Pigments and extenders - Testing of colouring materials in plasticized polyvinyl chloride (PVC-P) - Part 1: Composition and preparation of basic mixtures

This Part of EN 14469 specifies a procedure for producing basic mixtures for the testing of colouring materials )  in plasticized polyvinyl chloride (PVC-P) materials, together with the composition of these basic mixtures.
It distinguishes between:
   - basic mixture A (transparent basic mixture)
   - basic mixture B (white basic mixture)

Pigmente und Füllstoffe - Prüfung von Farbmitteln in weichmacherhaltigem Polyvinylchlorid (PVC-P) - Teil 1: Zusammensetzung und Herstellen der Grundmischungen

Dieser Teil von EN 14469 legt ein Verfahren zum Herstellen von Grundmischungen für die Prüfung von Farb-mitteln ) in weichmacherhaltigem Polyvinylchlorid (PVC-P) sowie die Zusammensetzung dieser Grundmischungen fest.
Danach werden unterschieden:
¾ Grundmischung A (transparente Grundmischung)
¾ Grundmischung B (weiße Grundmischung)

Pigments et matières de charge - Essai des matières colorantes dans le chlorure de polyvinyle plastifié (PVC-P) - Partie 1: Composition et préparation des mélanges de base

La présente partie de l'EN 14469 spécifie une méthode permettant de produire des mélanges de base en vue de soumettre à l'essai les matières colorantes  ) des matériaux constitués de chlorure de polyvinyle plastifié (PVC-P), et définit la composition desdits mélanges de base.
Elle fait la distinction entre :
-   le mélange de base A (mélange de base transparent) ;
-   le mélange de base B (mélange de base blanc).

Pigmenti in polnila - Preskušanje sredstev za obarvanje v mehčanem polivinilkloridu (PVC-P) - 1. del: Sestava in priprava osnovnih mešanic

General Information

Status
Published
Publication Date
25-May-2004
Current Stage
9093 - Decision to confirm - Review Enquiry
Start Date
27-Mar-2025
Completion Date
03-Jun-2026

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Effective Date
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Overview

EN 14469-1:2004 is a European standard developed by the European Committee for Standardization (CEN) that specifies the procedures for producing basic mixtures used in the testing of pigments and extenders (colouring materials) within plasticized polyvinyl chloride (PVC-P). This standard outlines essential requirements for the composition and the methodical preparation of these basic mixtures to ensure accurate and reproducible pigment testing in PVC-P.

The standard distinguishes between:

  • Basic mixture A: Transparent basic mixture
  • Basic mixture B: White basic mixture

These mixtures serve as controlled matrices for evaluating the performance, compatibility, and visual properties of colouring materials used in PVC-P polymer systems.

Key Topics

Composition of Basic Mixtures

EN 14469-1:2004 defines the specific constituents to be used when creating the basic mixtures, which typically include:

  • Vinyl chloride homopolymer (PVC resin)
  • Plasticizer (e.g., diisodecyl phthalate)
  • Epoxidized soybean oil (ESO)
  • Liquid barium/zinc (Ba/Zn) stabilizer
  • Lubricant (e.g., stearic acid)
  • Titanium dioxide pigment (for Basic mixture B)

All raw materials must meet strict quality criteria and be free from inhomogeneity, ensuring valid pigment testing results.

Preparation Methods

The standard describes the rigorous procedure for mixing the materials:

  • High-speed mixing of PVC resin, stabilizer, and lubricant until a set temperature is achieved
  • Gradual addition of plasticizer, ESO, and, if needed, titanium dioxide pigment
  • Final cooling and storage requirements to prevent degradation or contamination

Differentiation of Basic Mixtures

  • Basic mixture A provides a transparent matrix for assessing the colour and clarity of pigments in PVC-P.
  • Basic mixture B contains added titanium dioxide, offering a white reference for testing opaque pigments or extenders.

Applications

EN 14469-1:2004 is essential for:

  • Pigment and additive manufacturers: Ensuring consistent evaluation of colouring materials intended for use in plasticized PVC products.
  • Quality control laboratories: Providing a standardized method for comparing pigment performance, colour stability, and compatibility in PVC-P systems.
  • Plastic product manufacturers: Assuring conformity and reproducibility when using pigments and extenders for PVC-P items like flooring, cables, films, and profiles.

The use of basic mixtures as per EN 14469-1:2004 helps reduce variability in testing, allowing more reliable selection and validation of colour formulations for PVC-P applications.

Related Standards

EN 14469-1:2004 references and is complemented by a range of related European and international standards, including:

  • EN 14469-2: Testing of colouring materials in plasticized polyvinyl chloride (PVC-P) - Part 2: Preparation of test specimens
  • EN ISO 489: Determination of refractive index in plastics
  • EN ISO 591-1: Titanium dioxide pigments for paints - Specifications and methods of test
  • EN ISO 1060-1: Designation system and specifications for vinyl chloride resins
  • EN ISO 1628-2: Determination of polymer viscosity in dilute solution
  • EN ISO 2114: Determination of acid values in plastics and binders
  • EN ISO 12185: Determination of density for crude petroleum and products
  • ISO 6271: Colour estimation by platinum-cobalt scale
  • EN 971-1: Paints and varnishes - General terms for coating materials

Implementing EN 14469-1:2004 in conjunction with these standards supports a harmonized approach to testing and ensures material consistency for the PVC manufacturing and pigment sectors.

