 30
ID Substance CAS Number EC Group Reason for Occurrence in
name Number inclusion Footwear
4.1 Acrylamide 79-06-1 201- Amides Carcinogenic Not used in
173-7 and mutagenic footwear or
(Articles 57a footwear
and 57b) components
(possible in
polymers not
fully
polymerized)
Table 5 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 18 June 2010
ID Substance CAS EC Group Reason for Occurrence in
name Number Number inclusion Footwear
5.2 Disodium 1303-96-4, 215- Substances Toxic for Not used in
tetraborate 1330-43-4, 540-4 containing reproduction footwear or
anhydrous 12179-04-3 boron (Article 57c) footwear
components
(leather:
possible traces,
use for the
preservation of
raw hides
Flame retardant
for plastics)
5.3 Boric acid 10043-35-3, 233- Substances Toxic for Not used in
11113-50-1 139-2, containing reproduction footwear or
234- boron (Article 57c) footwear
343-4 components
(leather:
possible traces,
use for the
preservation of
raw hides
Flame retardant
for plastics)
5.8 Tetraboron 12267-73-1 235- Substances Toxic for Not used in
disodium 541-3 containing reproduction footwear or
heptaoxide boron (Article 57c) footwear
hydrate components
(leather :
possible traces,
use for the
preservation of
raw hides
Flame retardant
for plastics)
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Table 6 — Identification of substances of very high concern included in the candidate list for
th
December 2010
Annex XIV of REACH — Date of inclusion 15
ID Substance name CAS EC Group Reason for Occurrence in
Number Numbe inclusion Footwear
r
6.3 2-Ethoxyethanol; 110-80-5 203- Dihydroxy Toxic for Not used in footwear
Ethylene glycol 804-1 ethers reproduction or footwear
monoethyl ether (Article 57c) components
(EGEE)
(possible in certain
leather finishing at
low levels)
6.4 2-Methoxyethanol; 109-86-4 203- Dihydroxy Toxic for Not used in footwear
Ethylene glycol 713-7 ethers reproduction or footwear
monomethyl ether (Article 57c) components
(EGME)
(possible in certain
leather finishing at
low levels)
6.5 Cobalt (di)acetate 71-48-7 200- Substances Carcinogenic and Not used in footwear
755-8 containing toxic for or footwear
cobalt reproduction components
(Articles 57a and
57c)
6.6 Cobalt carbonate 513-79-1 208- Substances Carcinogenic and Not used in footwear
169-4 containing toxic for or footwear
cobalt reproduction components
(Articles 57a and
57c)
6.7 Cobalt dinitrate 10141-05- 233- Substances Carcinogenic and Not used in footwear
6 402-1 containing toxic for or footwear
cobalt reproduction components
(Articles 57a and
57c)
6.8 Cobalt sulphate 10124-43- 233- Substances Carcinogenic and Not used in footwear
3 334-2 containing toxic for or footwear
cobalt reproduction components
(Articles 57a and
57c)
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Table 7 — Identification of substances of very high concern included in the candidate list for
th
June 2011
Annex XIV of REACH — Date of inclusion 20
ID Substance name CAS Number EC Group Reason for Occurrence in
Number inclusion Footwear
a
7.1 1,2-Benzenedicarboxylic 71888-89-6 276-158-1 Phthalates Toxic for Theoretically
acid, di-C6-8-branched reproduction possible
alkyl esters, C7-rich (Article 57c)
Practically
(DIHP)
never has been
detected in
footwear or
footwear
components
7.2 1,2,3-trichloropropane 96-18-4 202-486-1 Chlorinated Carcinogenic and Solvent in
aliphates toxic for rubber industry
reproduction volatile product,
(Articles 57a traces can be
and 57c) present only as
a residue.
a
7.3 N-methyl-2-pyrrolidone; 872-50-4 212-828-1 Nitrogen Toxic for Solvent used in
containing reproduction leather industry
1-methyl-2-pyrrolidone
heterocycles (Article 57c)
(concentration
higher than
0,1% possible)
7.4 Hydrazine 302-01-2 206-114-9 Other Carcinogenic Basic chemical
substances (Article 57a) for synthesis
Not used in
footwear or
footwear
components
7.5 Cobalt dichloride 7646-79-9 231-589-4 Substances Carcinogenic and Not used in
containing toxic for footwear or
cobalt reproduction footwear
(Articles 57a components
and 57c)
a
7.6 1,2-Benzenedicarboxylic 68515-42-4 271-084-6 Phthalates Toxic for Theoretically
acid, di-C7-11-branched reproduction possible
and linear alkyl esters (Article 57c)
Practically
never has been
detected in
footwear or
footwear
components
7.7 Strontium chromate 7789-06-2 232-142-6 Substances Carcinogenic Not used in
containing (Article 57a) footwear or
chromate footwear
components
(Cr VI possible
in leather at low
concentration)
7.8 2-Ethoxyethyl acetate 111-15-9 203-839-2 Dihydroxy Toxic for Solvent
ethers reproduction
volatile product,
(Article 57c)
traces can be
present only as
a residue.
a
These substances are especially important for footwear and footwear components.
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Table 8 — Identification of substances of very high concern included in the candidate list for
th
December 2011
Annex XIV of REACH — Date of inclusion 20
ID Substance name CAS EC Group Reason for Occurrence in
Number Number inclusion Footwear
a
8.1 4-(1,1,3,3- 140-66-9 205-426-2 Alkyl phenols Toxic for Used as surfactant in
tetramethylbutyl)phe and their reproduction leather and textile
nol, ethoxylates (Article 57c) industry
(4-tert-Octylphenol)
Only low level residue
will be expected (less
than 0,1%
8.2 2-Methoxyaniline; 90-04-0 201-963-1 Aryl amine Carcinogen, Not used as a free
o-Anisidine cat. 2 compound
This substance can
be detected after the
degra-dation of :azo
colorant,
see Annex XVII of
Reach)
Only low level residue
will be expected (less
than 0,1%
8.3 Arsenic acid 7778-39- 231-901-9 Arsenic Carcinogenic Not used in footwear
4 compounds (Article 57a) or footwear
components
8.4 Calcium arsenate 7778-44- 231-904-5 Arsenic Carcinogenic Not used in footwear
1 compounds (Article 57a) or footwear
components
8.5 Trilead diarsenate 3687-31- 222-979-5 Arsenic Carcinogenic Not used in footwear
8 compounds (Article 57a) or footwear
components
8.6 1,2-Dichloroethane; 107-06-2 203-458-1 Chlorinated Carcinogenic Solvent used in not
ethylene dichloride aliphate (Article 57a) flammable adhesive,
volatile product can
be present only as a
residue.
More possible to
detect in the
packaging of
footwear than in the
footwear itself.
8.7 Bis(2-methoxyethyl) 111-96-6 203-924-4 Dihydroxy Carcinogenic Not used in footwear
ether ether (Article 57a) or footwear
components volatile
product, traces can
be present only as a
residue.
a
8.8 Bis(2-methoxyethyl) 117-82-8 204-212-6 Phthalate Toxic for Possible
phthalate reproduction
(concentration higher
(Article 57c)
than 0,1% possible)
8.9 N,N- 127-19-5 204-826-4 Amide Carcinogenic Solvent used in
dimethylacetamide synthetic textile
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ID Substance name CAS EC Group Reason for Occurrence in
Number Number inclusion Footwear
(DMAC) (Article 57a) industry and in
leather finishing
Only low level residue
will be expected (less
than 0,1%.
