Standard Specification for Methyl Isoamyl Ketone

ABSTRACT
This specification covers the properties and requirements for 98 % grade methyl isoamyl ketone for use in paint, varnish, lacquer, and related products. The material shall be sampled and tested appropriately, and shall conform to properties as to apparent specific gravity, color (Pt-Co scale), distillation (initial boiling and dry points), water content, acidity as acetic acid, and purity.
SCOPE
1.1 This specification covers methyl isoamyl ketone (98 % grade) for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
30-Jun-2021

Relations

Effective Date
01-Jun-2012
Effective Date
15-Nov-2011
Effective Date
01-Jan-2010
Effective Date
01-Dec-2009
Effective Date
01-Oct-2008
Effective Date
01-Jun-2007
Effective Date
01-Jun-2007
Effective Date
01-Jun-2007
Effective Date
15-Nov-2006
Effective Date
15-Sep-2006
Effective Date
01-May-2006
Effective Date
01-Apr-2006
Effective Date
15-Oct-2005
Effective Date
15-May-2005
Effective Date
15-May-2005

Overview

ASTM D2917-07(2021) - Standard Specification for Methyl Isoamyl Ketone provides comprehensive requirements and standard test methods for 98% grade methyl isoamyl ketone (MIAK). This standard, developed by ASTM International, is specifically intended for manufacturers and users of paint, varnish, lacquer, and related products. By standardizing the properties and testing procedures for MIAK, ASTM D2917 ensures consistency, safety, and performance in chemical supply chains and end-user applications.

Methyl isoamyl ketone is a high-purity solvent prized for its role in industrial coatings. Adherence to ASTM D2917 assures that the material meets stringent criteria for purity, color, density, distillation characteristics, and chemical stability - all critical for optimal performance and regulatory compliance.

Key Topics

  • Grade Requirements: Details requirements for 98% purity methyl isoamyl ketone, including:

    • Apparent specific gravity (20/20 °C: 0.812-0.815 or 25/25 °C: 0.809-0.812)
    • Color (Pt-Co scale, max 15)
    • Distillation range (initial boiling point minimum 140°C, dry point maximum 148°C)
    • Maximum water content (0.1% by weight)
    • Maximum acidity as acetic acid (0.02% by weight)
    • Minimum purity (98% by weight)
  • Sampling and Testing: Specifies appropriate sampling and test methods to ensure batch conformity and consistency, referencing robust ASTM procedures for each property.

  • SI Units: Declares SI units as standard to maintain international coherence.

  • Rounding Practice: Directs rounding of test results using ASTM Practice E29 to ensure accuracy and repeatability in reporting.

  • Safety: Advises consulting supplier Material Safety Data Sheets (MSDS) for hazard information.

Applications

Methyl isoamyl ketone meeting ASTM D2917 is widely used across several industries requiring high-purity solvents, especially:

  • Paints and Coatings: Acts as a strong solvent in paint formulations, ensuring improved flow, leveling, and drying properties.
  • Varnishes & Lacquers: Used as a key ingredient to dissolve binders and resins, enhancing finish quality and application ease.
  • Industrial Cleaners: Its solvent power makes it effective for removing coatings or residues in industrial settings.
  • Chemical Manufacture: Serves as an intermediate or processing aid in various specialty chemical syntheses.

Strict adherence to the specification reduces risks of contamination, inconsistent performance, and regulatory penalties, supporting both quality control and client satisfaction.

Related Standards

ASTM D2917 references several important standards and guidelines to ensure proper measurement, testing, and conformity:

  • ASTM D1078: Distillation range of volatile organic liquids
  • ASTM D1209 / D5386: Color determination using Platinum-Cobalt scale and tristimulus colorimetry
  • ASTM D1364: Water content by Karl Fischer method
  • ASTM D1613: Acidity in volatile solvents and chemical intermediates
  • ASTM D3893: Purity determination by gas chromatography
  • ASTM D4052: Density measurement using a digital density meter
  • ASTM E29: Rounding of test data for specification conformance
  • ASTM E300: Sampling of industrial chemicals

For packaging, compliance with U.S. Federal Specification PPP-C-2020 may be required.

Practical Value

By following ASTM D2917-07(2021), manufacturers, distributors, and end-users can ensure safe handling, reliable performance, and regulatory compliance for methyl isoamyl ketone used in coatings and chemical processes. This standard serves as a critical benchmark for quality assurance, supporting downstream product consistency and industrial best practices.

Keywords: ASTM D2917, methyl isoamyl ketone, MIAK, solvent standard, industrial solvent specification, paint solvent requirements, lacquer solvent, varnish solvent, chemical compliance, test methods for solvents.

