EN 15560:2023
(Main)Inorganic fertilizers - Determination of total nitrogen in calcium cyanamide nitrate free
Inorganic fertilizers - Determination of total nitrogen in calcium cyanamide nitrate free
This document specifies a method for the determination of total nitrogen in nitrate-free calcium cyanamide.
Anorganische Düngemittel - Bestimmung von Gesamtstickstoff in nitratfreiem Kalkstickstoff
Dieses Dokument legt ein Verfahren zur Bestimmung von Gesamtstickstoff in nitratfreiem Kalkstickstoff fest.
Engrais inorganiques - Dosage de l'azote total dans la cyanamide calcique exempte de nitrate
Le présent document spécifie une méthode de détermination de l’azote total dans la cyanamide calcique exempte de nitrate.
Anorganska gnojila - Določanje celotnega dušika v kalcijevem cianoamidu, ki ne vsebuje nitratov
Ta evropski standard določa metodo za določanje celotnega dušika v kalcijevem cianoamidu, ki ne vsebuje nitratov.
General Information
- Status
- Published
- Publication Date
- 22-Aug-2023
- Technical Committee
- CEN/TC 260 - Fertilizers and liming materials
- Drafting Committee
- CEN/TC 260/WG 7 - Chemical analysis
- Current Stage
- 6060 - Definitive text made available (DAV) - Publishing
- Start Date
- 23-Aug-2023
- Due Date
- 29-Jun-2023
- Completion Date
- 23-Aug-2023
Relations
- Replaces
EN 15560:2009 - Fertilizers - Determination of total nitrogen in calcium cyanamide nitrate free - Effective Date
- 18-Jan-2023
Overview
EN 15560:2023 - Inorganic fertilizers: Determination of total nitrogen in calcium cyanamide (nitrate free) specifies a wet-chemistry method to measure total nitrogen in nitrate‑free calcium cyanamide. Prepared by CEN/TC 260, this standard supersedes EN 15560:2009 and defines the digestion, distillation and titration procedure (Kjeldahl-type) used by laboratories to produce legally and technically defensible nitrogen content results.
Key topics and technical requirements
- Scope: Method applies only to nitrate‑free calcium cyanamide samples.
- Principle: Acid digestion in sulfuric acid with a catalyst → alkaline distillation of liberated ammonia → absorption in excess standardized sulfuric acid → back‑titration with standardized NaOH or KOH.
- Reagents: Specifies analytical‑grade reagents and low‑conductivity water. Key reagents include concentrated sulfuric acid, potassium sulfate, copper(II) oxide or copper(II) sulfate catalyst, several strengths of sulfuric and hydroxide solutions, and indicator solutions (mixed indicator or methyl red).
- Apparatus: Standard Kjeldahl/distillation setup (round‑bottom flask, condenser, splash head). Automatic distillation is permitted if statistically equivalent. Glassware (pipettes, burettes, flasks) of specified volumes is required.
- Procedure variants: Table 1 defines three variants (a, b, c) with different aliquots, acid strengths and titrant concentrations (e.g., 50, 100 or 200 ml aliquots and corresponding titrant molarities). Digestion, dilution, controlled distillation rate, and titration endpoints are prescribed.
- Quality checks: Mandatory blank test (omit sample) and a control test using 1 g potassium thiocyanate to verify technique and apparatus performance.
- Calculation and reporting: Nitrogen mass fraction is calculated as N% = (Vblank – Vsample) × F, where V are titrant volumes and F is a factor accounting for sample mass, dilution and volumetric equivalents. Test reports must identify the sample, reference EN 15560:2023, provide result as % N, sampling/analysis dates and any deviations or incidents.
Applications and users
- Who uses it: fertilizer manufacturers, independent testing laboratories, quality control departments, regulatory authorities and R&D labs working with calcium cyanamide fertilizers.
- Practical uses: product certification and labeling, batch quality control, compliance testing with fertilizer regulations, comparative analyses during product development, and dispute resolution where certified nitrogen content is required.