8.10 Formaldehyde, 25214- 500-036-1 aldehyde Carcinogenic reaction products
oligomeric reaction 70-4 (Article 57a)
Not used in footwear
products with aniline
or footwear
(technical MDA)
components
8.11 Lead diazide; Lead 13424- 236-542-1 Substances Carcinogenic Not used in footwear
azide 46-9 containing and toxic for or footwear
lead reproduction components
(Articles 57a
and 57c)
8.12 Lead styphnate 15245- 239-290-0 Substances Carcinogenic Not used in footwear
44-0 containing and toxic for or footwear
lead reproduction components
(Articles 57a
and 57c)
8.13 2,2'-dichloro-4,4'- 101-14-4 202-918-9 Aryl amine Carcinogenic Used as a curing
a
methylenedianiline (Article 57a) agent in PU industry,
(MOCA) Possible in certain
technical PU
Only low level residue
will be expected (less
than 0,1%
8.14 Dichromium 24613- 246-356-2 Substances Carcinogenic Not used in footwear
tris(chromate) 89-6 containing (Article 57a) or footwear
chromium components
(Cr VI possible in
leather at low
concentration)
8.15 Potassium 11103- 234-329-8 Substances Carcinogenic Not used in footwear
hydroxyoctaoxodizin 86-9 containing (Article 57a) or footwear
catedichromate chromate components
(Cr VI possible in
leather at low
concentration)
8.16 Pentazinc chromate 49663- 256-418-0 Substances Carcinogenic Not used in footwear
octahydroxide 84-5 containing (Article 57a) or footwear
chromium components
(Cr VI possible in
leather at low
concentration)
8.17 Phenolphthalein 77-09-8 201-004-7 Aromatic Carcinogenic Not used in footwear
hydrocarbons (Article 57a) or footwear
components
8.18 Aluminosilicate — — Refractory Carcinogenic Not used in footwear
Refractory Ceramic Ceramic (Article 57a) or footwear
Fibres Fibres components
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ID Substance name CAS EC Group Reason for Occurrence in
Number Number inclusion Footwear
8.19 Zirconia — — Refractory Carcinogenic Not used in footwear
Aluminosilicate Ceramic (Article 57a) or footwear
Refractory Ceramic Fibres components
Fibres
8.20 Lead dipicrate 6477-64- 229-335-2 Substances Carcinogenic Not used in footwear
1 containing and toxic for or footwear
lead reproduction components
(Articles 57a
and 57c)
a
These substances are especially important for footwear and footwear components.
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Table 9 — Identification of substances of very high concern included in the candidate list for
th
June 2012
Annex XIV of REACH — Date of inclusion 18
ID Substance name CAS EC Number Group Reason for Occurrence
Number inclusion in Footwear
9.1 α,α-Bis[4-(dimethylamino)phenyl]-4 6786-83-0 229-851-8 colorant Carcinogenic Complex
(phenylamino)naphthalene-1-methanol (Article 57a) mixture not
(C.I. Solvent Blue 4) [with ≥ 0.1% of used in
Michler's ketone (EC No. 202-027-5) or footwear or
Michler's base (EC No. 202-959-2)] footwear
components
(However, C.I.
Solvent Blue 4
can be found
in plastics,
paper,
paperboard)
9.2 1,3,5-tris[(2S and 2R)-2,3- 59653-74-6 423-400-0 Mutagenic Not used in
epoxypropyl]-1,3,5-triazine-2,4,6- (Article 57b) footwear or
(1H,3H,5H)-trione (β-TGIC) footwear
components
9.3 N,N,N',N'-tetramethyl-4,4'- 101-61-1 202-959-2 Carcinogenic Not used in
methylenedianiline (Michler’s base) (Article 57a) footwear or
footwear
components
9.4 Diboron trioxide 1303-86-2 215-125-8 Substances Toxic for Not used in
containing reproduction footwear or
boron (Article 57 c) footwear
components
9.5 1,2-bis(2-methoxyethoxy)ethane 112-49-2 203-977-3 solvant Toxic for Used as a
(TEGDME; triglyme) reproduction solvent for
(Article 57 c) certain dyes
Only low level
residue will be
expected (less
than 0,1%
a
9.6 Formamide 75-12-7 200-842-0 Toxic for Possible at
reproduction more than
(Article 57 c) 0.1% for EVA
materials
9.7 4,4'-bis(dimethylamino)-4''- 561-41-1 209-218-2 colorant Carcinogenic Complex
(methylamino)trityl alcohol [with ≥ 0.1% (Article 57a) mixture not
of Michler's ketone (EC No. 202-027-5) used in
or Michler's base (EC No. 202-959-2)] footwear or
footwear
(solvent violet 8)
components
(However, C.I.
Solvent Blue 4
can be found
in plastics,
paper,
paperboard
9.8 Lead(II) bis(methanesulfonate) 17570-76-2 401-750-5 Substances Toxic for Not used in
containing reproduction footwear or
lead (Article 57 c) footwear
components
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9.9 [4-[4,4'-bis(dimethylamino) 548-62-9 208-953-6 colorant Carcinogenic Complex
benzhydrylidene]cyclohexa-2,5-dien-1- (Article 57a) mixture not
ylidene]dimethylammonium chloride used in
(C.I. Basic Violet 3) [with ≥ 0.1% of footwear or
Michler's ketone (EC No. 202-027-5) or footwear
Michler's base (EC No. 202-959-2)] components
(However C.I.
Solvent Blue 4
can be found
in plastics,
paper,
paperboard
9.10 1,2-dimethoxyethane; ethylene glycol 110-71-4 203-794-9 solvent Toxic for Used as a
dimethyl ether (EGDME) reproduction solvent for
(Article 57 c) certain dyes
Only low level
residue will be
expected (less
than 0,1%
9.11 [4-[[4-anilino-1-naphthyl][4- 2580-56-5 219-943-6 colorant Carcinogenic Complex
(dimethylamino)phenyl]methylene]cyclo (Article 57a) mixture not
hexa-2,5-dien-1-ylidene] used in
dimethylammonium chloride (C.I. Basic footwear or
Blue 26) [with ≥ 0.1% of Michler's footwear
ketone (EC No. 202-027-5) or Michler's components
base (EC No. 202-959-2)]
(However C.I.
Basic Blue 26
can be found
in textile
9.12 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5- 2451-62-9 219-514-3 Mutagenic Not used in
triazinane-2,4,6-trione (TGIC) (Article 57b) footwear or
footwear
components
9.13 4,4'-bis(dimethylamino)benzophenone 90-94-8 202-027-5 Carcinogenic Not used in
(Michler’s ketone) (Article 57a) footwear or
footwear
components
a
These substances are especially important for footwear and footwear components.