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ASTM D2917-07(2021) - Standard Specification for Methyl Isoamyl Ketone

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Frequently Asked Questions

ASTM D2917-07(2021) is a technical specification published by ASTM International. Its full title is "Standard Specification for Methyl Isoamyl Ketone". This standard covers: ABSTRACT This specification covers the properties and requirements for 98 % grade methyl isoamyl ketone for use in paint, varnish, lacquer, and related products. The material shall be sampled and tested appropriately, and shall conform to properties as to apparent specific gravity, color (Pt-Co scale), distillation (initial boiling and dry points), water content, acidity as acetic acid, and purity. SCOPE 1.1 This specification covers methyl isoamyl ketone (98 % grade) for use in paint, varnish, lacquer, and related products. 1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ABSTRACT This specification covers the properties and requirements for 98 % grade methyl isoamyl ketone for use in paint, varnish, lacquer, and related products. The material shall be sampled and tested appropriately, and shall conform to properties as to apparent specific gravity, color (Pt-Co scale), distillation (initial boiling and dry points), water content, acidity as acetic acid, and purity. SCOPE 1.1 This specification covers methyl isoamyl ketone (98 % grade) for use in paint, varnish, lacquer, and related products. 1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 For specific hazard information and guidance, see the supplier’s Material Safety Data Sheet. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

ASTM D2917-07(2021) is classified under the following ICS (International Classification for Standards) categories: 87.060.30 - Solvents. The ICS classification helps identify the subject area and facilitates finding related standards.

ASTM D2917-07(2021) has the following relationships with other standards: It is inter standard links to ASTM D1613-06(2012), ASTM D1078-11, ASTM D5386-10, ASTM D3893-03(2009), ASTM E29-08, ASTM D268-01(2007), ASTM D1364-02(2007), ASTM D1476-02(2007), ASTM E29-06b, ASTM E29-06a, ASTM E29-06, ASTM D1613-06, ASTM D5386-05, ASTM D1078-05, ASTM D1209-05. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

ASTM D2917-07(2021) is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D2917 −07 (Reapproved 2021)
Standard Specification for
Methyl Isoamyl Ketone
This standard is issued under the fixed designation D2917; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope Fischer Reagent Titration Method) (Withdrawn 2021)
D1476 Test Method for Heptane Miscibility of Lacquer
1.1 This specification covers methyl isoamyl ketone (98 %
Solvents (Withdrawn 2021)
grade) for use in paint, varnish, lacquer, and related products.
D1613 Test Method for Acidity in Volatile Solvents and
1.2 The following applies to all specified limits in this
Chemical Intermediates Used in Paint, Varnish, Lacquer,
standard: for purposes of determining conformance with this
and Related Products
standard, an observed value or a calculated value shall be
D3893 Test Method for Purity of Methyl Amyl Ketone and
rounded off “to the nearest unit” in the last right-hand digit
Methyl Isoamyl Ketone by Gas Chromatography
used in expressing the specification limit, in accordance with
D4052 Test Method for Density, Relative Density, and API
the rounding-off method of Practice E29.
Gravity of Liquids by Digital Density Meter
1.3 The values stated in SI units are to be regarded as D5386 Test Method for Color of Liquids Using Tristimulus
Colorimetry
standard. No other units of measurement are included in this
standard. E29 Practice for Using Significant Digits in Test Data to
Determine Conformance with Specifications
1.4 For specific hazard information and guidance, see the
E300 Practice for Sampling Industrial Chemicals
supplier’s Material Safety Data Sheet.
2.2 U.S. Federal Specification:
1.5 This international standard was developed in accor-
PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packaging
dance with internationally recognized principles on standard-
of
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom-
3. Properties
mendations issued by the World Trade Organization Technical
3.1 Methyl isoamyl ketone shall conform to the following
Barriers to Trade (TBT) Committee.
requirements:
Apparent specific gravity:
2. Referenced Documents
20/20 °C 0.812 to 0.815
2.1 ASTM Standards: or
25/25 °C 0.809 to 0.812
D268 Guide for Sampling and Testing Volatile Solvents and
Color, Pt-Co scale, max (Note 1) 15
Chemical Intermediates for Use in Paint and Related
Distillation, °C
Coatings and Material (Withdrawn 2021) Initial boiling point, min 140
Dry point, max 148
D1078 Test Method for Distillation Range of Volatile Or-
Water, wt %, max 0.1
ganic Liquids
Acidity as acetic acid, wt %, max 0.02
Purity, wt %, min 98
D1209 Test Method for Color of Clear Liquids (Platinum-
__________________
Cobalt Scale)
NOTE 1—Instrumental Pt-Co color determined by Test Method D5386
D1364 Test Method for Water in Volatile Solvents (Karl
has been shown to have no statistically significant difference from Pt-Co
color determined by Test Method D1209. However, it is not known
whether methyl isoamyl ketone was part of the sample set included in the
This specification is under the jurisdiction of ASTM Committee D01 on Paint
interlaboratory study.
and Related Coatings, Materials, andApplications and is
...

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