EN ISO 22854:2025

SLOVENSKI STANDARD
01-april-2025
Nadomešča:
SIST EN ISO 22854:2021
Tekoči naftni proizvodi - Določanje vrste ogljikovodikov in oksigenatov v
motornem bencinu in bencinu na osnovi etanola (E85) - Metoda
multidimenzionalne plinske kromatografije (ISO 22854:2025)
Liquid petroleum products - Determination of hydrocarbon types and oxygenates in
automotive-motor gasoline and in ethanol (E85) automotive fuel - Multidimensional gas
chromatography method (ISO 22854:2025)
Flüssige Mineralölerzeugnisse - Bestimmung von Kohlenwasserstoffgruppen und
sauerstoffhaltigen Verbindungen in Ottokraftstoffen und in Ethanolkraftstoff (E85) -
Multidimensionales gaschromatographisches Verfahren (ISO 22854:2025)
Produits pétroliers liquides - Détermination des groupes d'hydrocarbures et de la teneur
en composés oxygénés de l'essence pour moteurs automobiles et du carburant éthanol
pour automobiles E85 - Méthode par chromatographie multidimensionnelle en phase
gazeuse (ISO 22854:2025)
Ta slovenski standard je istoveten z: EN ISO 22854:2025
ICS:
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
75.160.20 Tekoča goriva Liquid fuels
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 22854
EUROPEAN STANDARD
NORME EUROPÉENNE
January 2025
EUROPÄISCHE NORM
ICS 75.080 Supersedes EN ISO 22854:2021
English Version
Liquid petroleum products - Determination of
hydrocarbon types and oxygenates in automotive-motor
gasoline and in ethanol (E85) automotive fuel -
Multidimensional gas chromatography method (ISO
22854:2025)
Produits pétroliers liquides - Détermination des Flüssige Mineralölerzeugnisse - Bestimmung von
groupes d'hydrocarbures et de la teneur en composés Kohlenwasserstoffgruppen und sauerstoffhaltigen
oxygénés de l'essence pour moteurs automobiles et du Verbindungen in Ottokraftstoffen und in
carburant éthanol pour automobiles E85 - Méthode par Ethanolkraftstoff (E85) - Multidimensionales
chromatographie multidimensionnelle en phase gaschromatographisches Verfahren (ISO 22854:2025)
gazeuse (ISO 22854:2025)
This European Standard was approved by CEN on 13 December 2024.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2025 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 22854:2025 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 22854:2025) has been prepared by Technical Committee ISO/TC 28 "Petroleum
and related products, fuels and lubricants from natural or synthetic sources" in collaboration with
Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of
petroleum, synthetic and biological origin” the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by July 2025, and conflicting national standards shall be
withdrawn at the latest by July 2025.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 22854:2021.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 22854:2025 has been approved by CEN as EN ISO 22854:2025 without any modification.

International
Standard
ISO 22854
Fifth edition
Liquid petroleum products —
2025-01
Determination of hydrocarbon
types and oxygenates in
automotive-motor gasoline and
in ethanol (E85) automotive
fuel — Multidimensional gas
chromatography method
Produits pétroliers liquides — Détermination des groupes
d'hydrocarbures et de la teneur en composés oxygénés de
l'essence pour moteurs automobiles et du carburant éthanol
pour automobiles (E85) — Méthode par chromatographie
multidimensionnelle en phase gazeuse
Reference number
ISO 22854:2025(en) © ISO 2025
ISO 22854:2025(en)
© ISO 2025
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
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Published in Switzerland
ii
ISO 22854:2025(en)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms, definitions, symbols and abbreviated terms . 1
3.1 Terms and definitions .1
3.2 Symbols and abbreviated terms .2
4 Principle . 3
5 Reagents and materials . 4
6 Apparatus . 5
7 Sampling . 6
8 Procedure . 6
8.1 Conditioning.6
8.2 Sample preparation .6
8.2.1 Procedure B only — Sample dilution .6
8.2.2 All procedures — Sample cooling .7
8.3 Test sample injection volume .7
8.4 Tuning of the apparatus (Procedure C) .7
8.5 V erification of the apparatus and test conditions .7
8.6 Validation .7
8.7 Preparation of the test sample .8
8.8 Preparation of the apparatus and test conditions .8
9 Calculation . 8
9.1 General .8
9.2 Calculation as a mass fraction in per cent .8
9.3 Calculation as a volume fraction in per cent .9
9.4 Calculation of total oxygen content in mass fraction in per cent .11
9.5 Data report according to automotive motor gasoline specifications .11
10 Expression of results .11
10.1 Procedure A and C .11
10.2 Procedure B . 12
11 Precision .12
11.1 General . 12
11.2 Repeatability, r. 12
11.3 Reproducibility, R . 12
12 Test report .
...