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Table 10 — Identification of substances of very high concern included in the candidate list for
th
December 2012
Annex XIV of REACH — Date of inclusion 19
ID Substance name CAS EC Group Reason for Occurrence
Number Number inclusion in Footwear
10.1 Hexahydromethylphthalic 25550- 247-094- Equivalent Not used in
anhydride [1], Hexahydro-4- 51-0, 1, 243- level of footwear or
methylphthalic anhydride [2], 19438- 072-0, concern footwear
Hexahydro-1-methylphthalic 60-9, 256-356- having components
anhydride [3], Hexahydro-3- 48122- 4, 260- probable
methylphthalic anhydride [4] 14-1, 566-1 serious
[The individual isomers [2], [3] 57110- effects to
and [4] (including their cis- 29-9 human
and trans- stereo isomeric health
forms) and all possible (Article 57 f)
combinations of the isomers
[1] are covered by this entry]
10.2 6-methoxy-m-toluidine (p- 120-71-8 204-419- Aryl amine Carcinogenic Not used as a
cresidine) 1 (Article 57a) free
compound
This
substance
can be
detected after
the
degradation
of :azo
colorant,
see annex
XVII of
Reach)
Only low level
residue will be
expected
(less than
0,1%
10.3 Cyclohexane-1,2-dicarboxylic 85-42-7, 201-604- Equivalent Not used in
anhydride [1], cis- 13149- 9, 236- level of footwear or
cyclohexane-1,2-dicarboxylic 00-3, 086-3, concern footwear
anhydride [2], trans- 14166- 238-009- having components
cyclohexane-1,2-dicarboxylic 21-3 9 probable
anhydride [3] [The individual serious
cis- [2] and trans- [3] isomer effects to
substances and all possible human
combinations of the cis- and health
trans-isomers [1] are covered (Article 57 f)
by this entry]
10.4 Pyrochlore, antimony lead 8012-00- 232-382- Substances Toxic for Not used in
yellow 8 1 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.5 Henicosafluoroundecanoic 2058-94- 218-165- vPvB (Article Not used in
acid 8 4 57 e) footwear or
footwear
components
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ID Substance name CAS EC Group Reason for Occurrence
Number Number inclusion in Footwear
10.6 4-Aminoazobenzene 60-09-3 200-453- Aryl amine Carcinogenic Not used as a
6 (Article 57a) free
compound
This
substance
can be
detected after
the
degradation
of :azo
colorant,
see Annex
XVII of
Reach)
Only low level
residue will be
expected
(less than
0,1%
10.7 Silicic acid, lead salt 11120- 234-363- Substances Toxic for Not used in
22-2 3 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.8 Lead titanium zirconium oxide 12626- 235-727- Substances Toxic for Not used in
81-2 4 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.9 Lead monoxide (lead oxide) 1317-36- 215-267- Toxic for Not used in
8 0 reproduction footwear or
(Article 57 c) footwear
components
10.10 o-Toluidine 95-53-4 202-429- Aryl amine Carcinogenic Not used as a
0 (Article 57a) free
compound
This
substance
can be
detected after
the
degradation
of :azo
colorant,
see Annex
XVII of
Reach)
Only low level
residue will be
expected
(less than
0,1%
a
10.11 3-ethyl-2-methyl-2-(3- 143860- 421-150- Toxic for Possible at
methylbutyl)-1,3-oxazolidine 04-2 7 reproduction more than
(Article 57 c) 0.1% for
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ID Substance name CAS EC Group Reason for Occurrence
Number Number inclusion in Footwear
Polyurethane
materials
a
10.12 Dibutyltin dichloride (DBTC) 683-18-1 211-670- organotin Toxic for Stabilizer or
0 reproduction catalyst of
(Article 57 c) polymers
10.13 Lead bis(tetrafluoroborate) 13814- 237-486- Substances Toxic for Not used in
96-5 0 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.14 Lead dinitrate 10099- 233-245- Substances Toxic for Not used in
74-8 9 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.15 Silicic acid (H2Si2O5), barium 68784- 272-271- Substances Toxic for Not used in
salt (1:1), lead-doped 75-8 5 containing reproduction footwear or
[with lead (Pb) content above lead (Article 57 c) footwear
the applicable generic components
concentration limit for ’toxicity
for reproduction’ Repr. 1A
(CLP) or category 1 (DSD);
the substance is a member of
the group entry of lead
compounds, with index
number 082-001-00-6 in
Regulation (EC) No
1272/2008]
10.16 Trilead 1319-46- 215-290- Substances Toxic for Not used in
bis(carbonate)dihydroxide 6 6 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.17 4,4'-methylenedi-o-toluidine 838-88-0 212-658- Aryl amine Carcinogenic Not used as a
8 (Article 57a) free
compound
This
substance
can be
detected after
the
degradation
of :azo
colorant,
see Annex
XVII of
Reach)
Only low level
residue will be
expected
(less than
0,1%
10.18 Diethyl sulphate 64-67-5 200-589- Carcinogenic Not used in
6 (Article 57a); footwear or
Mutagenic footwear
(Article 57b) components
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
ID Substance name CAS EC Group Reason for Occurrence
Number Number inclusion in Footwear
10.19 Dimethyl sulphate 77-78-1 201-058- Carcinogenic Not used in
1 (Article 57a) footwear or
footwear
components
a
10.20 N,N-dimethylformamide 68-12-2 200-679- solvent Toxic for Possible for
5 reproduction PU coated
(Article 57 c) material
obtained by
dipping
These
material are
rarely used in
footwear
a
10.21 4-(1,1,3,3- - - Surfactant Equivalent Used in the
tetramethylbutyl)phenol, level of past in the
ethoxylated [covering well- concern textile
defined substances and having industry
UVCB substances, polymers probable
see Annex
and homologues] serious
XVII of Reach
effects to the
can be found
environment
at residual
(Article 57 f)
levels
a
10.22 4-Nonylphenol, branched and - - Surfactant Equivalent Used in the
linear [substances with a level of past in the
linear and/or branched alkyl concern textile
chain with a carbon number having industry
of 9 covalently bound in probable
see Annex
position 4 to phenol, covering serious
XVII of Reach
also UVCB- and well-defined effects to the
can be found
substances which include any environment
at residual
of the individual isomers or a (Article 57 f)
levels
combination thereof]
10.23 Furan 110-00-9 203-727- Solvent Carcinogenic Not used in
3 (Article 57a) footwear or
footwear
components
10.24 Lead oxide sulfate 12036- 234-853- Substances Toxic for Not used in
76-9 7 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.25 Lead titanium trioxide 12060- 235-038- Substances Toxic for Not used in
00-3 9 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.26 Bis(pentabromophenyl) ether 1163-19- 214-604- Brominated PBT (Article Not used in
(decabromodiphenyl ether; 5 9 flame 57 d); vPvB footwear or
DecaBDE) retardant (Article 57 e) footwear
components
10.27 Dinoseb (6-sec-butyl-2,4- 88-85-7 201-861- pesticide Toxic for Not used in
dinitrophenol) 7 reproduction footwear or
(Article 57 c) footwear
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
ID Substance name CAS EC Group Reason for Occurrence
Number Number inclusion in Footwear
components
10.28 1,2-Diethoxyethane 629-14-1 211-076- solvent Toxic for Used as a
1 reproduction solvent for
(Article 57 c) leather
finishing
Only low level
residue will be
expected
(less than
0,1%
10.29 N-methylacetamide 79-16-3 201-182- solvent Toxic for Not used in
6 reproduction footwear or
(Article 57 c) footwear
components
10.30 Tetralead trioxide sulphate 12202- 235-380- Substances Toxic for Not used in
17-4 9 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.31 Acetic acid, lead salt, basic 51404- 257-175- Substances Toxic for Not used in
69-4 3 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.32 [Phthalato(2-)]dioxotrilead 69011- 273-688- Substances Toxic for Not used in
06-9 5 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.33 Tetraethyllead 78-00-2 201-075- Substances Toxic for Not used in
4 containing reproduction footwear or
lead (Article 57 c) footwear
components
a
10.34 N-pentyl-isopentylphthalate 776297- - phthalates Toxic for Possible
69-9 reproduction
(concentration
(Article 57 c)
higher than
0,1%
possible)
10.35 Pentalead tetraoxide sulphate 12065- 235-067- Substances Toxic for Not used in
90-6 7 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.36 Heptacosafluorotetradecanoic 376-06-7 206-803- vPvB (Article Not used in
acid 4 57 e) footwear or
footwear
components
10.37 Tricosafluorododecanoic acid 307-55-1 206-203- vPvB (Article Not used in
2 57 e) footwear or
footwear
components
10.38 1-bromopropane (n-propyl 106-94-5 203-445- Toxic for Not used in
bromide) 0 reproduction footwear or
(Article 57 c) footwear
components
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
ID Substance name CAS EC Group Reason for Occurrence
Number Number inclusion in Footwear
10.39 Dioxobis(stearato)trilead 12578- 235-702- Substances Toxic for Not used in
12-0 8 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.40 Pentacosafluorotridecanoic 72629- 276-745- vPvB (Article Not used in
acid 94-8 2 57 e) footwear or
footwear
components
10.41 Methoxyacetic acid 625-45-6 210-894- Toxic for Not used in
6 reproduction footwear or
(Article 57 c) footwear
components
10.42 Methyloxirane (Propylene 75-56-9 200-879- Carcinogenic Not used in
oxide) 2 (Article 57a); footwear or
Mutagenic footwear
(Article 57b) components
10.43 Trilead dioxide phosphonate 12141- 235-252- Substances Toxic for Not used in
20-7 2 containing reproduction footwear or
lead (Article 57 c) footwear
components
10.44 o-aminoazotoluene 97-56-3 202-591- Aryl amine Carcinogenic Not used as a
2 (Article 57a) free
compound
This
substance
can be
detected after
the
degradation
of :azo
colorant,
see Annex
XVII of
Reach)
Only low level
residue will be
expected
(less than
0,1%
10.45 4-methyl-m- 95-80-7 202-453- Aryl amine Carcinogenic Not used as a
phenylenediamine (toluene- 1 (Article 57a) free
2,4-diamine) compound
This
substance
can be
detected after
the
degradation
of :azo
colorant,
see Annex
XVII of
kSIST-TP FprCEN/TR 16417:2014
FprCEN/TR 16417:2014 (E)
ID Substance name CAS EC Group Reason for Occurrence
Number Number inclusion in Footwear
Reach)
Only low level
residue will be
expected
(less than
0,1%
a
10.46 Diisopentylphthalate 605-50-5 210-088- phthalate Toxic for Possible
4 reproduction
(concentration
(Article 57 c)
higher than
0,1%
possible)
a
10.47 1,2-Benzenedicarboxylic acid, 84777- 284-032- phthalate Toxic for Possible
dipentylester, branched and 06-0 2 reproduction
(concentration
linear (Article 57 c)
higher than
0,1%
possible)
10.48 Biphenyl-4-ylamine 92-67-1 202-177- Aryl amine Carcinogenic Not used as a
1 (Article 57a) free
compound
This
substance
can be
detected after
the
degradation
of :azo
colorant,
see Annex
XVII of
Reach)
Only low level
residue will be
...
