Chemicals used for treatment of water intended for human consumption - Iron (II) sulfate

This document is applicable to iron (II) sulfate heptahydrate and iron (II) sulfate monohydrate used for treatment of water intended for human consumption. It describes the characteristics of iron (II) sulfate heptahydrate and monohydrate, specifies the requirements and the corresponding analytical methods and gives information on their use in water treatment. It also determines the rules relating to safe handling (Annex B) and use of iron (II) sulfate (Annex A).

Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch - Eisen(II)sulfat

Dieses Dokument ist anzuwenden für Eisen(II)sulfat-Heptahydrat und Eisen(II)sulfat-Monohydrat zur Aufbereitung von Wasser für den menschlichen Gebrauch. Es beschreibt die Eigenschaften von Eisen(II)sulfat-Heptahydrat und  Monohydrat und legt die Anforderungen sowie die entsprechenden Analysenverfahren fest. Es enthält Angaben für deren Anwendung in der Wasseraufbereitung. Es legt darüber hinaus Regeln für die sichere Handhabung (Anhang B) und Verwendung von Eisen(II)sulfat fest (Anhang A).

Produits chimiques utilisés pour le traitement de l'eau destinée à la consommation humaine - Sulfate de fer (II)

Le présent document est applicable au sulfate de fer (II) heptahydraté et au sulfate de fer (II) monohydraté utilisés pour le traitement de l’eau destinée à la consommation humaine. Il décrit les caractéristiques du sulfate de fer (II) heptahydraté et monohydraté, spécifie les exigences et les méthodes d’analyse correspondantes et donne les informations sur son utilisation dans le traitement de l’eau. Il fixe également les règles relatives à la sécurité de manipulation (Annexe B) et d’utilisation du sulfate de fer (II) (Annexe A).

Kemikalije, ki se uporabljajo za pripravo pitne vode - Železov (II) sulfat

General Information

Status
Not Published
Public Enquiry End Date
15-Oct-2025
Current Stage
4020 - Public enquire (PE) (Adopted Project)
Start Date
19-Aug-2025
Due Date
06-Jan-2026
Completion Date
20-Oct-2025

Relations

Effective Date
04-Dec-2024

Overview

prEN 889:2025 (draft) is a CEN technical standard for Iron (II) sulfate - ferrous sulfate - used in the treatment of water intended for human consumption. It applies to the heptahydrate and monohydrate forms (and solutions derived from them), describing their identification, physical and chemical properties, minimum purity criteria, required analytical test methods, labelling/transportation/storage rules and guidance on safe handling and use (Annex A: use information; Annex B: safety rules). This draft supersedes EN 889:2023 and is subject to change while under enquiry.

Key topics and requirements

  • Scope and identification
    • Covers iron (II) sulfate heptahydrate and monohydrate and their solutions.
    • Chemical identifiers included: molecular masses (heptahydrate 278.02 g·mol−1; monohydrate 169.96 g·mol−1), empirical/chemical formulas and CAS numbers (e.g., 7782‑63‑0).
  • Commercial forms & physical properties
    • Heptahydrate: damp or free‑flowing light green/off‑white crystals; density ≈ 1.9 g·cm−3 (20 °C); solubility ≈ 550 g·dm−3 (25 °C).
    • Monohydrate: dry grey crystalline powder; density 1.4–1.7 g·cm−3 (25 °C); solubility 90 g·dm−3 (20 °C).
    • Solutions: dark green, saturated solution density ≈ 1.25 g·cm−3 (20 °C).
  • Purity criteria & impurities
    • Specifies minimum purity requirements and limits for common impurities; manufacturers must notify users of other impurities arising from raw materials or processes.
  • Analytical methods and testing
    • Includes requirements for sampling and analyses (normative references such as EN 17215 for iron‑based coagulants are cited).
  • Labelling, transport and storage
    • Requirements for risk/safety labelling, transportation rules and storage (including incompatibilities and long‑term stability).
  • Safety and use guidance
    • Annex A: practical guidance on origin, manufacturing, dosing, application methods, secondary effects and removal of excess product.
    • Annex B (normative): first aid, spillage, fire response and general safety rules.

