EN ISO 18857-2:2011
(Main)Water quality - Determination of selected alkylphenols - Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered samples following solid-phase extraction and derivatisation (ISO 18857-2:2009)
Water quality - Determination of selected alkylphenols - Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered samples following solid-phase extraction and derivatisation (ISO 18857-2:2009)
ISO 18857-2:2009 specifies a gas chromatographic-mass spectrometric (GC‑MS) determination of selected alkylphenols, their ethoxylates and bisphenol A in non-filtered samples of drinking, ground, surface, and waste waters following solid‑phase extraction and derivatisation.
The lower limit of the working range depends on the matrix, on the specific compound to be analysed and on the sensitivity of the mass spectrometric detection unit. The method is applicable in a working range from 0,005 µg/l to 0,2 µg/l for 4-(1,1,3,3-tetramethylbutyl)phenol (OP), and its mono- (OP1EO) and diethoxylate (OP2EO), from 0,03 µg/l to 0,2 µg/l for 4-nonylphenol (mixture of isomers) (NP), and its mono- (NP1EO) and diethoxylate (NP2EO), and from 0,05 µg/l to 0,2 µg/l for bisphenol A (BPA).
Depending on the matrix, the method is also applicable to waste water in a working range from 0,1 µg/l to 50 µg/l for OP, OP1EO, OP2EO and BPA, and from 0,5 µg/l to 50 µg/l for NP, NP1EO and NP2EO. The working ranges are based on experimental work carried out in ruggedness testing. Water samples containing suspended matter at concentrations of more than 500 mg/l and waste water samples are extracted by passing a 100 ml sample through the cartridge.
Wasserbeschaffenheit - Bestimmung von ausgewählten Alkylphenolen - Teil 2: Gaschromatographische-massenspektrometrische Bestimmung von Alkylphenolen, deren Ethoxylaten und Bisphenol A für nichtfiltrierte Proben unter Verwendung der Festphasenextraktion und Derivatisierung (ISO 18857-2:2009)
Dieser Teil von ISO 18857 legt die gaschromatographisch-massenspektrometrische (GC-MS) Bestimmung
ausgewählter Alkylphenole, ihrer Ethoxylate und Bisphenol A in nichtfiltrierten Trink-, Grund-, Oberflächenund
Abwasserproben nach Festphasenextraktion und Derivatisierung fest.
Die untere Grenze des Arbeitsbereichs hängt von der Matrix, den einzelnen zu analysierenden Verbindungen
und der Empfindlichkeit der massenspektrometrischen Detektionseinheit ab. Das Verfahren ist im
Arbeitsbereich von 0,005 µg/l bis 0,2 µg/l für 4-(1,1,3,3-Tetramethylbutyl)phenol (OP), sein Mono- (OP1EO)
und Diethoxylat (OP2EO), von 0,03 µg/l bis 0,2 µg/l für 4-Nonylphenol (Isomerengemisch) (NP), sein Mono-
(NP1EO) und Diethoxylat (NP2EO) und von 0,05 µg/l bis 0,2 µg/l für Bisphenol A (BPA) anwendbar.
In Abhängigkeit von der Matrix ist das Verfahren auch für Abwasser im Arbeitsbereich von 0,1 µg/l bis 50 µg/l
für OP, OP1EO, OP2EO und BPA und von 0,5 µg/l bis 50 µg/l für NP, NP1EO und NP2EO anwendbar. Die
angegebenen Arbeitsbereiche beruhen auf Robustheitsuntersuchungen. Wasserproben, die mehr als
500 mg/l Schwebstoffe enthalten, und Abwasserproben werden extrahiert, indem 100 ml Probe durch die
Kartusche laufen gelassen werden.
Qualité de l'eau - Dosage d'alkylphénols sélectionnés - Partie 2: Dosage par chromatographie en phase gazeuse-spectrométrie de masse d'alkylphénols, de leurs éthoxylates et du bisphénol A dans des échantillons non filtrés après extraction en phase solide et dérivation (ISO 18857-2:2009)
L'ISO 18857-2:2009 spécifie le dosage par chromatographie en phase gazeuse-spectrométrie de masse (CG‑SM) d'alkylphénols sélectionnés, de leurs éthoxylates et du bisphénol A dans des échantillons non filtrés d'eau potable, d'eaux souterraines, d'eaux de surface et d'eaux résiduaires après extraction en phase solide et dérivation.
La limite inférieure du domaine de travail dépend de la matrice, du composé spécifique à analyser et de la sensibilité de l'unité de détection de spectrométrie de masse. La méthode est applicable dans un domaine de travail allant de 0,005 µg/l à 0,2 µg/l pour le 4‑(1,1,3,3‑tétraméthylbutyl)phénol (OP) et ses mono- (OP1EO) et diéthoxylates (OP2EO), de 0,03 µg/l à 0,2 µg/l pour le 4‑nonylphénol (mélange d'isomères) (NP) et ses mono- (NP1EO) et diéthoxylates (NP2EO), et de 0,05 µg/l à 0,2 µg/l pour le bisphénol A (BPA).