SLOVENSKI STANDARD
01-marec-2016
1DGRPHãþD
SIST-TP CEN/TR 16417:2014
Obutev - Smernica, namenjena obutveni industriji, o snoveh, ki zelo zbujajo skrb
(Priloga XIV iz REACH)
Footwear - Footwear industry guideline for substances of very high concern (Annex XIV
of REACH)
Schuhe - Leitfaden für die Schuhindustrie für sehr bedenkliche Substanzen (Anhang XIV
von REACH)
Chaussures - Lignes directrice de l’industrie de la chaussure concernant les substances
extrêmement préoccupantes (annexe XIV de REACH)
Ta slovenski standard je istoveten z: CEN/TR 16417:2016
ICS:
61.060 Obuvala Footwear
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
CEN/TR 16417
TECHNICAL REPORT
RAPPORT TECHNIQUE
January 2016
TECHNISCHER BERICHT
ICS 61.060 Supersedes CEN/TR 16417:2012
English Version
Footwear - Footwear industry guideline for substances of
very high concern (Annex XIV of REACH)
Chaussures - Lignes directrice de l'industrie de la Schuhe - Leitfaden für die Schuhindustrie für sehr
chaussure concernant les substances extrêmement bedenkliche Substanzen (Anhang XIV von REACH)
préoccupantes (annexe XIV de REACH)
This Technical Report was approved by CEN on 24 August 2015. It has been drawn up by the Technical Committee CEN/TC 309.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2016 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TR 16417:2016 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
1 Scope . 4
2 Terms and definitions . 5
3 SVHC potentially present in the footwear industry . 6
3.1 General . 6
3.2 SVHC included in Annex XIV of REACH. 6
3.3 SVHC included in the candidate list of Annex XIV of REACH . 11
Annex A (informative) Available test methods for the identification of the substances of
very high concern given in the future REACH — Annex XIV . 29
Bibliography . 39
European foreword
This document (CEN/TR 16417:2016) has been prepared by Technical Committee CEN/TC 309
“Footwear”, the secretariat of which is held by AENOR.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
This document supersedes CEN/TR 16417:2012.
In comparison with the previous edition, the most significant changes are:
— inclusion of the new substances (Tables 9 to 13) published in the candidate list of Annex XIV of
REACH after January 2012;
— substances from Tables 2 to 8 have been transferred to table after their final inclusion in Annex XIV
of REACH;
— the new substances of Tables 9 to 13 have been added in the annex.
1 Scope
This Technical Report is intended to provide information on the chemicals listed in the Candidate List /
Annex XIV of the Regulation (EC) 1907/2006, also known as REACH (Regulation, Evaluation and
Authorisation of Chemicals) and their usage and presence in the footwear industry.
The Annex XIV, overseen by the ECHA (European Chemicals Agency), is a list of substances subject to
authorization, substances of very high concern (SVHC). Before the inclusion of a substance in the
Annex XIV, the procedure is strictly fixed:
— A European member state shall propose it to ECHA.
— ECHA inform all the members’ state and a first enquiry is done in order to include the substance to
the candidate list of Annex XIV.
— After the agreement of the member’s state, ECHA includes the substances in the candidate list to
Annex XIV. As soon as a substance has been included in the candidate list, it should be taken into
account exactly as a SVHC.
— ECHA prioritizes the substances from the Candidate List to determine which ones should be
included in the Authorisation List (Annex XIV of REACH) and therefore, subject to authorization.
ECHA regularly submits recommendations to the European Commission, who will decide on the
substances to be included in the Authorisation List.
Following the evaluation of the Annex XIV substances, ECHA can take the decision to restrict the
substances. This restriction may take the form of an authorization for use, an authorization only for
specific applications in specified fields or, in some cases, a complete ban on the use of the substance.
During the evaluation process, these chemicals are not forbidden or limited in use. The regulation
requires that the user shall be informed if one or more of these substances are present in any part of the
article in quantity over 0,1 % by weight.
This Technical Report shows which of these chemicals may be present in footwear materials and the
footwear industry in order to help shoe manufacturers to collect mandatory information from suppliers
regarding the content of these chemicals and, at same time, allow them to provide accurate information
to their customers.
The test methods reported in Annex A are informative only to identify where these chemicals may be
found and control the use along the supply chain where their suppliers are not under the jurisdiction of
the REACH Regulation.
Taking into account final decision of the European Commission, ECHA, implements the Annex XIV and
the candidate list to Annex XIV of REACH, regularly. This revision interval is difficult to follow by the
standardization procedures.
Therefore this document reflects the situation at the date of June 2014. This document will be annually
revised.
This Technical Report does not concern the substances for which restriction have been already enacted
under Annex XVII of REACH.
NOTE Chemicals that are restricted under Annex XVII, are identified as a category 1 chemical in
CEN ISO/TR 16178.
2 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
2.1
Very Persistent and Very Bioaccumulative substance
vPvB
substance that fulfils the criteria of both the sections below:
a) Persistence
1) the half-life in marine, fresh- or estuarine water is higher than 60 d, or
2) the half-life in marine, fresh- or estuarine water sediment is higher than 180 d, or
3) the half-life in soil is higher than 180 d
b) Bioaccumulation
1) the bioconcentration factor is greater than 5 000
2.2
Persistent, Bioaccumulative and Toxic substance
PBT
substance that fulfils all three of the criteria of the sections below:
a) Persistence
1) the half-life in marine water is higher than 60 d, or
2) the half-life in fresh- or estuarine water is higher than 40 d, or
3) the half-life in marine sediment is higher than 180 d, or
4) the half-life in fresh- or estuarine water sediment is higher than 120 d, or
5) the half-life in soil is higher than 120 d
b) Bioaccumulation
1) the bioconcentration factor (BCF) is higher than 2 000
c) Toxicity
1) the long-term no-observed effect concentration (Noec) for marine or freshwater organisms is
less than 0,01 mg/l, or
2) the substance is classified as carcinogenic (category 1 or 2), mutagenic (category 1 or 2) or
toxic for reproduction (category 1, 2, or 3), or
3) there is other evidence of chronic toxicity, as identified by the classifications: T, R48, or Xn, R48
according to Directive 67/548/EEC
3 SVHC potentially present in the footwear industry
3.1 General
The following subclauses contain tables with the substances of very high concern (SVHC) that could be
found in the footwear or in the footwear components.
3.2 SVHC included in Annex XIV of REACH
Table 1 includes the substances of very high concern included, at the moment of publication of this
th
Technical Report, in Annex XIV of REACH after the 17 April 2014.