Related standards
- EN 1482-2 - Sampling and sample preparation (referenced for sample prep)
- EN 12944-1 / EN 12944-2 - Vocabulary for fertilizers and liming materials
- EN 15560:2023 replaces EN 15560:2009
Keywords: EN 15560:2023, calcium cyanamide, total nitrogen determination, nitrate‑free, inorganic fertilizers, Kjeldahl digestion, distillation, fertilizer testing.
Frequently Asked Questions
EN 15560:2023 is a standard published by the European Committee for Standardization (CEN). Its full title is "Inorganic fertilizers - Determination of total nitrogen in calcium cyanamide nitrate free". This standard covers: This document specifies a method for the determination of total nitrogen in nitrate-free calcium cyanamide.
This document specifies a method for the determination of total nitrogen in nitrate-free calcium cyanamide.
EN 15560:2023 is classified under the following ICS (International Classification for Standards) categories: 65.080 - Fertilizers. The ICS classification helps identify the subject area and facilitates finding related standards.
EN 15560:2023 has the following relationships with other standards: It is inter standard links to EN 15560:2009. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.
EN 15560:2023 is associated with the following European legislation: EU Directives/Regulations: 2019/1009; Standardization Mandates: M/564, M/564 AMD 1. When a standard is cited in the Official Journal of the European Union, products manufactured in conformity with it benefit from a presumption of conformity with the essential requirements of the corresponding EU directive or regulation.
You can purchase EN 15560:2023 directly from iTeh Standards. The document is available in PDF format and is delivered instantly after payment. Add the standard to your cart and complete the secure checkout process. iTeh Standards is an authorized distributor of CEN standards.
Standards Content (Sample)
SLOVENSKI STANDARD
01-junij-2024
Nadomešča:
SIST EN 15560:2009
Anorganska gnojila - Določanje celotnega dušika v kalcijevem cianoamidu, ki ne
vsebuje nitratov
Inorganic fertilizers - Determination of total nitrogen in calcium cyanamide nitrate free
Anorganische Düngemittel - Bestimmung von Gesamtstickstoff in nitratfreiem
Kalkstickstoff
Engrais inorganiques - Dosage de l'azote total dans la cyanamide calcique exempte de
nitrate
Ta slovenski standard je istoveten z: EN 15560:2023
ICS:
65.080 Gnojila Fertilizers
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 15560
EUROPEAN STANDARD
NORME EUROPÉENNE
August 2023
EUROPÄISCHE NORM
ICS 65.080 Supersedes EN 15560:2009
English Version
Inorganic fertilizers - Determination of total nitrogen in
calcium cyanamide nitrate free
Engrais inorganiques - Dosage de l'azote total dans la Anorganische Düngemittel - Bestimmung von
cyanamide calcique exempte de nitrate Gesamtstickstoff in nitratfreiem Kalkstickstoff
This European Standard was approved by CEN on 26 June 2023.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 15560:2023 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 4
5 Reagents . 4
6 Apparatus and equipment . 5
7 Sampling and sample preparation . 6
8 Procedure. 6
8.1 Preparation of the solution for analysis . 6
8.2 Analysis of the solution . 6
8.3 Blank test . 7
8.4 Control test . 7
9 Expression of the result . 7
10 Test report . 8
Bibliography . 9
European foreword
This document (EN 15560:2023) has been prepared by Technical Committee CEN/TC 260 “Fertilizers
and liming materials”, the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by February 2024, and conflicting national standards
shall be withdrawn at the latest by February 2024.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 15560:2009.
In comparison with the previous edition EN 15560:2009, the following technical modifications have
been made:
— deletion of former tables and addition of a technically revised Table (8.2);
— rewording of the control test (8.4);
— deletion of distillation apparatus drawings;
— rewording of the Expression of the result (Clause 8).
This document has been prepared under a standardization request addressed to CEN by the European
Commission. The Standing Committee of the EFTA States subsequently approves these requests for its
Member States.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
1 Scope
This document specifies a method for the determination of total nitrogen in nitrate-free calcium
cyanamide.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1482-2, Fertilizers and liming materials — Sampling and sample preparation — Part 2: Sample
preparation
EN 12944-1, Fertilizers and liming materials — Vocabulary — Part 1: General terms
EN 12944-2, Fertilizers and liming materials — Vocabulary — Part 2: Terms relating to fertilizers
3 Terms and definitions
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