Selon la matrice, la méthode est également applicable aux eaux résiduaires dans un domaine de travail allant de 0,1 µg/l à 50 µg/l pour les composés OP, OP1EO, OP2EO et BPA, et de 0,5 µg/l à 50 µg/l pour les composés NP, NP1EO et NP2EO. Les domaines de travail se fondent sur des travaux expérimentaux menés au cours d'essais de robustesse. Les échantillons d'eau contenant des matières en suspension à des concentrations supérieures à 500 mg/l et les échantillons d'eaux résiduaires sont extraits en faisant circuler un échantillon de 100 ml dans la cartouche.
Kakovost vode - Določevanje izbranih alkilfenolov - 2. del: Metoda plinske kromatografije z masno selektivnim detektorjem za določevanje alkilfenolov, njihovih etoksilatov in bisfenola-A v nefiltriranih vzorcih po ekstrakciji na trdni fazi in derivatizaciji (ISO 18857-2:2009)
Ta del standarda ISO 18857 obravnava določevanje izbranih alkilfenolov, njihovih etoksilatov in bisfenola A s plinsko kromatografijo z masno selektivnim detektorjem (GC-MS) v nefiltriranih vzorcih pitne, podzemne, površinske in odpadne vode po ekstrakciji na trdni fazi in derivatizaciji. Spodnja meja delovnega razpona je odvisna od matriksa, specifične spojine za analizo in občutljivosti masno selektivnega detektorja. Metoda se za 4-(1,1,3,3-tetrametilbutil) fenol (OP) ter njegov mono- (OP1EO) in dietoksilat (OP2EO) uporablja v delovnem razponu 0,005 μg/–0,2 μg/l, za 4-nonilfenol (mešanica izomerov) (NP) ter njegov mono- (NP1EO) in dietoksilat (NP2EO) v razponu 0,03 μg/l–0,2 μg/l ter za bisfenol A (BPA) v razponu 0,05 μg/l–0,2 μg/l. Metoda se, odvisno od matriksa, uporablja tudi za odpadno vodo v delovnem razponu 0,1 μg/l–50 μg/l za 4-(1,1,3,3-tetrametilbutil) fenol, njegov mono- in dietoksilat in bisfenol A ter 0,5 μg/l–50 μg/l za 4-nonilfenol ter njegov mono- in dietoksilat. Delovni razponi temeljijo na eksperimentalnem delu, izvedenem med preskusom robustnosti. Ekstrakcija vzorcev vode, ki vsebujejo lebdečo snov v koncentracijah, višjih od 500 mg/l, in vzorcev odpadne vode se izvaja s pretočenjem 100 ml vzorca skozi filter.
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-februar-2012
.DNRYRVWYRGH'RORþHYDQMHL]EUDQLKDONLOIHQRORYGHO 0HWRGDSOLQVNH
NURPDWRJUDILMH]PDVQRVHOHNWLYQLPGHWHNWRUMHP]DGRORþHYDQMHDONLOIHQRORY
QMLKRYLKHWRNVLODWRYLQELVIHQROD$YQHILOWULUDQLKY]RUFLKSRHNVWUDNFLMLQDWUGQLID]L
LQGHULYDWL]DFLML ,62
Water quality - Determination of selected alkylphenols - Part 2: Gas chromatographic-
mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in
non-filtered samples following solid-phase extraction and derivatisation (ISO 18857-
2:2009)
Wasserbeschaffenheit - Bestimmung von ausgewählten Alkylphenolen - Teil 2:
Gaschromatographische-massenspektrometrische Bestimmung von Alkylphenolen,
deren Ethoxylaten und Bisphenol-A für nicht filtrierte Proben unter Verwendung der
Festphasenextraktion und Derivatisierung (ISO 18857-2:2009)
Qualité de l'eau - Dosage d'alkylphénols sélectionnés - Partie 2: Dosage par
chromatographie en phase gazeuse-spectrométrie de masse d'alkylphénols, de leurs
éthoxylates et de bisphénol A dans des échantillons non filtrés après extraction en phase
solide et dérivation (ISO 18857-2:2009)
Ta slovenski standard je istoveten z: EN ISO 18857-2:2011
ICS:
13.060.50 3UHLVNDYDYRGHQDNHPLþQH Examination of water for
VQRYL chemical substances
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EUROPEAN STANDARD
EN ISO 18857-2
NORME EUROPÉENNE
EUROPÄISCHE NORM
November 2011
ICS 13.060.50
English Version
Water quality - Determination of selected alkylphenols - Part 2:
Gas chromatographic-mass spectrometric determination of
alkylphenols, their ethoxylates and bisphenol A in non-filtered
samples following solid-phase extraction and derivatisation (ISO
18857-2:2009)
Qualité de l'eau - Dosage d'alkylphénols sélectionnés - Wasserbeschaffenheit - Bestimmung von ausgewählten
Partie 2: Dosage par chromatographie en phase gazeuse- Alkylphenolen - Teil 2: Gaschromatographische-
spectrométrie de masse d'alkylphénols, de leurs massenspektrometrische Bestimmung von Alkylphenolen,
éthoxylates et du bisphénol A dans des échantillons non deren Ethoxylaten und Bisphenol A für nichtfiltrierte Proben
filtrés après extraction en phase solide et dérivation (ISO unter Verwendung der Festphasenextraktion und
18857-2:2009) Derivatisierung (ISO 18857-2:2009)
This European Standard was approved by CEN on 15 October 2011.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2011 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 18857-2:2011: E
worldwide for CEN national Members.