Table 1 — Identification of substances of very high concern included in Annex XIV of REACH —
th
after the 17 April 2014
Reason for Occurrence in
ID Substance name CAS number EC number Group
inclusion footwear
Not used in
5-tert-butyl-2,4,6-trinitro- vPvB footwear or
1.1 81-15-2 201-329-4
m-xylene (musk xylene) (article 57e) footwear
components
Not used as a free
compound
This substance can
be detected after
the degradation of:
— azo colorant,
see Annex XVII
4,4’- Carcinogenic
of Reach)
1.2 101-77-9 202-974-4 Aryl amine
Diaminodiphenylmethane (article 57a)
— PU material,
(false positive
result is
possible,
generated as a
marker in
testing of PU
material)
Not used in
Hexabromocyclododecane 25637-99-4 and
footwear or
(HBCDD) and all major 3194-55-6 247-148-4
PBT footwear
1.3 diastereoisomers identified (134237-51-7, and
(article 57d) components
(α – HBCDD, β-HBCDD, 134237-50-6, 221-695-9
(flame retardant for
γ-HBCDD) 134237-52-8)
electronics)
Possible
Bis (2- Toxic for
(concentration
a
1.4 ethyl(hexyl)phthalate) 117-81-7 204-211-0 Phthalate reproduction
higher than 0,1 %
(DEHP) (article 57c)
possible)
Possible
Toxic for
Benzyl butyl phthalate (concentration
a
1.5 85-68-7 201-622-7 Phthalate reproduction
(BBP) higher than 0,1 %
(article 57c)
possible)
Reason for Occurrence in
ID Substance name CAS number EC number Group
inclusion footwear
Possible
Toxic for
(concentration
a
1.6 Dibutyl phthalate (DBP) 84-74-2 201-557-4 Phthalate reproduction
higher than 0,1 %
(article 57c)
possible)
Not used in
2,4 – Dinitrotoluene Aromatic Carcinogenic footwear or
1.7 121-14-2 204-450-0
(2,4-DNT) hydrocarbons (article 57a) footwear
components
Not used in
footwear or
Tris(2- footwear
Tris(2- Toxic for
chloroethyl) components
1.8 chloroethyl)phosphate 115-96-8 204-118-5 reproduction
phosphate (flame retardant for
(TCEP) (article 57c)
(TCEP) furniture,
plasticizer for
PU-PVC)
Not used in
Arsenic Carcinogenic footwear or
1.9 Diarsenic pentaoxide 1303-28-2 215-116-9
compounds (article 57a) footwear
components
Carcinogenic
Substances and toxic for Possible pigment in
Lead sulfochromate yellow
1.10 1344-37-2 215-693-7 containing reproduction certain surface
(C.I. Pigment Yellow 34)
lead (articles 57a coating
and 57c)
Carcinogenic
Lead chromate molybdate Substances and toxic for Possible pigment in
1.11 sulphate red (C.I. Pigment 12656-85-8 235-759-9 containing reproduction certain surface
Red 104) lead (articles 57a coating
and 57c)
Not used in
Arsenic Carcinogenic footwear or
1.12 Diarsenic trioxide 1327-53-3 215-481-4
compounds (article 57a) footwear
components
Carcinogenic
Substances and toxic for Possible pigment in
1.13 Lead chromate 7758-97-6 231-846-0 containing reproduction certain surface
chromate (articles 57a coating
and 57c)
Possible
Toxic for
Diisobutyl phthalate (concentration
a
1.14 84-69-5 201-553-2 phthalate reproduction
(DIBP) higher than 0,1 %
(article 57c)
possible)
Reason for Occurrence in
ID Substance name CAS number EC number Group
inclusion footwear
Solvent used in not
flammable
adhesive, volatile
product can be
present only as a
Chlorinated Carcinogenic
1.15 Trichloroethylene 79-01-6 201-167-4
residue
aliphates (article 57a)
More possible to
detect in the
footwear packaging
than in the footwear
Not used in
footwear or
Carcinogenic
Substances footwear
and mutagenic
1.16 Chromium trioxide 1333-82-0 215-607-8 containing components
(articles 57a
chromium (Cr VI possible in
and 57b)
leather at low
concentration)
Not used in
footwear or
231-801-5,
Chromic acid, Dichromic 7738-94-5, Substances footwear
236-881-5, Carcinogenic
1.17 acid, Oligomers of chromic 13530-68-2, not containing components
not yet (article 57a)
acid and dichromic acid yet assigned chromium (Cr VI possible in
assigned
leather at low
concentration)
Not used in
Carcinogenic,
footwear or
mutagenic and
Substances footwear
7789-12-0 and toxic for
1.18 Sodium dichromate 234-190-3 containing components
10588-01-9 reproduction
chromate (Cr VI possible in
(articles 57a,
leather at low
57b and 57c)
concentration)
Not used in
Carcinogenic,
footwear or
mutagenic and
Substances footwear
toxic for
1.19 Potassium dichromate 7778-50-9 231-906-6 containing components
reproduction
chromate (Cr VI possible in
(articles 57a,
leather at low
57b and 57c)
concentration)
Not used in
Carcinogenic,
footwear or
mutagenic and
Substances footwear
toxic for
1.20 Ammonium dichromate 7789-09-5 232-143-1 containing components
reproduction
chromate (Cr VI possible in
(articles 57a,
leather at low
57b and 57c)
concentration)
Not used in
footwear or
Carcinogenic
Substances footwear
and mutagenic
1.21 Potassium chromate 7789-00-6 232-140-5 containing components
(articles 57a
chromate (Cr VI possible in
and 57b)
leather at low
concentration)
Reason for Occurrence in
ID Substance name CAS number EC number Group
inclusion footwear
Not used in
Carcinogenic,
footwear or
mutagenic and
Substances footwear
toxic for
1.22 Sodium chromate 7775-11-3 231-889-5 containing components
reproduction
chromate (Cr VI possible in
(articles 57a,
leather at low
57b and 57c)
concentration)
Reaction products
Formaldehyde, oligomeric Not used in
Carcinogenic
1.23 reaction products with 25214-70-4 500-036-1 aldehyde footwear or
(article 57a)
aniline (technical MDA) footwear
components
Not used in
Arsenic Carcinogenic footwear or
1.24 Arsenic acid 7778-39-4 231-901-9
compounds article 57a) footwear
components
Not used in
footwear or
footwear
Dihydroxy Carcinogenic
1.25 Bis(2-methoxyethyl) ether 111-96-6 203-924-4 components volatile
ether (article 57a)
product, traces can
be present only as a
residue
Solvent used in not
flammable
adhesive, volatile
product can be
present only as a
1,2-Dichloroethane; Chlorinated Carcinogenic
residue
1.26 107-06-2 203-458-1
ethylene dichloride aliphate (article 57a)
More possible to
detect in the
packaging of
footwear than in the
footwear itself
Used as a curing
agent in PU
industry, Possible in
2,2'-dichloro-4,4'-
certain technical PU
Carcinogenic
1.27 methylenedianiline 101-14-4 202-918-9 Aryl amine
(article 57a)
Only low level
(MOCA)
residue will be
expected (less than
0,1 %)
Not used in
footwear or
Substances footwear
Dichromium Carcinogenic
1.28 24613-89-6 246-356-2 containing components
tris(chromate) (article 57a)
chromium (Cr VI possible in
leather at low
concentration)
Reason for Occurrence in
ID Substance name CAS number EC number Group
inclusion footwear
Not used in
footwear or
Substances footwear
Carcinogenic
1.29 Strontium chromate 7789-06-2 232-142-6 containing components
(article 57a)
chromate (Cr VI possible in
leather at low
concentration)
Not used in
footwear or
Potassium Substances footwear
Carcinogenic
1.30 hydroxyoctaoxodizincatedi 11103-86-9 234-329-8 containing components
(article 57a)
chromate chromate (Cr VI possible in
leather at low
concentration)
Not used in
footwear or
Substances footwear
Pentazinc chromate Carcinogenic
1.31 49663-84-5 256-418-0 containing components
octahydroxide (article 57a)
chromium (Cr VI possible in
leather at low
concentration)
a
These substances are especially important for footwear and footwear components.
3.3 SVHC included in the candidate list of Annex XIV of REACH
The following tables include the substances of very high concern included, at the moment of publication
of this Technical Report, in the candidate list of Annex XIV of REACH. Different tables have been drafted
to identify the date of inclusion in the candidate list.
Table 2 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 28 October 2008
Reason for Occurrence in
ID Substance name CAS number EC number Group
inclusion footwear
2.1 Bis(tributyltin) oxide 56-35-9 200-268-0 Substances PBT Not used in
(TBTO) containing tin (article 57d) footwear or
footwear
components
Use in the pass as
a preservative
agent
a
2.2 Anthracene 120-12-7 204-371-1 PAHs PBT PAH compound
(article 57d)
Possible
contaminant
(recycled
materials, leather
fat liquor, black
plastics, rubbers)
2.3 Lead hydrogen arsenate 7784-40-9 232-064-2 Arsenic Carcinogenic and Not used in
compounds toxic for footwear or
reproduction footwear
(articles 57a components
and 57c)
2.4 Triethyl arsenate 15606-95-8 427-700-2 Arsenic Carcinogenic Not used in
compounds (article 57a) footwear or
footwear
components
a
2.8 Alkanes, C10-13,chloro 85535-84-8 287-476-5 Chlorinated PBT and vPvB Possible
[Short Chain Chlorinated aliphates (articles 57d (flame retardant
paraffins] (SCCP) and 57e) for textile or fat
liquor for
leather)
See Table 1 – 1.3
See Table 1 – 1.2
See Table 1 – 1.6
See Table 1 – 1.18
See Table 1 – 1.7
See Table 1 – 1.9
See Table 1 – 1.4
See Table 1 – 1.5
See Table 1 – 1.12
See Table 3 – 3.6
a
These substances are especially important for footwear and footwear components.
