Standard Specification for Hafnium and Hafnium Alloy Strip, Sheet, and Plate

ABSTRACT
This specification covers the standard requirements for two grades of wrought hafnium and hafnium alloy strip, sheet, and plate: Grade R1 for nuclear applications and Grade R3 for commercial applications. The materials shall be made from ingots that are produced in a furnace by vacuum or plasma arc melting, vacuum electron-beam melting, a combination of these three methods, or other melting process conventionally used for reactive metals. The various mill products shall be formed with the conventional extrusion, forging, or rolling equipment normally found in primary ferrous and nonferrous plants. The sheet, strip, and plate shall either be hot-rolled or cold-rolled and shall be supplied in the recrystallized annealed condition. Grades R1 and R3 metal shall conform to the chemical composition requirements for aluminum, carbon, chromium, copper, hydrogen, iron, molybdenum, nickel, niobium, nitrogen, oxygen, silicon, tantalum, tin, titanium, tungsten, uranium, vanadium, zirconium, and hafnium as shall be determined by chemical analysis. Mechanical properties, which shall be determined by tension tests both in longitudinal and transverse direction, shall meet the prescribed tensile strength, yield strength, and elongation requirements. Corrosion testing in water shall also be performed to determine the corrosion resistance of the materials.
SCOPE
1.1 This specification covers two grades of wrought hafnium and hafnium alloy strip, sheet, and plate as follows:  
1.1.1 Grade R1 for nuclear applications, and  
1.1.2 Grade R3 for commercial applications.  
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm2, the values stated in either inch-pound or SI units are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must be used independently of the other. SI values cannot be mixed with inch-pound values.  
1.3 The following precautionary caveat pertains only to the test method portions of this specification.  This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:B776 −12
Standard Specification for
1
Hafnium and Hafnium Alloy Strip, Sheet, and Plate
This standard is issued under the fixed designation B776; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope turer and purchaser, a lot shall be limited to the product of an
8 h period for final continuous anneal, or to a single furnace
1.1 This specification covers two grades of wrought haf-
load for final batch anneal.
nium and hafnium alloy strip, sheet, and plate as follows:
1.1.1 Grade R1 for nuclear applications, and 3.2 Forms:
1.1.2 Grade R3 for commercial applications. 3.2.1 strip, n—a flat product, may be supplied in coil, less
than 6 in. (150 mm) in width and from0.005 to0.188in. (0.13
1.2 Unlessasingleunitisused,forexamplecorrosionmass
2 to 4.8 mm) in thickness.
gain in mg/dm , the values stated in either inch-pound or SI
3.2.2 sheet, n—a flat product 6 in. (150 mm) or more in
units are to be regarded separately as standard. The values
width and from 0.005 to 0.188 in. (0.13 to 4.8 mm) in
stated in each system are not exact equivalents; therefore each
thickness.
system must be used independently of the other. SI values
cannot be mixed with inch-pound values.
3.2.3 plate, n—a flat product more than 0.125 in. (3.2 mm)
in thickness.
1.3 The following precautionary caveat pertains only to the
test method portions of this specification. This standard does
4. Classification
not purport to address all of the safety concerns, if any,
4.1 Thestrip,sheet,orplateistobefurnishedintwogrades
associated with its use. It is the responsibility of the user of this
standard to establish appropriate safety and health practices as follows:
4.1.1 Grade R1 (Nuclear) — Unalloyed.
and determine the applicability of regulatory limitations prior
to use. 4.1.2 Grade R3 (Commercial) — Unalloyed.
5. Ordering Information
2. Referenced Documents
2
5.1 Purchase orders for materials under this specification
2.1 ASTM Standards:
shall include the following information as applicable:
E8Test Methods for Tension Testing of Metallic Materials
5.1.1 Quantity (weight or number of pieces),
E21TestMethodsforElevatedTemperatureTensionTestsof
5.1.2 Form (3.2) and dimensions,
Metallic Materials
5.1.3 Grade (4.1),
E29Practice for Using Significant Digits in Test Data to
5.1.4 Lot definition for continuous anneal, if applicable
Determine Conformance with Specifications
(3.1),
5.1.5 Metallurgical condition, if not in the recrystallized
3. Terminology
annealed condition (6.3),
3.1 Lot Definition:
5.1.6 Chemical analysis of elements not listed (7.1.3),
3.1.1 lot,n—alotshallconsistofamaterialofthesamesize,
5.1.7 Product analysis (7.1.1.1 and 7.1.3),
shape, condition, and finish produced from the same ingot by
5.1.8 Tensile test temperatures (8.1),
the same reduction schedule and the same heat treatment
5.1.9 Mechanical properties, for Grade R3 (8.1),
parameters. Unless otherwise agreed upon between manufac-
5.1.10 Corrosion properties and testing, (9.1 and 9.1.3),
5.1.11 Material condition and finish (12.1 – 12.5),
5.1.12 Workmanship standards and methods of inspection
1
This specification is under the jurisdiction of ASTM Committee B10 on
(Section 13),
Reactive and Refractory Metals and Alloys and is the direct responsibility of
Subcommittee B10.02 on Zirconium and Hafnium.