Contents Page
Foreword .3
Foreword
The text of ISO 18857-2:2009 has been prepared by Technical Committee ISO/TC 147 “Water quality” of the
International Organization for Standardization (ISO) and has been taken over as EN ISO 18857-2:2011 by
Technical Committee CEN/TC 230 “Water analysis” the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by May 2012, and conflicting national standards shall be withdrawn at the
latest by May 2012.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
Sweden, Switzerland and the United Kingdom.
Endorsement notice
The text of ISO 18857-2:2009 has been approved by CEN as a EN ISO 18857-2:2011 without any
modification.
INTERNATIONAL ISO
STANDARD 18857-2
First edition
2009-09-15
Water quality — Determination of
selected alkylphenols —
Part 2:
Gas chromatographic-mass
spectrometric determination of
alkylphenols, their ethoxylates and
bisphenol A in non-filtered samples
following solid-phase extraction and
derivatisation
Qualité de l'eau — Dosage d'alkylphénols sélectionnés —
Partie 2: Dosage par chromatographie en phase gazeuse-spectrométrie
de masse d'alkylphénols, de leurs éthoxylates et de bisphénol A dans
des échantillons non filtrés après extraction en phase solide et
dérivation
Reference number
ISO 18857-2:2009(E)
©
ISO 2009
ISO 18857-2:2009(E)
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ii © ISO 2009 – All rights reserved
ISO 18857-2:2009(E)
Contents Page
Foreword .iv
Introduction.v
1 Scope.1
2 Normative references.1
3 Principle.2
4 Interferences .2
5 Reagents.3
6 Apparatus.4
7 Sampling and sample pretreatment .5
8 Procedure.5
9 Calibration and analysis of samples .8
10 Expression of results.9
11 Test report.10
Annex A (informative) Example of a sorbent .11
Annex B (informative) Suitable capillary columns .12
Annex C (informative) Examples of chromatograms .13
Annex D (informative) Performance data .17
Bibliography.18
ISO 18857-2:2009(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 18857-2 was prepared by Technical Committee ISO/TC 147, Water quality, Subcommittee SC 2, Physical,
chemical and biochemical methods.
ISO 18857 consists of the following parts, under the general title Water quality — Determination of selected
alkylphenols:
⎯ Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass
selective detection
⎯ Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and
bisphenol A in non-filtered samples following solid-phase extraction and derivatisation
iv © ISO 2009 – All rights reserved
ISO 18857-2:2009(E)
Introduction
The user should be aware that particular problems could require the specifications of additional marginal
conditions.
INTERNATIONAL STANDARD ISO 18857-2:2009(E)
Water quality — Determination of selected alkylphenols —
Part 2:
Gas chromatographic-mass spectrometric determination of
alkylphenols, their ethoxylates and bisphenol A in non-filtered
samples following solid-phase extraction and derivatisation
WARNING — Persons using this part of ISO 18857 should be familiar with normal laboratory practice.
This part of ISO 18857 does not purport to address all of the safety problems, if any, associated with
its use. It is the responsibility of the user to establish appropriate safety and health practices and to
ensure compliance with any national regulatory conditions.
IMPORTANT — It is absolutely essential that tests conducted in accordance with this part of ISO 18857
be carried out by suitably qualified staff.
1 Scope
This part of ISO 18857 specifies a gas chromatographic-mass spectrometric (GC-MS) determination of
selected alkylphenols, their ethoxylates and bisphenol A in non-filtered samples of drinking, ground, surface,
and waste waters following solid-phase extraction and derivatisation.
The lower limit of the working range depends on the matrix, on the specific compound to be analysed and on
the sensitivity of the mass spectrometric detection unit. The method is applicable in a working range from
0,005 µg/l to 0,2 µg/l for 4-(1,1,3,3-tetramethylb
...
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