Table 3 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Dates of inclusion 13 January 2010
Reason for Occurrence in
ID Substance name CAS number EC number Group
inclusion footwear
3.1 Coal tar pitch, high 65996-93-2 266-028-2 PAHs Carcinogenic, PBT Not used in footwear
temperature and vPvB or footwear
(articles 57a, 57d components
and 57e)
3.5 Anthracene oil 90640-80-5 292-602-7 PAHs Carcinogenic[1], PBT Not used in footwear
and vPvB or footwear
(articles 57a, 57d components
and 57e)
3.6 Anthracene oil, 91995-17-4 295-278-5 PAHs Carcinogenic[2],
anthracene paste, mutagenic[3], PBT
distn. Lights and vPvB (articles
57a, 57b, 57d and
57e)
3.7 Anthracene oil, 91995-15-2 295-275-9 PAHs Carcinogenic[2],
anthracene paste, mutagenic[3], PBT
anthracene fraction and vPvB (articles
57a, 57b, 57d and
57e)
3.8 Anthracene oil, 90640-82-7 292-604-8 PAHs Carcinogenic[2],
anthracene-low mutagenic[3], PBT
and vPvB (articles
57a, 57b, 57d and
57e)
3.9 Anthracene oil, 90640-81-6 292-603-2 PAHs Carcinogenic[2],
anthracene paste mutagenic[3], PBT
and vPvB
(articles 57a, 57b,
57d and 57e)
3.10 Aluminosilicate — — Refractory Carcinogenic Not used in footwear
Refractory Ceramic Ceramic (article 57a) or footwear
Fibres Fibres components
3.11 Zirconia — — Refractory Carcinogenic Not used in footwear
Aluminosilicate Ceramic (article 57a) or footwear
Refractory Ceramic Fibres components
Fibres
See Table 1 – 1.7
See Table 1 – 1.8
See Table 1 – 1.10
See Table 1 – 1.11
See Table 1 – 1.13
See Table 1 – 1.14
Table 4 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Dates of inclusion 30 March 2010
CAS EC Reason for Occurrence in
ID Substance name Group
number number inclusion footwear
Not used in
footwear or
Carcinogenic and
footwear
201-173- mutagenic
4.1 Acrylamide 79-06-1 Amides components
7 (articles 57a and
(possible in
57b)
polymers not fully
polymerized)
Table 5 — Identification of substances of very high concern included in the candidate list for
Annex XIV of REACH — Date of inclusion 18th June 2010
CAS EC Reason for Occurrence in
ID Substance name Group
number number inclusion footwear
5.2 Disodium 1303-96-4, 215-540- Substances Toxic for Not used in
tetraborate 1330-43-4, 4 containing reproduction footwear or
anhydrous 12179-04- boron (article 57c) footwear
3 components
(leather: possible
traces, use for the
preservation of raw
hides
Flame retardant for
plastics)
5.3 Boric acid 10043-35- 233-139- Substances Toxic for Not used in
3, 11113- 2, 234- containing reproduction footwear or
50-1 343-4 boron (article 57c) footwear
components
(leather: possible
traces, use for the
preservation of raw
hides
Flame retardant for
plastics)
5.8 Tetraboron 12267-73- 235-541- Substances Toxic for Not used in
disodium 1 3 containing reproduction footwear or
heptaoxide hydrate boron (article 57c) footwear
components
(leather : possible
traces, use for the
preservation of raw
hides
Flame retardant for
plastics)
See Table 1 – 1.15
See Table 1 – 1.19
See Table 1 – 1.20
See Table 1 – 1.21
See Table 1 – 1.22
Table 6 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 15 December 2010
CAS Reason for Occurrence in
ID Substance name EC number Group
number inclusion footwear
6.3 2-Ethoxyethanol; 110-80-5 203-804-1 Dihydroxy Toxic for Not used in footwear
Ethylene glycol ethers reproduction or footwear
monoethyl ether (article 57c) components
(EGEE) (possible in certain
leather finishing at
low levels)
6.4 2-Methoxyethanol; 109-86-4 203-713-7 Dihydroxy Toxic for Not used in footwear
Ethylene glycol ethers reproduction or footwear
monomethyl ether (article 57c) components
(EGME) (possible in certain
leather finishing at
low levels)
6.5 Cobalt (di)acetate 71-48-7 200-755-8 Substances Carcinogenic and Not used in footwear
containing toxic for or footwear
cobalt reproduction components
(articles 57a and
57c)
6.6 Cobalt carbonate 513-79-1 208-169-4 Substances Carcinogenic and Not used in footwear
containing toxic for or footwear
cobalt reproduction components
(articles 57a and
57c)
6.7 Cobalt dinitrate 10141-05-6 233-402-1 Substances Carcinogenic and Not used in footwear
containing toxic for or footwear
cobalt reproduction components
(articles 57a and
57c)
6.8 Cobalt sulphate 10124-43-3 233-334-2 Substances Carcinogenic and Not used in footwear
containing toxic for or footwear
cobalt reproduction components
(articles 57a and
57c)
See Table 1 – 1.16
See Table 1 – 1.17
Table 7 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 20 June 2011
CAS EC Reason for Occurrence in
ID Substance name Group
number number inclusion footwear
a
7.1 1,2- 71888-89- 276-158- Phthalates Toxic for Theoretically
Benzenedicarboxylic 6 1 reproduction possible
acid, di-C6-8-branched (article 57c)
Practically never
alkyl esters, C7-rich
has been
(DIHP)
detected in
footwear or
footwear
components
7.2 1,2,3- 96-18-4 202-486- Chlorinated Carcinogenic and Solvent in
trichloropropane 1 aliphates toxic for rubber industry
reproduction volatile product,
(articles 57a traces can be
and 57c) present only as a
residue
a
7.3 N-methyl-2- 872-50-4 212-828- Nitrogen Toxic for Solvent used in
pyrrolidone; 1 containing reproduction leather industry
heterocycles (article 57c) (concentration
1-methyl-2-
higher than 0,1
pyrrolidone
% possible)
7.4 Hydrazine 302-01-2 206-114- Other Carcinogenic Basic chemical
9 substances (article 57a) for synthesis
Not used in
footwear or
footwear
components
7.5 Cobalt dichloride 7646-79-9 231-589- Substances Carcinogenic and Not used in
4 containing toxic for footwear or
cobalt reproduction footwear
(articles 57a components
and 57c)
a
7.6 1,2- 68515-42- 271-084- Phthalates Toxic for Theoretically
Benzenedicarboxylic 4 6 reproduction possible
acid, di-C7-11- (article 57c)
Practically never
branched and linear
has been
alkyl esters
detected in
footwear or
footwear
components
7.8 2-Ethoxyethyl acetate 111-15-9 203-839- Dihydroxy Toxic for Solvent volatile
2 ethers reproduction product, traces
(article 57c) can be present
only as a residue
See Table 1 – 1.29
a
These substances are especially important for footwear and footwear components.
