Standard Test Method for Ash in Biomass

SIGNIFICANCE AND USE
The ash content is an approximate measure of the mineral content and other inorganic matter in biomass.
The ash content is used in conjunction with other assays to determine the total composition of biomass samples.
SCOPE
1.1 This test method covers the determination of ash, expressed as the mass percent of residue remaining after dry oxidation (oxidation at 575 ± 25°C), of hard and soft woods, herbaceous materials (such as switchgrass and sericea), agricultural residues (such as corn stover, wheat straw, and bagasse), wastepaper (such as office waste, boxboard, and newsprint), acid and alkaline pretreated biomass, and the solid fraction of fermentation residues. All results are reported relative to the 105°C oven-dried mass of the sample. For particulate wood fuels, Test Method E 1534 should be used.
1.2 The values stated in SI units are to be regarded as the standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

Status
Historical
Publication Date
09-Nov-2001
Current Stage
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ASTM E1755-01 - Standard Test Method for Ash in Biomass
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E 1755 – 01
Standard Test Method for
1
Ash in Biomass
This standard is issued under the fixed designation E 1755; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope 4.2 The ash content is used in conjunction with other assays
to determine the total composition of biomass samples.
1.1 This test method covers the determination of ash,
expressed as the mass percent of residue remaining after dry
5. Apparatus
oxidation (oxidation at 575 6 25°C), of hard and soft woods,
5.1 Ashing Crucibles, 50 mL, platinum crucibles are pre-
herbaceous materials (such as switchgrass and sericea), agri-
ferred, but silica or porcelain crucibles may be used.
cultural residues (such as corn stover, wheat straw, and
5.2 Muffle Furnace, an electric furnace is recommended for
bagasse), wastepaper (such as office waste, boxboard, and
igniting the sample. The furnace should be fitted with an
newsprint), acid and alkaline pretreated biomass, and the solid
indicating pyrometer or thermocouple, so that the required
fraction of fermentation residues. All results are reported
temperature of 575 6 25°C can be maintained.
relative to the 105°C oven-dried mass of the sample. For
5.3 Analytical Balance, sensitive to 0.1 mg.
particulate wood fuels, Test Method E 1534 should be used.
5.4 Desiccator, using anhydrous calcium sulfate.
1.2 The values stated in SI units are to be regarded as the
5.5 Drying Oven, with temperature control of 105 6 2°C.
standard.
1.3 This standard does not purport to address all of the
6. Test Specimen
safety concerns, if any, associated with its use. It is the
6.1 Test specimens suitable for analysis by this test method
responsibility of the user of this standard to establish appro-
are as follows:
priate safety and health practices and determine the applica-
6.1.1 Prepared biomass samples that have been prepared
bility of regulatory limitations prior to use.
according to Practice E 1757.
2. Referenced Documents 6.1.2 Biomass feedstocks, dried at 105°C according to Test
2 Method E 1756,
2.1 ASTM Standards:
6.1.3 Pretreated biomass, dried at 105°C according to Test
E 1534 Test Method for Determination of Ash Content of
Method E 1756, and
Particulate Wood Fuels
6.1.4 The solids fraction of fermentation residues, dried at
E 1756 TestMethodfortheDeterminationofTotalSolidsin
105°C according to Test Method E 1756.
Biomass
6.2 The test specimen shall consist of approximately 0.5 to
E 1757 Practice for Preparation of Biomass for Composi-
1.0 g of sample obtained in such a manner to ensure that it is
tional Analysis
representative of the entire lot of material being tested.
3. Terminology
NOTE 1—All samples should be ground or milled to reduce the size of
3.1 Descriptions of Terms Specific to This Standard: the large pieces to less than 1 mm in diameter. The sample is then redried
at 105°C prior to testing. Prepared biomass can be used in place of 105°C
3.1.1 ash—the inorganic residue left after ignition at 5756
dried material, but the mass of the material must be corrected for its
25°C.
moisture content by using Test Method E 1756, prior to calculating the
ash.
4. Significance and Use
4.1 The ash content is an approximate measure of the
7. Procedure
mineral content and other inorganic matter in biomass.
7.1 Markapanorcruciblewithauniqueidentificationusing
a porcelain marker, place it in the muffle furnace at 575 6
1
This test method is under the jurisdiction of ASTM Committee E48 on
25°C. Remove the pan or crucible from the furnace, cool to
Biotechnology and is the direct responsibility of Subcommittee E48.05 on Biomass
room temperature in a desiccator, and weigh to the nearest 0.1
Conversion.
mg. For an aluminum pan, two hours of heating at 575 6 25°C
Current edition approved November 10, 2001. Published February 2002.
Originally published as E1755-95. Last previous edition E1755-95. will be sufficient to bring the pan to constant mass. With a
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
crucible, however, the following procedure is used: place the
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
crucible in the furnace at 5756 25°C for 3 h. Remove the
Standards volume information, refer to the standard’s Document Summary page on
crucible and place in a desiccator.Allow the crucible to cool to
the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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E1755–01
room temperature and then weigh the crucible to the near
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