Practical applications

  • Coagulation and iron‑based dosing in municipal and industrial drinking‑water treatment.
  • Removal of phosphate, color or as a precursor to iron‑based flocculation.
  • Use as a supplier specification for chemical manufacturers and distributors supplying waterworks.
  • Laboratory quality control and conformity testing of ferrous sulfate products destined for potable water use.

Who should use this standard

  • Water utilities and treatment plant operators
  • Chemical manufacturers and suppliers of iron (II) sulfate
  • Analytical and testing laboratories
  • Regulatory bodies and procurement officers
  • Health & safety and transport compliance officers

Related standards

  • EN 17215 - Chemicals used for treatment of water intended for human consumption - Iron‑based coagulants (referenced for analytical methods).
  • Note: Conformity with prEN 889 does not automatically imply national approval; national regulations remain applicable.
Draft

oSIST prEN 889:2025 - BARVE

English language
19 pages
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Frequently Asked Questions

oSIST prEN 889:2025 is a draft published by the Slovenian Institute for Standardization (SIST). Its full title is "Chemicals used for treatment of water intended for human consumption - Iron (II) sulfate". This standard covers: This document is applicable to iron (II) sulfate heptahydrate and iron (II) sulfate monohydrate used for treatment of water intended for human consumption. It describes the characteristics of iron (II) sulfate heptahydrate and monohydrate, specifies the requirements and the corresponding analytical methods and gives information on their use in water treatment. It also determines the rules relating to safe handling (Annex B) and use of iron (II) sulfate (Annex A).

This document is applicable to iron (II) sulfate heptahydrate and iron (II) sulfate monohydrate used for treatment of water intended for human consumption. It describes the characteristics of iron (II) sulfate heptahydrate and monohydrate, specifies the requirements and the corresponding analytical methods and gives information on their use in water treatment. It also determines the rules relating to safe handling (Annex B) and use of iron (II) sulfate (Annex A).

oSIST prEN 889:2025 is classified under the following ICS (International Classification for Standards) categories: 13.060.20 - Drinking water; 71.100.80 - Chemicals for purification of water. The ICS classification helps identify the subject area and facilitates finding related standards.

oSIST prEN 889:2025 has the following relationships with other standards: It is inter standard links to SIST EN 889:2023. Understanding these relationships helps ensure you are using the most current and applicable version of the standard.

oSIST prEN 889:2025 is available in PDF format for immediate download after purchase. The document can be added to your cart and obtained through the secure checkout process. Digital delivery ensures instant access to the complete standard document.

Standards Content (Sample)


SLOVENSKI STANDARD
01-oktober-2025
Kemikalije, ki se uporabljajo za pripravo pitne vode - Železov (II) sulfat
Chemicals used for treatment of water intended for human consumption - Iron (II) sulfate
Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch - Eisen(II)sulfat
Produits chimiques utilisés pour le traitement de l'eau destinée à la consommation
humaine - Sulfate de fer (II)
Ta slovenski standard je istoveten z: prEN 889
ICS:
13.060.20 Pitna voda Drinking water
71.100.80 Kemikalije za čiščenje vode Chemicals for purification of
water
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

DRAFT
EUROPEAN STANDARD
NORME EUROPÉENNE
EUROPÄISCHE NORM
July 2025
ICS 71.100.80 Will supersede EN 889:2023
English Version
Chemicals used for treatment of water intended for human
consumption - Iron (II) sulfate
Produits chimiques utilisés pour le traitement de l'eau Produkte zur Aufbereitung von Wasser für den
destinée à la consommation humaine - Sulfate de fer menschlichen Gebrauch - Eisen(II)sulfat
(II)
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 164.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2025 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 889:2025 E
worldwide for CEN national Members.

Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 6
4 Description . 6
4.1 Identification . 6
4.1.1 Chemical names . 6
4.1.2 Synonym or common names . 6
4.1.3 Relative molecular mass . 7
4.1.4 Empirical formula . 7
4.1.5 Chemical formula . 7
4.1.6 CAS Registry Number . 7
4.1.7 EINECS reference . 7
4.2 Commercial forms . 7
4.3 Physical properties . 8
4.3.1 Appearance . 8
4.3.2 Density . 8
4.3.3 Solubility (in water) . 8
4.3.4 Vapour pressure . 8
4.3.5 Boiling point at 100 kPa . 8
4.3.6 Melting point . 8
4.3.7 Specific heat . 8
4.3.8 Viscosity (dynamic) . 8
4.3.9 Critical temperature . 8
4.3.10 Critical pressure . 9
4.3.11 Physical hardness . 9
4.4 Chemical properties . 9
5 Purity criteria . 9
5.1 General . 9
5.2 Composition of commercial product . 9
5.3 The grade of the product . 9
5.4 The type of the product . 10
6 Test methods . 10
6.1 Sampling . 10
6.2 Analyses . 11
7 Labelling - Transportation - Storage . 11
7.1 Means of delivery . 11
7.2 Risk and safety labelling according to the EU Directives . 11
7.3 Transportation regulations and labelling . 12
7.4 Marking . 12
7.5 Storage . 12
7.5.1 Long term stability . 12
7.5.2 Storage incompatibilities . 13
Annex A (informative) General information on iron (II) sulfate . 14
A.1 Origin . 14
A.1.1 Raw materials . 14
A.1.2 Manufacturing process . 14
A.2 Quality of commercial product . 14
A.3 Use . 16
A.3.1 Function . 16
A.3.2 Form in which it is used. 16
A.3.3 Treatment dose . 16
A.3.4 Means of application . 16
A.3.5 Secondary effects . 16
A.3.6 Removal of excess product . 17
Annex B (normative) General rules relating to safety . 18
B.1 General rules relating to safety . 18
B.2 Emergency procedures . 18
B.2.1 First aid . 18
B.2.2 Spillage . 18
B.2.3 Fire . 18
Bibliography . 19

European foreword
This document (prEN 889:2025) has been prepared by Technical Committee CEN/TC 164 “Water
supply”, the secretariat of which is held by AFNOR.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 889:2023.
— update of the information related to limit values in Table 2 and Annex A.

Introduction
In respect of potential adverse effects on the quality of water intended for human consumption, caused
by the product covered by this document:
a) this document provides no information as to whether the product may be used without restriction
in any of the Member States of the EU or EFTA;
b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing
national regulations concerning the use and/or the characteristics of this product remain in force.
NOTE Conformity with this document does not confer or imply acceptance or approval of the product in any
of the Member States of the EU or EFTA. The use of the product covered by this document is subject to regulation
or control by National Authorities.

1 Scope
This document is applicable to iron (II) sulfate heptahydrate and iron (II) sulfate monohydrate used for
treatment of water intended for human consumption. It describes the characteristics of iron (II) sulfate
heptahydrate and monohydrate, specifies the requirements and the corresponding analytical methods
and gives information on their use in water treatment. It also determines the rules relating to safe
handling (Annex B) and use of iron (II) sulfate (Annex A).
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 17215, Chemicals used for treatment of water intended for human consumption — Iron-based
coagulants — Analytical methods
3 Terms and definitions
No terms and definitions are listed in this document.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https://www.iso.org/obp
— IEC Electropedia: available at https://www.electropedia.org/
4 Description
4.1 Identification
4.1.1 Chemical names
a) Iron (II) sulfate heptahydrate
b) Iron (II) sulfate monohydrate
c) Iron (II) sulfate solution
4.1.2 Synonym or common names
a) Ferrous sulfate, iron vitriol, copperas, green salt
b) Ferrous sulfate, monohydrate
c) Ferrous sulfate, solution
4.1.3 Relative molecular mass
a) 278,02 g/mol
b) 169,96 g/mol
c) 151,94 g/mol
4.1.4 Empirical formula
a) FeSO ·7H O
4 2
b) FeSO ·H O
4 2
c)
...

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