Table 8 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 20 December 2011
CAS Reason for Occurrence in
ID Substance name EC number Group
number inclusion footwear
a
8.1 4-(1,1,3,3- 140-66-9 205-426-2 Alkyl phenols Toxic for Used as surfactant in
tetramethylbutyl)phenol, and their reproduction leather and textile
(4-tert-Octylphenol) ethoxylates (article 57c) industry
Only low level residue
will be expected (less
than 0,1 %)
8.2 2-Methoxyaniline; 90-04-0 201-963-1 Aryl amine Carcinogen, Not used as a free
o-Anisidine cat. 2 compound
This substance can be
detected after the
degradation of: azo
colorant,
see Annex XVII of
Reach
Only low level residue
will be expected (less
than 0,1 %)
8.4 Calcium arsenate 7778-44-1 231-904-5 Arsenic Carcinogenic Not used in footwear
compounds (article 57a) or footwear
components
8.5 Trilead diarsenate 3687-31-8 222-979-5 Arsenic Carcinogenic Not used in footwear
compounds (article 57a) or footwear
components
a
8.8 Bis(2-methoxyethyl) 117-82-8 204-212-6 Phthalate Toxic for Possible
phthalate reproduction (concentration higher
(article 57c) than 0,1 % possible)
8.9 N,N-dimethylacetamide 127-19-5 204-826-4 Amide Carcinogenic Solvent used in
synthetic textile
(DMAC) (article 57a)
industry and in
leather finishing
Only low level residue
will be expected (less
than 0,1 %)
8.11 Lead diazide; Lead azide 13424-46-9 236-542-1 Substances Carcinogenic Not used in footwear
containing lead and toxic for or footwear
reproduction
components
(articles 57a
and 57c)
8.12 Lead styphnate 15245-44-0 239-290-0 Substances Carcinogenic Not used in footwear
containing lead and toxic for or footwear
reproduction components
(articles 57a
and 57c)
8.17 Phenolphthalein 77-09-8 201-004-7 Aromatic Carcinogenic Not used in footwear
hydrocarbons (article 57a) or footwear
components
8.18 Aluminosilicate — — Refractory Carcinogenic Not used in footwear
Refractory Ceramic or footwear
Ceramic Fibres (article 57a)
Fibres components
CAS Reason for Occurrence in
ID Substance name EC number Group
number inclusion footwear
8.19 Zirconia Aluminosilicate — — Refractory Carcinogenic Not used in footwear
Refractory Ceramic Ceramic Fibres (article 57a) or footwear
Fibres components
8.20 Lead dipicrate 6477-64-1 229-335-2 Substances Carcinogenic Not used in footwear
containing lead and toxic for or footwear
reproduction components
(articles 57a
and 57c)
See Table 1 – 1.23
See Table 1 – 1.24
See Table 1 – 1.25
See Table 1 – 1.26
See Table 1 – 1.27
See Table 1 – 1.28
See Table 1 – 1.30
See Table 1 – 1.31
a
These substances are especially important for footwear and footwear components.
Table 9 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 18 June 2012
ID Substance name CAS EC number Group Reason for Occurrence
number inclusion in footwear
9.1 α,α-Bis[4-(dimethylamino)phenyl]-4 6786-83-0 229-851-8 Colorant Carcinogenic Complex
(phenylamino)naphthalene-1-methanol (article 57a) mixture not
(C.I. Solvent Blue 4) [with ≥ 0,1% of used in
Michler's ketone (EC No. 202-027-5) or footwear or
Michler's base (EC No. 202-959-2)] footwear
components
(However
C.I. Solvent
Blue 4 can
be found in
plastics,
paper,
paperboard)
9.2 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]- 59653-74-6 423-400-0 Mutagenic Not used in
1,3,5-triazine-2,4,6-(1H,3H,5H)-trione (article 57b) footwear or
(β-TGIC) footwear
components
9.3 N,N,N',N'-tetramethyl-4,4'- 101-61-1 202-959-2 Carcinogenic Not used in
methylenedianiline (Michler’s base) (article 57a) footwear or
footwear
components
9.4 Diboron trioxide 1303-86-2 215-125-8 Substances Toxic for Not used in
containing reproduction footwear or
boron (article 57c) footwear
components
9.5 1,2-bis(2-methoxyethoxy)ethane 112-49-2 203-977-3 Solvant Toxic for Used as a
(TEGDME; triglyme) reproduction solvent for
(article 57c) certain dyes
Only low
level residue
will be
expected
(less than
0,1 %)
a
9.6 Formamide 75-12-7 200-842-0 Toxic for Possible at
reproduction more than
(article 57c) 0,1 % for
EVA
materials
9.7 4,4'-bis(dimethylamino)-4''- 561-41-1 209-218-2 Colorant Carcinogenic Complex
(methylamino)trityl alcohol (article 57a) mixture not
[with ≥ 0,1 % of Michler's ketone used in
(EC No. 202-027-5) or Michler's base footwear or
(EC No. 202-959-2)] footwear
components
(solvent violet 8)
(However
C.I. Solvent
Blue 4 can
be found in
plastics,
paper,
paperboard)
ID Substance name CAS EC number Group Reason for Occurrence
number inclusion in footwear
9.8 Lead(II) bis(methanesulfonate) 17570-76-2 401-750-5 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
9.9 [4-[4,4'-bis(dimethylamino) 548-62-9 208-953-6 Colorant Carcinogenic Complex
benzhydrylidene]cyclohexa-2,5-dien-1- (article 57a) mixture not
ylidene]dimethylammonium chloride used in
(C.I. Basic Violet 3) [with ≥ 0,1 % of footwear or
Michler's ketone (EC No. 202-027-5) or footwear
Michler's base (EC No. 202-959-2)] components
(However
C.I. Solvent
Blue 4 can
be found in
plastics,
paper,
paperboard)
9.10 1,2-dimethoxyethane; ethylene glycol 110-71-4 203-794-9 Solvent Toxic for Used as a
dimethyl ether (EGDME) reproduction solvent for
(article 57c) certain dyes
Only low
level residue
will be
expected
(less than
0,1 %)
9.11 [4-[[4-anilino-1-naphthyl][4- 2580-56-5 219-943-6 Colorant Carcinogenic Complex
(dimethylamino)phenyl]methylene]cycl (article 57a) mixture not
ohexa-2,5-dien-1-ylidene] used in
dimethylammonium chloride (C.I. Basic footwear or
Blue 26) [with ≥ 0,1 % of Michler's footwear
ketone (EC No. 202-027-5) or Michler's components
base (EC No. 202-959-2)]
(However
C.I. Basic
Blue 26 can
be found in
textile)
9.12 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5- 2451-62-9 219-514-3 Mutagenic Not used in
triazinane-2,4,6-trione (TGIC) (article 57b) footwear or
footwear
components
9.13 4,4'-bis(dimethylamino)benzophenone 90-94-8 202-027-5 Carcinogenic Not used in
(Michler’s ketone) (article 57a) footwear or
footwear
components
a
These substances are especially important for footwear and footwear components.