5.1.13 Purchaser inspection (16.1),
Current edition approved Nov. 1, 2012. Published December 2012. Originally
5.1.14 Rejection and referee (17.2),
approved in 1987. Last previous edition approved in 2007 as B776–07. DOI:
5.1.15 Certification report (Section 18),
10.1520/B0776-12.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or 5.1.16 Product marking (Section 19), and
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
5.1.17 Packaging and package marking (Section 20).
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
B776−12
NOTE 1—A typical ordering description is as follows: twenty-eight TABLE 2 Check Analyses Limits
pieces hafnium plate, annealed; mechanically descaled and pickled; 0.158
Element Variations Under Min. or
by 6.000 in. thick by 18-in. long lengths; Grade R1; ASTM B776–07.
Over Max. %
Hydrogen 0.002
Nitrogen 0.01
6. Materials and Manufacture
Carbon 0.01
6.1 Material covered by this specification shall be made Zirconium 0.02
Iron and Chromium 0.025
from ingots that are produced by vacuum or plasma arc
Ti
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: B776 − 07 B776 − 12
Standard Specification for
1
Hafnium and Hafnium Alloy Strip, Sheet, and Plate
This standard is issued under the fixed designation B776; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This specification covers two grades of wrought hafnium and hafnium alloy strip, sheet, and plate as follows:
1.1.1 Grade R1 for nuclear applications, and
1.1.2 Grade R3 for commercial applications.
2
1.2 Unless a single unit is used, for example corrosion mass gain in mg/dm , the values stated in either inch-pound or SI units
are to be regarded separately as standard. The values stated in each system are not exact equivalents; therefore each system must
be used independently of the other. SI values cannot be mixed with inch-pound values.
1.3 The following precautionary caveat pertains only to the test method portions of this specification. This standard does not
purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to
establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
E8 Test Methods for Tension Testing of Metallic Materials
E21 Test Methods for Elevated Temperature Tension Tests of Metallic Materials
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
3. Terminology
3.1 Lot Definition:
3.1.1 lot, n—a lot shall consist of a material of the same size, shape, condition, and finish produced from the ingot or powder
blend same ingot by the same reduction schedule and the same heat treatment parameters. Unless otherwise agreed upon between
manufacturer and purchaser, a lot shall be limited to the product of an 8 h period for final continuous anneal, or to a single furnace
load for final batch anneal.
3.2 Forms: Forms:
3.2.1 strip, n—a flat product, may be supplied in coil, less than 6 in. (150 mm) in width and from 0.005 to 0.188 in. (0.13 to
4.8 mm) in thickness.
3.2.2 sheet, n—a flat product 6 in. (150 mm) or more in width and from 0.005 to 0.188 in. (0.13 to 4.8 mm) in thickness.
3.2.3 plate, n—a flat product more than 0.1880.125 in. (4.8(3.2 mm) in thickness.
4. Classification
4.1 The strip, sheet, or plate is to be furnished in two grades as follows:
4.1.1 Grade R1 (Nuclear) — Unalloyed.
4.1.2 Grade R3 (Commercial) — Unalloyed.
5. Ordering Information
5.1 Purchase orders for materials under this specification shall include the following information as applicable:
5.1.1 Quantity (weight or number of pieces),
1
This specification is under the jurisdiction of ASTM Committee B10 on Reactive and Refractory Metals and Alloys and is the direct responsibility of Subcommittee
B10.02 on Zirconium and Hafnium.
Current edition approved May 1, 2007Nov. 1, 2012. Published May 2007December 2012. Originally approved in 1987. Last previous edition approved in 20062007 as
B776 – 06.B776 – 07. DOI: 10.1520/B0776-07.10.1520/B0776-12.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
B776 − 12
5.1.2 Form (3.2) and dimensions,
5.1.3 Grade (4.1),
5.1.4 Lot definition for continuous anneal, if applicable (3.1),
5.1.5 Metallurgical condition, if not in the recrystallized annealed condition (6.3),
5.1.6 Chemical analysis of elements not listed (7.1.3),
5.1.7 Product analysis (7.1.1.1 and 7.1.3),
5.1.8 Tensile test temperatures (8.1),
5.1.9 Mechanical properties, for Grade R3 (8.1),
5.1.10 Corrosion properties and testing, (9.1 and 9.1.3),
5.1.11 Material condition and finish (12.1-12.5),
5.1.12 Workmanship standards and methods of inspection (Section 13),
5.1.13 Purchaser inspection (16.1),
5.1.14 Rejection and referee (17.2),
5.1.15 Certification report (Section 18),
5.1.16 Product marking (Section 19), and
5.1.17 Packaging and package marking (Section 20).
NOTE 1—A typical ordering description is as follows: twenty-eight pieces hafni
...

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