EN ISO 5667-14:2016

SLOVENSKI STANDARD
01-junij-2017
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Water quality - Sampling - Part 14: Guidance on quality assurance and quality control of
environmental water sampling and handling (ISO 5667-14:2014)
Wasserbeschaffenheit - Probenahme - Teil 14: Anleitung zur Qualitätssicherung und
Qualitätskontrolle der umweltrelevanten Wasserprobenahme und -handhabung (ISO
5667-14:2014)
Qualité de l'eau - Échantillonnage - Partie 14: Lignes directrices pour le contrôle de la
qualité dans l'échantillonnage et la manutention des eaux environnementales (ISO 5667-
14:2014)
Ta slovenski standard je istoveten z: EN ISO 5667-14:2016
ICS:
13.060.45 Preiskava vode na splošno Examination of water in
general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 5667-14
EUROPEAN STANDARD
NORME EUROPÉENNE
August 2016
EUROPÄISCHE NORM
ICS 13.060.45
English Version
Water quality - Sampling - Part 14: Guidance on quality
assurance and quality control of environmental water
sampling and handling (ISO 5667-14:2014)
Qualité de l'eau - Échantillonnage - Partie 14: Lignes Wasserbeschaffenheit - Probenahme - Teil 14:
directrices pour le contrôle de la qualité dans Anleitung zur Qualitätssicherung und
l'échantillonnage et la manutention des eaux Qualitätskontrolle bei der Entnahme und Handhabung
environnementales (ISO 5667-14:2014) von umweltrelevanten Wasserproben (ISO 5667-
14:2014)
This European Standard was approved by CEN on 15 July 2016.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2016 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 5667-14:2016 E
worldwide for CEN national Members.

Contents Page
European foreword . 3
European foreword
The text of ISO 5667-14:2014 has been prepared by Technical Committee ISO/TC 147 “Water quality”
of the International Organization for Standardization (ISO) and has been taken over as EN
ISO 5667-14:2016 by Technical Committee CEN/TC 230 “Water analysis” the secretariat of which is
held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by February 2017, and conflicting national standards
shall be withdrawn at the latest by February 2017.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 5667-14:2014 has been approved by CEN as EN ISO 5667-14:2016 without any
modification.
INTERNATIONAL ISO
STANDARD 5667-14
Second edition
2014-12-15
Water quality — Sampling —
Part 14:
Guidance on quality assurance and
quality control of environmental
water sampling and handling
Qualité de l’eau — Échantillonnage —
Partie 14: Lignes directrices pour le contrôle de la qualité dans
l’échantillonnage et la manutention des eaux environnementales
Reference number
ISO 5667-14:2014(E)
©
ISO 2014
ISO 5667-14:2014(E)
© ISO 2014
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
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Tel. + 41 22 749 01 11
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Published in Switzerland
ii © ISO 2014 – All rights reserved

ISO 5667-14:2014(E)
Contents Page
Foreword .iv
Introduction .vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Sources of sampling error . 4
5 Sampling quality . 5
5.1 General . 5
5.2 Technical and personnel requirements . 6
5.3 Sampling manual . 6
5.4 Training of sampling staff . 7
6 Strategy and organization . 7
6.1 Time, duration and frequency of sampling. 7
6.2 Sampling collection locations . 8
7 Sample collection and handling . 8
7.1 Equipment and vehicle check prior to carrying out a sampling programme . 8
7.2 Preparation for sampling on-site . 9
7.3 Field measurements . 9
7.4 Taking the samples . 9
8 Sample identification .12
9 Field sample protocol .12
10 Transport and storage of samples .12
11 Sampling quality control techniques .13
11.1 General .13
11.2 Replicate quality control samples .15
11.3 Field blank samples .16
11.4 Rinsing of equipment (sampling containers) .17
11.5 Filtration recovery .18
11.6 Technique 1 — Spiked samples .20
11.7 Technique 2 — Spiked environmental samples .22
12 Analysis and interpretation of quality control data .22
12.1 Shewhart control charts.22
12.2 Construction of duplicate control charts .23
13 Independent audits.23
[7]
Annex A (informative) Common sources of sampling error .25
Annex B (informative) Control charts .27
Annex C (informative) Sub-sampling using a homogenizer .31
Bibliography .34
ISO 5667-14:2014(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with
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