Table 10 — Identification of substances of very high concern included in the candidate list for
th
Annex XIV of REACH — Date of inclusion 19 December 2012
EC Reason for Occurrence in
ID Substance name CAS number Group
number inclusion footwear
10.1 Hexahydromethylphthalic anhydride 25550-51-0, 247-094-1, Equivalent Not used in
[1], Hexahydro-4-methylphthalic 19438-60-9, 243-072-0, level of footwear or
anhydride [2], Hexahydro-1- 48122-14-1, 256-356-4, concern footwear
methylphthalic anhydride [3], 57110-29-9 260-566-1 having components
Hexahydro-3-methylphthalic probable
anhydride [4] [The individual isomers serious effects
[2], [3] and [4] (including their cis- to human
and trans- stereo isomeric forms) and health
all possible combinations of the (article 57f)
isomers [1] are covered by this entry]
10.2 6-methoxy-m-toluidine (p-cresidine) 120-71-8 204-419-1 Aryl amine Carcinogenic Not used as a
(article 57a) free compound
This substance
can be detected
after the
degradation of:
azo colorant,
see Annex XVII
of Reach
Only low level
residue will be
expected (less
than 0,1 %)
10.3 Cyclohexane-1,2-dicarboxylic 85-42-7, 201-604-9, Equivalent Not used in
anhydride [1], cis-cyclohexane-1,2- 13149-00-3, 236-086-3, level of footwear or
dicarboxylic anhydride [2], trans- 14166-21-3 238-009-9 concern footwear
cyclohexane-1,2-dicarboxylic having
components
anhydride [3] [The individual cis- [2] probable
and trans- [3] isomer substances and serious effects
all possible combinations of the cis- to human
and trans-isomers [1] are covered by health
this entry] (article 57f)
10.4 Pyrochlore, antimony lead yellow 8012-00-8 232-382-1 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.5 Henicosafluoroundecanoic acid 2058-94-8 218-165-4 vPvB Not used in
footwear or
(article 57e)
footwear
components
10.6 4-Aminoazobenzene 60-09-3 200-453-6 Aryl amine Carcinogenic Used as
(article 57a) colorant
(Solvent
Yellow 1) and
can be detected
after the
degradation of
azo colorants
Only low level
residue will be
expected (less
than 0,1 %)
EC Reason for Occurrence in
ID Substance name CAS number Group
number inclusion footwear
10.7 Silicic acid, lead salt 11120-22-2 234-363-3 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.8 Lead titanium zirconium oxide 12626-81-2 235-727-4 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.9 Lead monoxide (lead oxide) 1317-36-8 215-267-0 Toxic for Not used in
reproduction footwear or
(article 57c) footwear
components
10.10 o-Toluidine 95-53-4 202-429-0 Aryl amine Carcinogenic Not used as a
(article 57a) free compound
This substance
can be detected
after the
degradation of:
azo colorant,
see Annex XVII
of Reach
Only low level
residue will be
expected (less
than 0,1 %)
a
10.11 3-ethyl-2-methyl-2-(3-methylbutyl)- 143860-04-2 421-150-7 Toxic for Possible at
1,3-oxazolidine reproduction more than
(article 57c) 0,1 % for
Polyurethane
materials
a
10.12 Dibutyltin dichloride (DBTC) 683-18-1 211-670-0 Organotin Toxic for Stabiliser or
reproduction catalyst of
(article 57c) polymers
10.13 Lead bis(tetrafluoroborate) 13814-96-5 237-486-0 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.14 Lead dinitrate 10099-74-8 233-245-9 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.15 Silicic acid (H2Si2O5), barium salt 68784-75-8 272-271-5 Substances Toxic for Not used in
(1:1), lead-doped [with lead (Pb) containing reproduction footwear or
content above the applicable generic lead (article 57c) footwear
concentration limit for ’toxicity for components
reproduction’ Repr. 1A (CLP) or
category 1 (DSD); the substance is a
member of the group entry of lead
compounds, with index number
082-001-00-6 in Regulation (EC)
No 1272/2008]
10.16 Trilead bis(carbonate)dihydroxide 1319-46-6 215-290-6 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
EC Reason for Occurrence in
ID Substance name CAS number Group
number inclusion footwear
10.17 4,4'-methylenedi-o-toluidine 838-88-0 212-658-8 Aryl amine Carcinogenic Not used as a
(article 57a) free compound
This substance
can be detected
after the
degradation of:
azo colorant,
see Annex XVII
of Reach
Only low level
residue will be
expected (less
than 0,1 %)
10.18 Diethyl sulphate 64-67-5 200-589-6 Carcinogenic Not used in
(article 57a); footwear or
Mutagenic footwear
(article 57b) components
10.19 Dimethyl sulphate 77-78-1 201-058-1 Carcinogenic Not used in
(article 57a) footwear or
footwear
components
a
10.20 N,N-dimethylformamide 68-12-2 200-679-5 Solvent Toxic for Possible for PU
reproduction coated material
obtained by
(article 57c)
dipping
10.21 4-(1,1,3,3-tetramethylbutyl)phenol, — — Surfactant Equivalent Used in the past
ethoxylated [covering well-defined level of in the textile
substances and UVCB substances, concern industry
polymers and homologues] having
see Annex XVII
probable
of Reach
serious effects
can be found at
to the
residual levels
environment
(article 57f)
a
10.22 4-Nonylphenol, branched and linear — — Surfactant Equivalent Possible in the
[substances with a linear and/or level of textile industry
branched alkyl chain with a carbon concern
see Annex XVII
number of 9 covalently bound in having
of Reach
position 4 to phenol, covering also probable
can be found at
UVCB- and well-defined substances serious effects
residual levels
which include any of the individual to the
isomers or a combination thereof] environment
(article 57f)
10.23 Furan 110-00-9 203-727-3 Solvent Carcinogenic Not used in
(article 57a) footwear or
footwear
components
10.24 Lead oxide sulfate 12036-76-9 234-853-7 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.25 Lead titanium trioxide 12060-00-3 235-038-9 Substances Toxic for Not used in
containing reproduction footwear or
footwear
lead (article 57c)
components
10.26 Bis(pentabromophenyl) ether 1163-19-5 214-604-9 Brominated PBT Not used in
(decabromodiphenyl ether; DecaBDE) flame (article 57d); footwear or
retardant vPvB footwear
(article 57e) components
EC Reason for Occurrence in
ID Substance name CAS number Group
number inclusion footwear
10.27 Dinoseb (6-sec-butyl-2,4- 88-85-7 201-861-7 Pesticide Toxic for Not used in
dinitrophenol) reproduction footwear or
(article 57c) footwear
components
10.28 1,2-Diethoxyethane 629-14-1 211-076-1 Solvent Toxic for Used as a
reproduction solvent for
(article 57c) leather finishing
Only low level
residue will be
expected (less
than 0,1 %)
10.29 N-methylacetamide 79-16-3 201-182-6 Solvent Toxic for Not used in
reproduction footwear or
footwear
(article 57c)
components
10.30 Tetralead trioxide sulphate 12202-17-4 235-380-9 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.31 Acetic acid, lead salt, basic 51404-69-4 257-175-3 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.32 [Phthalato(2-)]dioxotrilead 69011-06-9 273-688-5 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.33 Tetraethyllead 78-00-2 201-075-4 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
a
10.34 N-pentyl-isopentylphthalate 776297-69-9 — Phthalates Toxic for Possible
reproduction
(concentration
(article 57c)
higher than
0,1 % possible)
10.35 Pentalead tetraoxide sulphate 12065-90-6 235-067-7 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.36 Heptacosafluorotetradecanoic acid 376-06-7 206-803-4 vPvB Not used in
(article 57e) footwear or
footwear
components
10.37 Tricosafluorododecanoic acid 307-55-1 206-203-2 vPvB Not used in
(article 57e) footwear or
footwear
components
10.38 1-bromopropane (n-propyl bromide) 106-94-5 203-445-0 Toxic for Not used in
reproduction footwear or
(article 57c) footwear
components
10.39 Dioxobis(stearato)trilead 12578-12-0 235-702-8 Substances Toxic for Not used in
containing reproduction footwear or
footwear
lead (article 57c)
components
10.40 Pentacosafluorotridecanoic acid 72629-94-8 276-745-2 vPvB Not used in
(article 57e) footwear or
footwear
components
EC Reason for Occurrence in
ID Substance name CAS number Group
number inclusion footwear
10.41 Methoxyacetic acid 625-45-6 210-894-6 Toxic for Not used in
reproduction footwear or
(article 57c) footwear
components
10.42 Methyloxirane (Propylene oxide) 75-56-9 200-879-2 Carcinogenic Not used in
(article 57a); footwear or
Mutagenic footwear
(article 57b) components
10.43 Trilead dioxide phosphonate 12141-20-7 235-252-2 Substances Toxic for Not used in
containing reproduction footwear or
lead (article 57c) footwear
components
10.44 o-aminoazotoluene 97-56-3 202-591-2 Aryl amine Carcinogenic Not used as a
(article 57a) free compound
This substance
can be detected
after the
degradation of:
azo colorant,
(see Annex XVII
of Reach)
Only low level
residue will be
expected (less
than 0,1 %)
10.45 4-methyl-m-phenylenediamine 95-80-7 202-453-1 Aryl amine Carcinogenic Not used as a
(toluene-2,4-diamine) (article 57a) free compound
This substance
can be detected
after the
degradation of:
azo colorant,
(see Annex XVII
of Reach)
Only low level
residue will be
expected (less
than 0,1 %)
a
10.46 Diisopentylphthalate 605-50-5 210-088-4 Phthalate Toxic for Possible
reproduction (concentration
(article 57c) higher than
0,1 % possible)
a
10.47 1,2-Benzenedicarboxylic acid, 84777-06-0 284-032-2 Phthalate Toxic for Possible
dipentylester, branched and linear reproduction (concentration
higher than
(article 57c)
0,1 % possible)
10.48 Biphenyl-4-ylamine 92-67-1 202-177-1 Aryl amine Carcinogenic Not used as a
(article 57a) free compound
This substance
can be detected
after the
degradation of:
azo colorant,
see Annex XVII
of Reach)
Only low level
residue will be
expected (less
than 0,1 %)
SIST-TP
...
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