Summary

EN 14469-1:2004 provides a vital framework for preparing and using standardized PVC-P mixtures in pigment and extender testing, ensuring quality, repeatability, and comparability throughout the plastics industry. If your operations involve pigment testing or formulation in flexible PVC products, compliance with EN 14469-1:2004 is crucial for reliable results and industry acceptance.

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Frequently Asked Questions

EN 14469-1:2004 is a standard published by the European Committee for Standardization (CEN). Its full title is "Pigments and extenders - Testing of colouring materials in plasticized polyvinyl chloride (PVC-P) - Part 1: Composition and preparation of basic mixtures". This standard covers: This Part of EN 14469 specifies a procedure for producing basic mixtures for the testing of colouring materials ) in plasticized polyvinyl chloride (PVC-P) materials, together with the composition of these basic mixtures. It distinguishes between: - basic mixture A (transparent basic mixture) - basic mixture B (white basic mixture)

This Part of EN 14469 specifies a procedure for producing basic mixtures for the testing of colouring materials ) in plasticized polyvinyl chloride (PVC-P) materials, together with the composition of these basic mixtures. It distinguishes between: - basic mixture A (transparent basic mixture) - basic mixture B (white basic mixture)

EN 14469-1:2004 is classified under the following ICS (International Classification for Standards) categories: 83.040.30 - Auxiliary materials and additives for plastics. The ICS classification helps identify the subject area and facilitates finding related standards.

EN 14469-1:2004 has the following relationships with other standards: It is inter standard links to ISO 6271:1997, EN ISO 1628-2:2020, EN 14469-2:2004, EN ISO 489:2022, CR 13694:1999, EN ISO 24024-1:2021, EN ISO 2114:2000, EN ISO 12185:2024, EN ISO 591-1:2000, EN 14469-3:2004. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

EN 14469-1:2004 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.PHãDQLFPigmente und Füllstoffe - Prüfung von Farbmitteln in weichmacherhaltigem Polyvinylchlorid (PVC-P) - Teil 1: Zusammensetzung und Herstellen der GrundmischungenPigments et matieres de charge - Essai des matieres colorantes dans le chlorure de polyvinyle plastifié (PVC-P) - Partie 1: Composition et préparation des mélanges de basePigments and extenders - Testing of colouring materials in plasticized polyvinyl chloride (PVC-P) - Part 1: Composition and preparation of basic mixtures83.040.30Pomožni materiali in aditivi za polimerne materialeAuxiliary materials and additives for plasticsICS:Ta slovenski standard je istoveten z:EN 14469-1:2004SIST EN 14469-1:2004en01-september-2004SIST EN 14469-1:2004SLOVENSKI
STANDARD
EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 14469-1May 2004ICS 83.040.30English versionPigments and extenders - Testing of colouring materials inplasticized polyvinyl chloride (PVC-P) - Part 1: Composition andpreparation of basic mixturesPigments et matières de charge - Essai des matièrescolorantes dans le chlorure de polyvinyle plastifié (PVC-P) -Partie 1: Composition et préparation des mélanges de basePigmente und Füllstoffe - Prüfung von Farbmitteln inweichmacherhaltigem Polyvinylchlorid (PVC-P) - Teil 1:Zusammensetzung und Herstellen der GrundmischungenThis European Standard was approved by CEN on 9 February 2004.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2004 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 14469-1:2004: ESIST EN 14469-1:2004

inplasticized polyvinyl chloride (PVC-P) materials, together with the composition of these basic mixtures.It distinguishes between:- basic mixture A (transparent basic mixture)- basic mixture B (white basic mixture)2 Normative referencesThis European Standard incorporates by dated or undated reference, provisions from other publications. Thesenormative references are cited at the appropriate places in the text, and the publications are listed hereafter. Fordated references, subsequent amendments to or revisions of any of these publications apply to this EuropeanStandard only when incorporated in it by amendment or revision. For undated references the latest edition of thepublication referred to applies (including amendments).EN 14469-2, Pigments and extenders — Testing of colouring materials in plasticized polyvinyl chloride (PVC-P) —Part 2: Preparation of test specimens.EN ISO 489, Plastics — Determination of refractive index (ISO 489:1999).EN ISO 591-1, Titanium dioxide pigments for paints — Part 1: Specifications and methods of test (ISO 591-1:2000).EN ISO 1060-1, Plastics — Homopolymer and copolymer resins of vinyl chloride — Part 1: Designation system andbasis for specifications (ISO 1060-1:1998).EN ISO 1628-2, Plastics - Determination of the viscosity of polymers in dilute solution using capillary viscometers— Part 2: Poly(vinyl chloride) resins (ISO 1628-2:1998).EN ISO 2114, Plastics (polyester resins) and paints and varnishes (binders) - Determination of partial acid valueand total acid value (ISO 2114:2000).EN ISO 12185, Crude petroleum and petroleum products — Determination of density — Oscillating U-tube method(ISO 12185:1996).ISO 6271, Clear liquids — Estimation of colour by the platinum-cobalt scale.3 Constituents of
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